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Preparation method of superfine ceramic powder injection molding mixture

A ceramic powder and injection molding technology, which is applied in ceramic molding machines, clay preparation devices, chemical instruments and methods, etc., can solve problems such as cracking and bubbling, difficulty in dispersing, and difficult control of degreasing rate

Inactive Publication Date: 2010-01-06
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Water degreasing is a new chemical degreasing method that introduces a thermoplastic and water-soluble polymer binder system into ceramic injection molding. It has high degreasing efficiency, easy control of degreasing defects, energy saving and environmental protection, and is suitable for complex shapes and large sizes. Advantages such as molding and preparation of ceramic parts, so as to overcome the disadvantages of low degreasing rate and long time caused by current thermal degreasing
However, ultra-fine ceramic powders are often used in the manufacture of high-reliability and high-performance structural ceramics, and ultra-fine ceramic powders are not easy to disperse in the water degreasing binder system, and are easy to agglomerate, resulting in decreased fluidity and poor uniformity of the injection mixture.
At the same time, the single use of water solvent degreasing, the degreasing rate is not easy to control, and it is easy to cause defects such as cracking and bubbling

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The ratio of ceramic powder and organic binder is shown in the table below (percentage by weight):

[0018] Zirconia

ceramic powder

polyethylene

butyral

aldehyde

polyethylene two

Alcohol

oxidation

polyethylene

olefin wax

stearin

sour

Microcrystalline Paraffin

terephthalate

Formic acid two

Butyl ester

87

1.5-2.0

6.5-8.5

0.6-1.7

0.65

0.65-0.80

0.5

[0019] Take the preparation of 1kg injection mixture as an example. Fully dissolve 6.5g of stearic acid into an appropriate amount of ethanol solution, the temperature of ethanol is 40°C, and then add 870g of zirconia ceramic powder into the solution. Then ultrasonically disperse for 30 minutes, ultrasonic power, and then stir for 2 hours; or ball mill for 12 hours, rotating speed r / min. Then the slurry is dried and the etha...

Embodiment 2

[0022] The ratio of ceramic powder and organic binder is shown in the table below (percentage by weight):

[0023] Aluminum oxide

ceramic powder

Polymethylpropane

methyl acrylate

high density

polyethylene

Polyoxygen

Chemical B

ene

Oxidized poly

vinyl wax

stearin

sour

Ceramic stone

the wax

terephthalate

Formic acid two

Butyl ester

89

0.9-1.2

0.9-1.2

5.0-7.0

0.55-1.65

0.75

0.65-0.8

0.45

[0024] The surface modification method of alumina powder is the same as Example 1. The surface-modified powder is mixed with polymethyl methacrylate, polymethyl methacrylate open mill or twin-screw mixer for 10 minutes, and the mixing temperature is 180°C. Then the temperature of the kneader was lowered to 130°C, and the oxidized polyethylene wax, polyethylene wax and microcrystalline paraffin wax w...

Embodiment 3

[0027] The ratio of ceramic powder and organic binder is shown in the table below (percentage by weight):

[0028] Silicon nitride

ceramic powder

polyethylene

butyral

aldehyde

Vinyl acetate

vinyl ester co

polymer

polyethylene two

Alcohol

oxidation

polyethylene

olefin wax

stearic acid

Terephthalate

dioctyl ester

83

1.3-2.2

0.8-1.6

8.5-11.1

0.7-2.0

0.8

0.7

[0029] The surface modification method of the silicon nitride powder is the same as that of Example 1. The surface-modified powder is mixed with polyvinyl butyral and ethylene vinyl acetate copolymer for 10 minutes on an open mill or a twin-screw mixer, and the mixing temperature is 170°C. Then lower the temperature of the mixer to 130° C., add oxidized polyethylene wax and polyethylene glycol, and knead for 15 minutes. Then lower the temperature...

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PUM

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Abstract

The invention discloses a preparation method of a superfine ceramic powder injection molding mixture, which belongs to the technical field of ceramic injection molding. The preparation method of the superfine ceramic powder injection molding mixture comprises the steps: carrying out ultrasonic dispersion or high-speed ball grinding dispersion and surface modification of submicron or nanometer level ceramic powder in surface active agent solution; evenly mixing the surface modified powder with a non water-solubility organic binding agent, a water-solubility organic binding agent and other additives in a mixer according to a specific order; injecting and molding obtained injecting and mixing material on an injection molding machine to obtain a blank body; and quickly degreasing the blank body by water in water and ethanol mixing solution with a certain proportion under a certain degreasing temperature system. The obtained water-degreased injection material has even mixture, high strength of a green blank and good fluidity. The degreasing method has high degreasing speed and good blank shape maintaining performance and avoids the defects of cracking, bubbling, and the like.

Description

technical field [0001] The invention belongs to the technical field of ceramic injection molding, and discloses a preparation method and a degreasing method of a superfine ceramic powder injection molding compound. Background technique [0002] Ceramic injection molding is a near-net-size molding technology that can continuously, efficiently, and low-cost manufacture ceramic parts with high dimensional accuracy and complex shapes. Its products are widely used in energy, environmental protection, automobiles, aerospace, chemical industry, biomedical and other fields . [0003] Water degreasing is a new chemical degreasing method that introduces a thermoplastic and water-soluble polymer binder system into ceramic injection molding. It has high degreasing efficiency, easy control of degreasing defects, energy saving and environmental protection, and is suitable for complex shapes and large sizes. Advantages such as molding and preparation of ceramic parts, so as to overcome th...

Claims

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Application Information

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IPC IPC(8): B28B3/20B28C1/02B28C3/00B28B11/24C04B35/48C04B35/10C04B35/565C04B35/584
Inventor 谢志鹏杨现锋曾兴华曾国华贾翠刘冠伟
Owner TSINGHUA UNIV
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