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Halogen-free flame-retardant thermoplastic elastomer sheath material and preparation method thereof

A thermoplastic elastomer and sheathing material technology, applied in the direction of plastic/resin/wax insulators, insulators, organic insulators, etc., can solve the problems of dense smoke and molten droplets, threats to life and property, and easy decomposition by heat, etc., to improve flow properties, excellent mechanical properties, and the effect of improving mechanical properties

Inactive Publication Date: 2019-12-03
SHANGHAI KAIBO SPECIAL CABLE FACTORY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since the oxygen index of thermoplastic elastomers is only 18%, thermoplastic elastomers and their blended materials are easy to decompose when heated, and the products are flammable, and will produce thick smoke and molten droplets when burned, which may cause serious fires once ignited Accidents pose a serious threat to human life and property. Therefore, the flame retardancy of the halogen-free thermoplastic elastomer charging pile sheath material has attracted widespread attention.

Method used

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  • Halogen-free flame-retardant thermoplastic elastomer sheath material and preparation method thereof
  • Halogen-free flame-retardant thermoplastic elastomer sheath material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0052] A preparation method of a halogen-free flame-retardant thermoplastic elastomer sheath material, comprising the following steps:

[0053] (1) Fill 20 parts of SEBS with 20 parts of paraffin-based white oil, and let it stand for 15-20 minutes;

[0054] (2) SEBS processed through step (1) and 10 parts of polypropylene T30S, 10 parts of PP grafted maleic anhydride, 5 parts of EPDM rubber, 5 parts of metallocene polyethylene resin, 20 parts of diethyl thiamine Aluminum phosphonate, 15 parts of triazine, 10 parts of polyphenylene ether resin, 0.4 part of antioxidant 1010, 0.1 part of antioxidant DLTP, 0.5 part of lubricating aid EBS and 0.5 part of PE wax are added to the high-speed mixer for mixing ;

[0055] (3) adding the mixture processed in step (2) into a banbury mixer for banburying;

[0056] (4) passing the mixture mixed in step (3) through a twin-screw extruder, and granulating it under the process condition of 160-200° C. to obtain a halogen-free flame-retardant t...

Embodiment 2

[0058] A preparation method of a halogen-free flame-retardant thermoplastic elastomer sheath material, comprising the following steps:

[0059] (1) Fill 20 parts of SEBS with 20 parts of paraffin-based white oil, and let it stand for 15-20 minutes;

[0060] (2) SEBS processed through step (1) and 5 parts of polypropylene T30S, 5 parts of SEBS grafted maleic anhydride, 2 parts of EPDM rubber, 15 parts of polyolefin elastomer, 10 parts of diethylphosphine Aluminum acid, 10 parts of aluminum hypophosphite, 20 parts of melamine cyanurate, 13 parts of hydrotalcite, 5 parts of polyphenylene ether resin, 0.2 parts of antioxidant 1010, 0.1 part of antioxidant CPL, 1 part of silicone lubricant Add 0.5 parts of lubricant additive EBS to the high-speed mixer for mixing;

[0061] (3) adding the mixture processed in step (2) into a banbury mixer for banburying;

[0062] (4) passing the mixture mixed in step (3) through a twin-screw extruder, and granulating it under the process condition...

Embodiment 3

[0064] A preparation method of a halogen-free flame-retardant thermoplastic elastomer sheath material, comprising the following steps:

[0065] (1) Use 10 parts of paraffin-based white oil to fill 30 parts of SEBS, and let it stand for 15-20 minutes;

[0066] (2) SEBS processed through step (1) and 5 parts of polypropylene T30S, 5 parts of SEBS grafted maleic anhydride, 3 parts of EPDM rubber, 7 parts of polyolefin elastomer, 20 parts of aluminum hypophosphite, 20 parts Parts of melamine cyanurate, 11 parts of hydrotalcite, 5 parts of polyphenylene ether resin, 0.5 part of antioxidant 1010 and 2 parts of lubricating additive silicone are added to the high-speed mixer and mixed;

[0067] (3) adding the mixture processed in step (2) into a banbury mixer for banburying;

[0068] (4) passing the mixture mixed in step (3) through a twin-screw extruder, and granulating it under the process condition of 160-200° C. to obtain a halogen-free flame-retardant thermoplastic elastomer she...

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Abstract

The invention relates to a halogen-free flame-retardant thermoplastic elastomer sheath material and a preparation method thereof. The halogen-free flame-retardant thermoplastic elastomer sheath material comprises the following components: a styrene thermoplastic elastomer, polypropylene resin, a compatilizer, filling oil, ethylene-propylene rubber, a flexibilizer, a halogen-free flame retardant, polyphenyl ether resin, a smoke suppressant, an antioxidant and a lubricating aid. The preparation method comprises the following steps: 1) filling the styrene thermoplastic elastomer with the fillingoil; 2) after oil filling is completed, adding the styrene thermoplastic elastomer and other components into a high-speed mixer for mixing; 3) adding the mixture into an internal mixer for internal mixing; and 4) feeding the internally mixed mixture into a twin-screw extruder, and performing stranding and pelletizing at 160-200 DEG C. The halogen-free flame-retardant thermoplastic elastomer sheathmaterial disclosed by the invention is low in processing temperature and low in hardness, has good scratch resistance and flame retardance, still has a cable folding and winding function in a low-temperature environment, is excellent in comprehensive performance, and is suitable for cables for electric automobile charging piles.

Description

technical field [0001] The invention relates to a cable material, in particular to a halogen-free flame-retardant thermoplastic elastomer sheath material and a preparation method thereof. Background technique [0002] With the continuous maturity of new energy vehicle technology, major auto manufacturers at home and abroad have invested in the development and promotion of new energy charging vehicles. With the support of Chinese government policies, new energy vehicles have entered a stage of rapid development. The corresponding new energy vehicles The construction of supporting charging facilities is also the focus of national development. Under the trend of environmental protection, traditional PVC charging pile sheathing materials and halogen-based thermoplastic elastomer sheathing materials have been gradually eliminated, and new environmentally friendly halogen-free thermoplastic elastomer charging pile sheathing materials have become the direction of market development...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L53/02C08L23/12C08L23/16C08L91/06C08L51/06C08L23/06C08L71/12C08K13/02C08K5/3492C08K5/5313H01B3/44
CPCC08L53/025C08L2201/02C08L2201/08C08L2201/22C08L2203/202C08L2205/025C08L2205/035C08L2205/08C08L2207/04H01B3/442C08L23/12C08L23/16C08L91/06C08L51/06C08L23/06C08L71/12C08K13/02C08K5/3492C08K5/5313
Inventor 胡琪杭崔德刚汪晓明
Owner SHANGHAI KAIBO SPECIAL CABLE FACTORY
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