Zinc-magnesium titanate series ceramic dielectric material and prepared ceramic capacitor
A technology of ceramic capacitors and ceramic dielectrics, applied in the direction of laminated capacitors, fixed capacitor electrodes, fixed capacitor dielectrics, etc., can solve problems such as harmful to the environment and human body, thermal stability, and insufficient dielectric properties
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Embodiment 1
[0027] Raw materials with a purity of 99.5 or more, with 0.999 moles of Mg(OH) 2 , 0.001 mole of ZnO and 1 mole of TiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1080-1130°C for 2.5 hours to obtain the main agglomerate zinc magnesium titanate Mg (1-x) Zn x TiO 3 (x=0.001).
[0028] Raw materials with a purity of 99.5 or more, with 1.999 moles of Mg(OH) 2 , 0.001 mole of ZnO and 1 mole of SiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1140-1180°C for 2.5 hours to obtain the main agglomerate zinc magnesium silicate Mg (2-y) Zn y SiO 4 (y=0.001).
[0029] Then, auxiliary components were added to the main components in predetermined proportions, as shown in Table 1. Make ceramic materials according to the conventional material production process; then, according to the production process of chip MLCC, add organic binders and ethanol and other solvents to form a slurry, and make the slurry flow into a 20-micro...
Embodiment 2
[0037] Raw materials with a purity of 99.5 or more, with 0.999 moles of Mg(OH) 2 , 0.001 mol ZnO and 1 mol TiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1080-1130°C for 2.5 hours to obtain the main agglomerate zinc magnesium titanate Mg (1-x) Zn x TiO 3 (x=0.001).
[0038] Raw materials with a purity of 99.5 or more, with 1.999 moles of Mg(OH) 2 , 0.001 mol ZnO and 1 mol SiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1140-1180°C for 2.5 hours to obtain the main agglomerate zinc magnesium silicate Mg (2-y) Zn y SiO 4 (y=0.001).
[0039] Raw materials with a purity of 99.5 or more, mixed with ZnO and H in a predetermined ratio 3 BO 3 , ball milled evenly, and then pre-calcined the mixture for 2.5 hours, thus obtaining a uniform auxiliary component ZnO and B2O3 mixture.
[0040] Then add auxiliary components to the main components according to a predetermined ratio, as shown in Table 3, manufacture and te...
Embodiment 3
[0047] Raw materials with a purity of 99.5 or more, with 0.995 moles of Mg(OH) 2 , 0.005 mol ZnO and 1 mol TiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1080-1130°C for 2.5 hours to obtain the main agglomerate zinc magnesium titanate Mg (1-x) Zn x TiO 3 (x=0.005).
[0048] Raw materials with a purity of 99.5 or more, with 1.98 moles of Mg(OH) 2 , 0.02 mol ZnO and 1 mol SiO 2 Mixing ratio, ball milling and mixing evenly, pre-calcine the mixture at 1140-1180°C for 2.5 hours to obtain the main agglomerate zinc magnesium silicate Mg (2-y) Zn y SiO 4 (y=0.02).
[0049] Raw materials with a purity of 99.5 or more, mixed with ZnO and H in a predetermined ratio 3 BO 3 , ball milled evenly, and then pre-calcined the mixture for 2.5 hours, thus obtaining a uniform auxiliary component ZnO and B2O3 mixture.
[0050] Then add auxiliary components to the main components in a predetermined proportion, as shown in Table 5, manufacture and test accor...
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