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A hexanuclear dysprosium cluster ring complex single-molecule magnet and its preparation method

A technology of single-molecule magnets and complexes, which is applied in the field of single-molecule magnets of hexanuclear dysprosium cluster ring complexes and its preparation, and can solve the problems of poor repeatability, complex synthesis methods of single-molecule magnets, and low controllability

Active Publication Date: 2022-03-25
HEILONGJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of complex synthesis method, low controllability and poor repeatability in the rare earth complex single-molecule magnet prepared by the existing method

Method used

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  • A hexanuclear dysprosium cluster ring complex single-molecule magnet and its preparation method
  • A hexanuclear dysprosium cluster ring complex single-molecule magnet and its preparation method
  • A hexanuclear dysprosium cluster ring complex single-molecule magnet and its preparation method

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specific Embodiment approach 1

[0020] Embodiment 1: This embodiment is a hexanuclear dysprosium cluster cyclic complex single-molecule magnet whose chemical formula is [Dy 6 (H 2 shi) 6 (2-pyca - ) 12 ], the molecular formula is C 114 H 90 Dy 6 N 18 O 42 ; The hexanuclear dysprosium cluster ring complex single-molecule magnet belongs to the monoclinic crystal system, P21 / c space group, and the unit cell parameters are: a=14.52, b=18.11, α=90°, β=104.07°, γ=90°;

[0021] This embodiment [Dy 6 (H 2 shi)6 (2-pyca - ) 12 ] in H 2 shi is salicylic hydroxamic acid that has lost a proton, 2-pyca is pyridine-2-carboxylic acid, and the structural formula of salicylic hydroxamic acid is The structural formula of pyridine-2-carboxylic acid is

specific Embodiment approach 2

[0022] Specific embodiment 2: This embodiment is: a preparation method of a hexanuclear dysprosium cluster ring complex single-molecule magnet is completed according to the following steps:

[0023] The salicylic hydroxamic acid, pyridine-2-carboxylic acid and Dy(NO 3 ) 3 ·6H 2 O is dissolved in the solvent, and ultrasonicated until the solution is clear to obtain a mixed solution A; in the solution A, salicylic hydroxamic acid, pyridine-2-carboxylic acid and Dy(NO 3 ) 3 ·6H 2 The molar ratio of O is 1:2:1; the volume ratio of the mass of salicylic hydroxamic acid to the solvent in the solution A is (0.0011g~0.0013g): 1mL; the mixed solution A is heated and refluxed for 1h under stirring conditions ~2h, the temperature of heating and refluxing reaction is 90 ℃ ~ 100 ℃ to obtain solution B; pyridine is added to solution B cooled to room temperature, and then heating and refluxing reaction under stirring conditions is 10min ~ 20min, the temperature of heating and refluxing r...

specific Embodiment approach 3

[0026] Embodiment 3: The difference between this embodiment and Embodiment 1 or 2 is that the solvent is a mixture of methanol and acetonitrile, and the volume ratio of methanol and acetonitrile is 1:3. Other steps are the same as in the first or second embodiment.

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Abstract

A single-molecule magnet of a hexanuclear dysprosium cluster ring complex and a preparation method thereof, which relates to a single-molecule magnet and a preparation method thereof. The purpose of the invention is to solve the problems of complex synthesis method, low controllability and poor repeatability in the rare earth complex single-molecule magnet prepared by the existing method. The chemical formula of the hexanuclear dysprosium cluster ring complex single-molecule magnet is [Dy 6 (H 2 sh) 6 (2‑pyca) 6 (2‑pyca ‑ ) 6 ], molecular formula is C 114 h 90 Dy 6 N 18 o 42 . Method: Salicylhydroxamic acid, pyridine‑2‑carboxylic acid and Dy(NO 3 ) 3 ·6H 2 O is dissolved in the solvent, and a mixed solution is obtained by ultrasonication. The mixed solution is heated to reflux, and then pyridine is added to obtain a preform; the solvent is volatilized on the preform to obtain a hexanuclear dysprosium cluster ring complex single-molecule magnet. The invention can obtain a hexanuclear dysprosium cluster ring complex single-molecule magnet.

Description

technical field [0001] The invention relates to a hexanuclear dysprosium cluster ring complex single-molecule magnet and a preparation method thereof. Background technique [0002] Single-molecule magnets (Single–Molecular Magnets, SMMs) are a new type of material between molecular-based magnets and nano-magnetic materials. Because of its potential applications in high-density information processing and storage, quantum computing, molecular spintronics, etc., it has become a research hotspot in the fields of chemistry, physics, and materials science. Among the many branches of single-molecule magnets, lanthanide atoms are [Ln]4f due to their special electronic structure arrangement. n 6s 2 and [Ln]4f n-1 5d 1 6s 2 (n=1–14), reflecting the large number of single electrons of rare earth elements, significant anisotropy, and strong spin-orbit coupling, making it an ideal choice for designing single-molecule magnets. At the same time, it is found that the introduction of s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07F5/00H01F1/42
CPCC07F5/003H01F1/42C07B2200/13
Inventor 高婷孙鸥闫鹏飞李洪峰
Owner HEILONGJIANG UNIV
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