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Thermoplastic polyimide cable material for nuclear power aviation

A technology of polyimide and polyetherimide, which is applied in the field of thermoplastic polyimide cable materials for nuclear power and aviation, can solve the problems that the cable materials cannot be reached, and the fluidity of the soft melt at room temperature and low temperature needs to be improved. Achieve the effects of improving fluidity, good high temperature resistance, and expanding application fields

Inactive Publication Date: 2020-04-21
中广核高新核材科技(苏州)有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these cable materials cannot meet the requirements of nuclear power and aviation cable materials.
CN109705576 A discloses a wear-resistant self-lubricating thermoplastic polyimide composite material and a preparation method thereof, through the use of ether bond-containing polar resin and non-polar crystalline resin, and through the synergistic modification of two polymer resins, the The thermoplastic processability of polyimide composite materials has been improved, but the room temperature and low temperature softness and melt fluidity of the above materials still need to be improved.

Method used

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  • Thermoplastic polyimide cable material for nuclear power aviation
  • Thermoplastic polyimide cable material for nuclear power aviation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] S1. Weigh 10 parts of polyimide (produced by Shanghai Resin, brand Ys-20: special product of Hangzhou Sumeng, brand SS100P=1:1), 14 parts of polyetherimide (Ultem1010), 50 parts by weight Parts of polyetherimide containing silicone (STM1700), 5 parts of polyethersulfone, 5 parts of fully aromatic polyimide liquid crystal polymer, 5 parts of polypropylene, 5 parts of polymethylphenyl silicone resin, 5 parts 1 part of talcum powder, 0.2 part of PETS, 0.3 part of anti-1010, 0.5 part of UV light stabilizer, mixed evenly to obtain a mixture.

[0038]S2. Add the mixed material to the main feed of the twin-screw extruder, melt it and extrude it out from the outlet of the die head, water-cool it and cut it into pellets to obtain thermoplastic polyimide cable material particles for nuclear power and aviation. Wherein, the melting extrusion temperature of the twin-screw extruder is 300-380° C., and the screw speed is 350 rpm / min.

[0039] The above-prepared cable material is pre...

Embodiment 2

[0042] S1. Weigh 5 parts of polyimide (produced by Changchun Gaoqi Polyimide Material Co., Ltd., brand HI-P), 30 parts of polyetherimide (Torlon4000TF: 4203L=2:1), 30 parts Silicone-containing polyetherimide (STM1600), 5 parts of polyether ketone, 5 parts of fully aromatic polyester liquid crystal polymer, 25 parts of LLDPE (linear low density polyethylene), 5 parts of ethylene-propylene copolymer, 5 parts 1 part of polyphenylsilsesquioxane, 5 parts of talcum powder, 0.2 part of erucamide, 0.2 part of anti-1076, 0.6 part of anti-168, 10 parts of flame retardant, and mix evenly to obtain a mixture.

[0043] S2. Add the mixed material to the main feed of the twin-screw extruder, melt it and extrude it out from the outlet of the die head, water-cool it and cut it into pellets to obtain thermoplastic polyimide cable material particles for nuclear power and aviation. Wherein, the melting extrusion temperature of the twin-screw extruder is 300-380° C., and the screw speed is 250 rpm...

Embodiment 3

[0046] S1, take by weight 30 parts of polyimide (Aurum PL450C of Mitsui company), 5 parts of polyetherimide (ULtem1010), 30 parts of silicone-containing polyetherimide (STM1500:1700=5 : 1), 20 parts of polyetheretherketone copolymer, 10 parts of polyether ketone ketone, 5 parts of fully aromatic polyester liquid crystal polymer, 5 parts of low density polyethylene, 5 parts of phenyl MQ silicone resin, 11 parts of talc powder, 0.4 part of oleic acid amide, 0.4 part of anti-1010, 0.2 part of anti-P-EPQ, 4 parts of nucleating agent, and 1 part of carbon black, and mix them evenly to obtain a mixture.

[0047] S2. Add the mixed material to the main feed of the twin-screw extruder, melt it and extrude it out from the outlet of the die head, water-cool it and cut it into pellets to obtain thermoplastic polyimide cable material particles for nuclear power and aviation. Wherein, the melting extrusion temperature of the twin-screw extruder is 300-380° C., and the screw speed is 150 rpm...

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Abstract

The invention relates to a thermoplastic polyimide cable material for nuclear power aviation. The thermoplastic polyimide cable material comprises, by weight, 5-30 parts of polyimide, 5-30 parts of polyetherimide, 30-70 parts of siloxane-containing polyetherimide, 5-30 parts of ether bond-containing polar resin, 5-30 parts of a liquid crystal polymer, 5-30 parts of non-polar crystalline resin, 5-30 parts of silicon resin, 5-20 parts of talcum powder, 0.2-1 part of a processing aid, 0.1-1 part of an antioxidant and 0.1-10 parts of an additive. Different types of polyimide base resins are mixedand used, and the polar resin containing ether bonds, the liquid crystal polymer, the non-polar crystalline resin, the silicon resin, the talcum powder and the like are used to improve the proecsing properties of the material, so the heat resistance and the processing properties are improved, and the radiation resistance, the high flame retardant property, the high insulating property and other comprehensive properties of the base material are also improved; and the cable material can be processed by using traditional thermoplastic cable processing equipment, so the cable processing technologyis simplified.

Description

technical field [0001] The invention relates to a cable material, in particular to a thermoplastic polyimide cable material for nuclear power aviation. Background technique [0002] At present, there are many types and quantities of cable materials used in nuclear power plants on the market, such as cross-linked polyolefin materials, ethylene-propylene rubber, low-smoke halogen-free flame-retardant materials, etc. In order to meet the needs of nuclear-grade cables, these cable materials contain a large amount of resistance Combustion agent, anti-radiation agent, etc., the addition of such a large number of components leads to a decrease in the mechanical properties of the material and an increase in processing difficulty. Cable materials for nuclear power plants must not only have good electrical properties and mechanical and physical properties, but also have excellent heat resistance and radiation resistance. [0003] Polyimide is resistant to high temperature, low temper...

Claims

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Application Information

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IPC IPC(8): C08L79/08C08L83/04C08L81/06C08L23/12C08K13/02C08K3/34C08L71/10C08L67/00C08L23/08C08L23/16C08L61/16C08L23/06C08L81/02H01B3/30
CPCC08L79/08C08L2201/08C08L2203/202C08L2205/025C08L2205/035H01B3/306C08L83/04C08L81/06C08L23/12C08K13/02C08K3/34C08L71/00C08L67/00C08L23/0815C08L23/16C08L61/16C08L23/06C08L81/02
Inventor 何晓东
Owner 中广核高新核材科技(苏州)有限公司
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