Solid oxide fuel cell and manufacturing method thereof

Abstract

An electric power generation cell 1 is constituted by arranging a fuel electrode layer 4 on one side of a solid electrolyte layer 3 and an air electrode layer 2 on the other side of the solid electrolyte layer 3. The solid electrolyte layer 3 is constituted of an oxide ion conductor mainly composed of a lanthanum gallate based oxide. The fuel electrode layer 4 is constituted of a porous sintered compact having a highly dispersed network structure in which a skeletal structure formed of a consecutive array of metal grains is surrounded by mixed conductive oxide grains. For the air electrode layer 2, a porous sintered compact mainly composed of cobaltite is used. This configuration reduces the overpotentials of the respective electrodes and the IR loss of the solid electrolyte layer 3, and accordingly can actualize a solid oxide type fuel cell excellent in electric power generation efficiency.

Description

TECHNICAL FIELD [0001] The present invention relates to a solid oxide fuel cell which is provided with the electric power generation cell constituted by arranging a fuel electrode layer on one side of a solid electrolyte layer and an air electrode layer on the other side of the solid electrolyte layer, in particular, to reduction of the electrode overpotential (polarization) in an electric power generation cell of the fuel cell. BACKGROUND OF THE INVENTION [0002] Development of the solid electrolyte type fuel cell having a laminated structure for which the solid electrolyte layer composed of an oxide ion conductor is sandwiched between an air electrode layer (oxidant electrode layer) and a fuel electrode layer is progressing as the fuel cell for use in the next (third) generation electric power production. In a solid electrolyte type fuel cell, oxygen (air) is supplied to an air electrode section and a fuel gas (H2, CO, and the like) is supplied to a fuel electrode section. Both the...

AI Technical Summary

Benefits of technology

[0017] The present invention takes as its object the provision of a high performance solid oxide fuel cell aiming at improvement of the electric power generation efficiency by reducing the electrode overpotentials, and a manufacturing method of the solid oxide fuel cell.

[0021] The configurations and the manufacturing methods according to the present invention as recited in claims 1 to 4 reduce the overpotential of each electrode and the IR loss, and accordingly improve the electric power generation efficiency.

Problems solved by technology

Because the air electrode material is required to be chemically stable in the oxidative atmosphere at high temperatures around 700° C., metals are unsuitable for the air electrode, and generally used are perovskite type oxide materials having electronic conductivity, specifically LaMnO3, LaCoO3 and the solid solutions in which part of the La component in these materials is replaced with Sr, Ca and the like.

The maximum voltage obtainable in an actual fuel cell is the equilibrium electromotive force and the voltage falls with increasing irreversibility.

Incidentally, in a fuel cell, in order to raise the voltage to be taken out, a cell stack is used in which a number of electric power generation cells (single cells) are jointed in series with interconnectors; however, in this case the electric resistance of the interconnectors themselves also causes the IR loss.

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