The invention discloses a peel-off type yellow orange whitening mask and a preparation method thereof. The peel-off type yellow orange whitening mask is prepared by using a conventional method from the following raw materials by weight: 10 to 14 parts of polyvinyl alcohol, 8 to 12 parts of glycerin, 0.8 to 1.2 parts of 3-myristoylamidopropyl betaine, 4 to 6 parts of ethanol, 6 to 8 parts of sodium lauryl amphoacetate, 0.8 to 2 parts of a yellow orange extract, 0.03 to 0.08 part of a composite antiseptic and 100 parts of deionized water, wherein the composite antiseptic is composed of, by weight, 1 to 3 parts of carnosic acid, 3 to 5 parts of a bamboo leaf antioxidant, 1 to 3 parts of nisin and 1 to 3 parts of 3-iodo-2-propynyl butyl carbamate. The peel-off type yellow orange whitening mask provided by the invention can effectively prevent dryness, yellowing, roughness and the like of the face caused by fatigue, pollution, radiation, drying, an air-conditioner, etc., improves non-uniform skin colors of the face and enables the skin to rapidly become clean, white and uniform and to maintain moistened and glossy for a long time.