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70 results about "Titanyl phthalocyanin" patented technology

Processes for the preparation of high sensitivity titanium phthalocyanines photogenerating pigments

A process for preparing a high sensitivity titanyl phthalocyanine (TiOPc) pigment includes dissolving a Type I TiOPc in a suitable solvent, precipitating an intermediate TiOPc pigment by quenching the solution comprising the dissolved Type I TiOPc in a solvent system comprising an alcohol and alkylene chloride such as, for example, methylene chloride, and treating the intermediate TiOPc pigment with monochlorobenzene. The resultant TiOPc pigment, which is designated as a Type V TiOPc, is suitable for use as a charge generating material in a photoreceptor of an imaging device.
Owner:XEROX CORP

Photoconductor, image forming apparatus, image forming process, and process cartridge

The object of the present invention is to provide a photoconductor that is highly sensitive, stable in image quality under repeated usages, and affords prolonged life. In order attain the object, a photoconductor is provided that comprises a charge generating layer, a charge transporting layer, and a crosslinked charge transporting layer, on an substrate in order, the charge generating layer contains titanyl phthalocyanine crystal particles that exhibit a highest peak at 27.2°, main peaks at 9.4°, 9.6° and 24.0°, a peak at 7.3° as the lowest angle, and with no peaks in a range between 7.3° and 9.4°, and with no peak at 26.3° as Bragg 2θangles (±0.2°) in terms of CuK-α characteristic X-ray wavelength at 1.542 Å, and the averaged primary particle size of the titanyl phthalocyanine crystal particles is 0.25 μm or less, and the crosslinked charge transporting layer contains a reaction product of a radical polymerizable monomer having three or more functionalities and no charge transporting structure and a radical polymerizable compound having one functionality and a charge transporting structure, and the thickness of the crosslinked charge transporting layer is 1 to 10 μm.
Owner:RICOH KK

Crystalline oxotitanylphthalocyanine and electrophotographic photoreceptor using the same

An object of the invention is to improve the photosensitivity characteristics, characteristics on repeated use and stability of a photoreceptor. A photosensitive layer formed on a conductive support of a photoreceptor contains crystalline oxotitanylphthalocyanine having major peaks in an X-ray diffraction spectrum at Bragg angles (2theta±0.2°) of 7.3°, 9.4°, 9.6°, 11.6°, 13.3°, 17,9°, 24.1° and 27.2°, wherein a peak bundle formed by overlapping the peaks at 9.4° and 9.6° is the largest peak, and the peak at 27.2° is the secondary largest peak as a charge generating substance. Furthermore, it contains a bisamine compound, an N,N'-bisenamine compound, a styryl compound, an amine-hydrazone compound, a benzofuran-bishydrazone compound, a bisenamine compound, a benzofuran-bishydrazone compound or a benzofuran-bis-cyclic hydrazone compound represented by the particular structural formulae as a charge transporting substance.
Owner:SHARP KK

Titanyl phthalocyanine, method for production thereof and electrophotographic photoreceptor containing the same

A peroxide-modified titanyl phthalocyanine for use in preparing charge generating layer of a photoreceptor is disclosed. The peroxide-modified titanyl phthalocyanine is obtained by subjecting titanyl phthalocyanine to a peroxide-induced complexation-mediated crystal transformation at a low temperature. The peroxide-modified titanyl phthalocyanine is characterized by having Bragg diffraction angles of 7.3, 9.4, 14.0, 24.1, 25.7, 27.2 and 28.5 degrees, and vibrational absorption resonances at 1486 cm (superscript: -1), 1420 cm (superscript: -1), 1134 cm (superscript: -1), 1078 cm (superscript: -1), 966 cm (superscript: -1), 900 cm (superscript: -1), 762 cm (superscript: -1) and 736 cm (superscript: -1). The photoreceptor exhibits excellent photosensitivity at wavelengths in the near-infrared range and has a unique crystal form, especially the peroxide-modified titanyl phthalocyanine shows a higher distinct absorption peak at the wavelength of 780 nm.
Owner:TAIWAN SALT INDAL CORP +1

Coating solution containing cocrystals and or crystals of a charge-generation pigment or a mixture of charge-generation pigments

A method for preparing a coating solution containing a cocrystallized titanyl phthalocyanine-titanyl fluorophthalocyanine, the method comprising: dry milling a charge-generation pigment or mixtures of charge-generation pigments; increasing the amorphousness of the pigment mixture as determined by X-ray crystallography using X-radiation characteristic of Cu Kα at a wavelength of 1.541 Å of the Bragg angle 2θ to provide an amorphous pigment mixture; contacting the amorphous pigment mixture with a first organic solvent having a gammac hydrogen bonding parameter of less than 9, with or without the presence of a dispersant material, to produce a crystalline pigment of the charge-generation pigment prior to contacting the pigment with a second organic solvent having a gammac hydrogen bonding parameter greater than 9; mixing at least one of a second organic solvent, a dispersant and a binder with the crystalline pigment / first solvent mixture without isolating the crystalline pigment to produce a mixture; and, adjusting the concentrations of the first organic solvent, crystalline pigment, binder, dispersants and second organic solvent as required to produce the coating solution of a selected composition.
Owner:EASTMAN KODAK CO

Electrophotographic photoreceptor, image forming apparatus using the electrophotographic photoreceptor, and method of producing electrophotographic photoreceptor

An electrophotographic photoreceptor is provided that contains a conductive substrate, an undercoat layer, a charge generation layer, and a charge transport layer, wherein the under coat layer contains a binder resin and multiple inorganic pigments each having different average primary particle diameters in a total amount of from 75 to 86% by weight, the charge generation layer contains a binder resin and a titanyl phthalocyanine pigment having a specific X-ray diffraction spectrum in an amount of from 70 to 85% by weight, the charge transport layer comprises a specific distyryl compound, and the following formulae (2-1) to (2-3) are satisfied:0.2≦(D(F2) / D(G))≦0.5  (2-1)0.2≦D(F1)  (2-2)D(F2)≦D(F1)  (2-3)wherein D(F1) (μm) and D(F2) (μm) represent average primary particle diameters of the largest and smallest inorganic pigments, respectively, and D(G) (μm) represents an average primary particle diameter of the titanyl phthalocyanine pigment.
Owner:RICOH KK

Photosensitive material, electrophotographic photoreceptor using the material, and electrophotographic image forming method and apparatus using the photoreceptor

A titanyl phthalocyanine crystal having an X-ray diffraction spectrum having a plurality of diffraction peaks in which a maximum diffraction peak is observed at a Bragg (2 θ) angle of 27.2°±0.2° and a diffraction peak is observed at a lowest Bragg (2θ) angle of 7.3°±0.2° when a specific X-ray of Cu—Kα having a wavelength of 1.514 Å irradiates the titanyl phthalocyanine crystal. A photoreceptor having a photosensitive layer including the titanyl phthalocyanine crystal is also provided.
Owner:RICOH KK

Titanyl phthalocyanin crystal, method for preparing the same and electrophotographic photoconductor

According to the present invention, a titanyl phthalocyanin crystal excellent in storage stability in organic solvents, a method for preparing the same and an electrophotographic photoconductor using the same are provided. In the titanyl phthalocyanin crystal, the method for preparing such a titanyl phthalocyanin crystal and the electrophotographic photoconductor using the same, the titanyl phthalocyanin crystal is characterized by having the maximum peak at a Bragg angle 2θ±0.2°=27.2° in a CuKα characteristic X-ray diffraction spectrum and one peak within the range of 270 to 400° C. other than a peak accompanied by the vaporization of adsorbed water in a differential scanning calorimetric analysis.
Owner:KYOCERA DOCUMENT SOLUTIONS INC

Electrophotographic image forming apparatus

ActiveUS7029810B2Stably producing high-resolution imageEradicating electrical deteriorationOrganic dyesElectrographic process apparatusX-rayEngineering
An electrophotographic image forming apparatus comprising:an electrophotographic photoreceptor comprising:an electroconductive substrate;a charge generation layer; anda charge transport layer in this order,a charger;an irradiator;an image developer; anda transferer applying an electric current not less than 65 μA to the electrophotographic photoreceptor,wherein the charge generation layer comprises titanylphthalocyanine crystals having a CuKα 1.542 Å X-ray diffraction spectrum having plural diffraction peaks, wherein a maximum diffraction peak is observed at a Bragg (2 θ) angle of 27.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and no diffraction peak is observed at an angle greater than 7.3° and less than 9.4°, wherein said angles may vary by ±0.2° and the minimum interval where no peak is observed between required peaks at 7.3 and 9.4 is 2.0 degrees absolute or more.
Owner:RICOH KK

Electrophotographic photoreceptor, method for manufacturing the electrophotographic photoreceptor, and image forming apparatus and process cartridge using the electrophotographic photoreceptor

A photoreceptor including an electroconductive substrate; and a charge blocking layer; a moiré preventing layer; and a photosensitive layer, which are overlaid overlying the substrate in this order, wherein the photosensitive layer includes a titanyl phthalocyanine crystal which has an average primary particle diameter not greater than 0.25 μm, and has an X-ray diffraction spectrum such that a maximum peak is observed at a Bragg (2θ) angle of 27.2°±0.2°; a peak is observed at Bragg (2θ) angle of 9.4°±0.2°, 9.6±0.2° and 24.0±0.2°; a lowest angle peak is observed at an angle of 7.3°±0.2°; no peak is observed between the lowest angle peak and the 9.4° peak; and no peak is observed at a Bragg (2θ) angle of 26.3°±0.2°, when a Cu—Kα X-ray having a wavelength of 0.1542 nm (1.542 Å) is used.
Owner:RICOH KK

Photoconductor, image forming apparatus, image forming process, and process cartridge

The object of the present invention is to provide a photoconductor that is highly sensitive, stable in image quality under repeated usages, and affords prolonged life.In order attain the object, a photoconductor is provided that comprises a charge generating layer, a charge transporting layer, and a crosslinked charge transporting layer, on an substrate in order,the charge generating layer contains titanyl phthalocyanine crystal particles that exhibit a highest peak at 27.2°, main peaks at 9.4°, 9.6° and 24.0°, a peak at 7.3° as the lowest angle, and with no peaks in a range between 7.3° and 9.4°, and with no peak at 26.3° as Bragg 2θangles (±0.2°) in terms of CuK-α characteristic X-ray wavelength at 1.542 Å, and the averaged primary particle size of the titanyl phthalocyanine crystal particles is 0.25 μm or less, andthe crosslinked charge transporting layer contains a reaction product of a radical polymerizable monomer having three or more functionalities and no charge transporting structure and a radical polymerizable compound having one functionality and a charge transporting structure, and the thickness of the crosslinked charge transporting layer is 1 to 10 μm.
Owner:RICOH KK

Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus

An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R1 and R2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R1 and R2 are optionally the same or different:The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Owner:FUJI ELECTRIC CO LTD

Titanyl phthalocyanine crystal and production method of the same, and electrophotosensitive material

The present invention relates to a novel titanyl phthalocyanine crystal which can prepare a coating solution having excellent storage stability because it satisfies both of the following two characteristics (a) and (b), a method of producing the same, an electrophotosensitive material using the above crystal as an electric charge generating material.(a) The crystal has a maximum peak at a Bragg angle 2θ±0.2°=27.2° and has no peak at 7.4° in a CuKα characteristic X-ray diffraction spectrum.(b) The crystal does not have a peak of a change in temperature within a range from 50 to 400° C. except for a peak associated with evaporation of adsorbed water in differential scanning calorimetry.
Owner:KYOCERA DOCUMENT SOLUTIONS INC

Electrophotographic photoreceptor, and image forming apparatus and process cartridge therefor using the photoreceptor

An electrophotographic photoreceptor, including a charge generation layer and a charge transport layer on an electroconductive substrate, wherein the charge generation layer includes titanylphthalocyanine and a binder resin which is a crosslinked material of a resin comprising a polyvinylbutyral site having the following formula (1) and an isocyanate compound having the following formula (2):wherein R1 and R2 independently represent an alkyl group having 1 to 3 carbon atoms; k, l, m and n represent composition ratios and k+l is from 0.60 to 0.80, wherein k or l may be 0, m is from 0.02 to 0.03, and n is from 0.20 to 0.40;wherein A represents a substituted or unsubstituted organic group having 2 to 4 valences; and O represents an integer of from 2 to 4.
Owner:RICOH KK

Method of using high temperature plasma to disintegrate waste containing titanyl phthalocyanine

A method of using high temperature plasma to disintegrate waste containing titanyl phthalocyanine (TiOPc) comprises heating a mixture of titanyl phthalocyanine (TiOPc), a vitrifying material and selected waste soil to a temperature of 1,220° C. to 10,000° C. until the mixture becomes molten lava. The plasma breaks down the titanyl phthalocyanine and encapsulates the benign products in the lava that is chemically very stable. Since the titanyl phthalocyanine (TiOPc) is disintegrated completely in the process, the titanyl phthalocyanine (TiOPc) no longer represents a threat to the environmental.
Owner:LABELTEK +1

Titanyl phthalocyanin crystal, method for preparing the same and electrophotographic photoconductor

According to the present invention, a titanyl phthalocyanin crystal excellent in storage stability in organic solvents, a method for preparing the same and an electrophotographic photoconductor using the same are provided. In the titanyl phthalocyanin crystal, the method for preparing such a titanyl phthalocyanin crystal and the electrophotographic photoconductor using the same, the titanyl phthalocyanin crystal is characterized by having the maximum peak at a Bragg angle 2 θ±0.2°=27.2° in a CuKα characteristic X-ray diffraction spectrum and one peak within the range of 270 to 400° C. other than a peak accompanied by the vaporization of adsorbed water in a differential scanning calorimetric analysis.
Owner:KYOCERA DOCUMENT SOLUTIONS INC

Titanylphthalocyanine crystal and method of producing the titanylphthalocyanine crystal, and electrophotographic photoreceptor, method, apparatus and process cartridge using the titanylphthalocyanine crystal

A titanylphthalocyanine crystal having an X-ray diffraction spectrum having plural diffraction peaks and a primary particle diameter not greater than 0.2 μm, wherein a maximum diffraction peak is observed at a Bragg (2 θ) angle of 27.2±0.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and preferably no diffraction peak is observed at an angle greater than 7.3° and less than 9.4° when a specific X-ray of CuKα having a wavelength of 1.542 Å irradiates the titanylphthalocyanine crystal.
Owner:NIIMI TATSUYA

Electrophotographic photoconductor having titanyl phthalocyanine and image forming apparatus

The present invention provides a monolayer type electrophotographic photoconductor which can effectively suppress the generation of an exposure memory and exhibits high sensitivity and an image forming apparatus using the monolayer type electrophotographic photoconductor. In an electrophotographic photoconductor which has a monolayer type photoconductive layer including at least a charge generating agent, a hole transfer agent, an electron transfer agent and a binding resin on a substrate, the charge generating agent contains oxo-titanyl phthalocyanine crystal, the electron transfer agent has a reduction potential thereof set to a value which falls within a range from −0.97 to −0.83 V, and the reflection absorbance (A / −) of the photoconductive layer with respect to light having a wavelength of 700 nm, a film thickness (d / m) of the photoconductive layer, and the concentration (C / weight %) of the oxo-titanyl phthalocyanine crystal of the photoconductive layer (100 weight %) satisfy a following formula (1).A·C−1·d−1>1.75×104  (1)
Owner:KYOCERA DOCUMENT SOLUTIONS INC

Titanylphthalocyanine comprising specific polymorph and method for producing thereof, and electrophotographic photoreceptor comprising charge generating material thereof

The present invention relates to a titanylphthalocyanine represented by the formula (1):comprising a polymorph having a peak at a Bragg angle (2θ±0.2°) in X-ray diffraction spectrum with CuK α-ray: 9.0°, 9.6°, 14.1°, 14.9°, 17.9°, 18.3°, 23.4°, 24.5° and 27.2°; and1.3<Ir1<1.8;1.0<Ir2;1.3<Ir3<2.0; and0.9<Ir4<1.1whereinIr1 is a ratio (9.6° / 9.0°) of an intensity of the peak at Bragg angle of 9.6° to an intensity of the peak at Bragg angle of 9.0°;Ir2 is a ratio (14.1° / 14.9°) of an intensity of the peak at Bragg angle of 14.1° to an intensity of the peak at Bragg angle of 14.9°;Ir3 is a ratio (17.9° / 18.3°) of an intensity of the peak at Bragg angle of 17.9° to an intensity of the peak at Bragg angle of 18.3°; andIr4 is a ratio (24.5° / 23.4°) of an intensity of the peak at Bragg angle of 24.5° to an intensity of the peak at Bragg angle of 23.4°.The present invention can provide the above novel titanylphthalocyanine having superior photoreceptor characteristics, particularly superior chargeability and photosensitivity to those of the conventional titanylphthalocyanines, and a method for producing the present titanylphthalocyanine, as well as an electrophotographic photoreceptor comprising a charge generating material of the present titanylphthalocyanine, which has excellent photosensitive characteristics.
Owner:ORIENT CHEM INDS

Electrophotographic photoreceptor and electrophotographic imaging apparatus employing the photoreceptor

InactiveUS7622232B2Good photosensitivity and repetition stabilityImprove featuresElectrographic process apparatusCorona dischargeEngineeringPhthalocyanine
An electrophotographic photoreceptor including a photosensitive layer which includes a titanyl phthalocyanine crystal having a major absorption peak at a wavelength of 780 nm±10 nm and a minor absorption peak having an intensity of ¾ or less of the major absorption peak at 690 nm±10 nm in the visible-infrared absorption spectrum and a distyryl compound having a predetermined structure. An electrophotographic image forming apparatus employing the electrophotographic photoreceptor is also provided. The electrophotographic photoreceptor and the electrophotographic image forming apparatus have good photosensitivity and charging properties and good stability over repeated charging obtained by using an optimum combination of a new crystal type of a highly photosensitive titanyl phthalocyanine and a distyryl compound which is a charge transporting material that is compatible with the titanyl phthalocyanine.
Owner:S PRINTING SOLUTION CO LTD

Titanyl phthalocyanine with improved milling properties

The invention is directed to mixtures of PcTiO and a minor amount of another, substituted titanyl phthalocyanine and the synthesis of mixtures of PcTiO and a minor amount of another, substituted titanyl phthalocyanine. The invention is further directed towards milled pigment compositions of such mixtures, and to use of such milled pigment compositions in an electrophotographic element.
Owner:EASTMAN KODAK CO

Method of using high temperature plasma to disintegrate waste containing titanyl phthalocyanine

A method of using high temperature plasma to disintegrate waste containing titanyl phthalocyanine (TiOPc) comprises heating a mixture of titanyl phthalocyanine (TiOPc), a vitrifying material and optionally selected waste soil to a temperature of 1,220° C. to 10,000° C. until the mixture becomes a molten lava. The plasma breaks down the titanyl phthalocyanine and encapsulates the benign products in the lava that is chemically very stable. Since the titanyl phthalocyanine (TiOPc) is disintegrated completely in the process, the titanyl phtbalocyanine (TiOPc) no longer represents a threat to the environmental.
Owner:LABELTEK +1
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