Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of polymer composite material additive and its application

A technology of composite materials and additives, which is applied in the field of high-value utilization of biomass, can solve the problems of poor dispersion of inorganic nanoparticles, increase of materials, and difficulty in achieving nanoscale compounding, so as to improve high-temperature rheological properties and benefit costs. Reduce the effect of environmental protection

Active Publication Date: 2022-05-10
NANJING TECH UNIV
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, bio-pyrolysis oil contains hundreds of products (complex structure, high separation cost), which contain a large number of oxygen-containing functional groups (low calorific value), oligomers (high viscosity) and organic acids (high acidity, equipment corrosion) and other issues, there is a certain distance to replace fossil fuels
Generally, catalytic hydrogenation, catalytic cracking and other modification processes are used to deal with oxygen-containing functional groups and viscosity problems, but ultimately face the "two high and one low" problems of high energy consumption, high separation cost, and low added value.
[0005] The uniform dispersion of nanoparticles is the basis for constructing the nanostructure of fillers and polymers, and also determines the performance of composite materials. However, at present, inorganic nanoparticles have poor dispersion, are difficult to mix, and are prone to inorganic phase agglomeration in composite materials. body, not only is it difficult to achieve nanoscale recombination, the nano effect cannot be better exerted, and it may increase material defects, which limits its wide application
However, currently used silane coupling agents, titanate coupling agents, zirconate coupling agents, etc. are expensive, and require certain toxic organic solvents as auxiliary agents to modify the surface of inorganic nanoparticles, and cannot be used at room temperature. It is prepared under normal pressure, which increases the cost, so it is necessary to research and develop non-toxic inorganic filler dispersants

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of polymer composite material additive and its application
  • A kind of polymer composite material additive and its application
  • A kind of polymer composite material additive and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Embodiment 1 (epoxidation+alkylation)

[0065] Solid acid catalyst with 1g of inorganic material 50nm SiO 2 with 1ml 0.75mol / L H 2 SO 4 The proportion of the solution was impregnated for 10 hours, dried at 100°C for 8 hours, and the obtained samples were activated by roasting at 400°C for 3 hours to obtain the corresponding SO 4 2- / SiO 2 solid acid catalyst;

[0066] Take 10g of rice husk powder and add it into a high-temperature and high-pressure reactor at 600°C and 0.1MPa pressure (gauge pressure) to prepare 4.3g of bio-oil. After the reaction, add 0.1g of SO to the liquefied bio-oil 4 2- / SiO 2 Solid acid catalyst, stirring, heating temperature to 40°C, and then slowly adding 20% ​​hydrogen peroxide dropwise, wherein hydrogen peroxide accounts for 20wt% of the mass ratio of bio-oil, and after the addition, constant temperature reaction for 2h to obtain modified bio-oil a, Add fatty alcohol: octanol as the raw material for alkylation, which accounts for 10wt...

Embodiment 2

[0067] Embodiment 2 (epoxidation+esterification):

[0068] Solid acid catalyst with 1g of inorganic material 50nm SiO 2 with 1ml 0.75mol / L H 2 SO 4 The proportion of the solution was impregnated for 10 h, dried at 100 °C for 8 h, and then the obtained samples were activated by roasting at 400 °C for 3 h to obtain the corresponding SO 4 2- / SiO 2 solid acid catalyst;

[0069]Take 10g of rice husk powder and add it into a high-temperature and high-pressure reactor at 400°C and 0.2MPa (gauge pressure) to prepare 3.8g of bio-oil. After the reaction, add 0.1g of SO to the liquefied bio-oil 4 2- / SiO 2 Solid acid catalyst, stirring, heating temperature to 40°C, and then slowly adding 20% ​​hydrogen peroxide dropwise, wherein hydrogen peroxide accounts for 20wt% of the mass ratio of bio-oil, after the addition, constant temperature reaction for 2h to obtain modified bio-oil a, Add polyol: pentaerythritol as the raw material of esterification, which accounts for 10wt% of the b...

Embodiment 3

[0070] Embodiment 3 (epoxidation+alkylation+esterification):

[0071] Solid acid catalyst with 1g of inorganic material 50nm SiO 2 with 1ml 0.75mol / L H 2 SO 4 The proportion of the solution was impregnated for 10 h, dried at 100 °C for 8 h, and the obtained samples were roasted at 400 °C for 3 h to obtain the corresponding SO 4 2- / SiO 2 solid acid catalyst;

[0072] Take 10g of rice husk powder and add it into a high-temperature and high-pressure reactor at 600°C and 0.1MPa (gauge pressure) to prepare 4.3g of bio-oil. After the reaction, add 0.1g of SO to the liquefied bio-oil 4 2- / SiO 2 Solid acid catalyst, stirring, heating temperature to 40°C, and then slowly adding 20% ​​hydrogen peroxide dropwise, wherein hydrogen peroxide accounts for 20wt% of the mass ratio of bio-oil, after the addition, constant temperature reaction for 2h to obtain modified bio-oil a, Add fatty alcohol: octanol as raw material for alkylation, which accounts for 5wt% of bio-oil, set the reac...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a polymer composite material additive and an application thereof, belonging to the field of high-value utilization of biomass. The composite material additive is a mixture composed of inorganic particles and modified biomass oil. The biomass oil of the present invention has both dispersing and plasticizing effects, so that it is not necessary to add a large amount of plasticizers and modifiers to the polymer composite material, avoiding the pressure of industrial waste treatment, and is conducive to cost reduction and environmental protection .

Description

technical field [0001] The invention relates to the field of high-value utilization of biomass, which converts biomass oil into a processing aid for polymer materials through catalytic upgrading and product engineering concepts. Background technique [0002] Utilizing biomass to develop green chemical raw materials and functional materials has become the focus and frontier of sustainable development research. An efficient biorefinery process can convert biomass into small molecule liquid fuels and platform compounds, which can then be polymerized to produce related products. However, the complex technological process and the underutilization of the natural structure of biomass itself make the biomass conversion process low in technical economy and cannot be applied on a large scale. [0003] The "EU Horizon 2020 Plan" proposes that the new-generation biomass utilization strategy should be transformed from the existing "physical substitution" that draws on fossil energy to a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08K9/04C08K3/36C08L91/00C08K3/22C08L7/00
CPCC08K9/08C08K3/36C08K3/22C08L7/00C08K2201/005C08K2201/011C08K2003/2241C08K2003/2244C08L91/00
Inventor 穆立文曹丹阳张同桓冯新朱家华陆小华
Owner NANJING TECH UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products