A kind of SBS adhesive and preparation method thereof

An adhesive, SIS1105 technology, applied in the direction of adhesives, adhesive types, conjugated diene adhesives, etc. The effect of enhanced viscosity, improved adhesion, and increased adhesion

Active Publication Date: 2021-01-05
自贡彩灯之乡文化产业集团有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the above-mentioned deficiencies in the prior art, the purpose of the present invention is to solve the problem that the existing adhesives used in the production of colored lanterns have low viscosity, poor stickiness, fast reduction of adhesive strength after gluing, and pollution in low temperature and high humidity environments. To solve environmental problems, we provide a SBS adhesive, which can quickly bond the wire frame and the color lamp cloth of the colored lights under low temperature and high humidity environment, and the stickiness is enhanced. After bonding, the adhesive strength of the adhesive decreases slowly, which can Meet the needs of high-temperature environments and long-term exhibitions, and are low-toxic and environmentally friendly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] S1. Completely dissolve the combined rubber of SBS792, SIS1105 and star-shaped SBSLG411 in mass parts of 4.4:2.9:2.9 in the mixed solvent at room temperature to obtain a mixed solution. Described mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, wherein, toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The mass-to-number ratio is 8.5:0.5:4.9:3.7:38:4.9.

[0028] S2. Add 1.6 parts by mass of oleum with a concentration of 20% to the mixed solution obtained in S1, stir at 35°C to cause sulfonation reaction for 3.5 hours, and add 2.2 parts by mass after the sulfonation reaction is completed. 20% urea methanol solution to reduce and neutralize excess oleum, reduce and neutralize excess oleum.

[0029] S3. Add styrene-butadiene rubber SBR1502 with a mass fraction of 4.2, antioxidant 1010 and tackifier resin with a mass fraction of 0.15 to the sulfonated solution obta...

Embodiment 2

[0031] S1. Completely dissolve the combined rubber of SBS792, SIS1105 and star-shaped SBSLG411 in mass parts of 4.4:2.9:2.9 in the mixed solvent at room temperature to obtain a mixed solution. Described mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, wherein, toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The mass-to-number ratio is 8.5:0.5:4.9:3.7:38:4.9.

[0032] S2. Add 1.2 parts by mass of fuming sulfuric acid with a concentration of 20% to the mixed solution obtained in S1, stir at 35°C for 3 hours, and add 1.8 parts by mass of oleum after the sulfonation reaction is completed. 20% urea methanol solution reduces and neutralizes excess oleum, reduces and neutralizes excess oleum.

[0033] S3. Add 3.5 parts by mass of styrene-butadiene rubber SBR1502, 0.15 parts by mass of antioxidant 1010 and tackifying resin to the sulfonated solution obtained in S2, stir and...

Embodiment 3

[0035]Embodiment 3 is a non-sulfonated SBS adhesive, which is a comparative test. The mass parts are SBS792: SIS1105: star SBS LG411: SBR1502 = 4.4: 2.9: 2.9 combined rubber, the mass parts are terpene resin T-100: C5 petroleum resin: rosin = 9.7: 7.3: 4.3 thickening Resin, 0.15 parts by mass of antioxidant 1010, dissolved in a mixed solvent, and prepared into a non-sulfonated modified SBS adhesive. Wherein, mixed solvent is made up of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride, and the mass parts of toluene, butyl acetate, ethyl acetate, acetone, 6# solvent naphtha and methylene chloride The ratio is 8.5:0.5:4.9:3.7:38:4.9.

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Abstract

The invention discloses an SBS adhesive and a preparation method thereof. The SBS adhesive contains the following components in parts by mass: 9.9-10.5 parts of combined rubber, 57.1-63 parts of a mixed solvent, 1.2-1.8 parts of fuming sulfuric acid, 2.5-4.5 parts of butadiene styrene rubber, 21-21.9 parts of tackifying resin and 0.1-0.2 part of an anti-aging agent. The preparation method of the SBS adhesive comprises the following steps: (S1) completely dissolving the combined rubber into the mixed solvent at the normal temperature, so as to obtain mixed liquid; (S2) adding fuming sulfuric acid into the mixed liquid obtained in the step (S1) to generate sulfonation reaction for 2-4 hours, and adding a urea methanol solution; (S3) adding the butadiene styrene rubber SBR1502, the tackifyingresin and the anti-aging agent, stirring for uniformly dissolving, and filtering, so as to obtain the SBS adhesive. According to the preparation method, metal wire frames of a colored lamp and colored lamp cloth can be rapidly adhered in low-temperature and high-humidity environment, the bonding strength of the adhesive is reduced after the adhesion, the adhesion speed is low, and the SBS adhesive can meet the demands of the high-temperature environment and long-term exhibition and is low in toxin and environment-friendly.

Description

technical field [0001] The invention relates to the technical field of chemical materials, in particular to an SBS adhesive and a preparation method thereof. Background technique [0002] The Zigong Lantern Festival has a long history and has formed an artistic feature of large scale, diverse materials and rich connotations. "Zigong Lantern" has become a well-known brand in China's traditional lantern culture industry. The Zigong Lantern Industry has more than 40,000 employees all year round, and more than 80,000 people in the peak period. The annual output value exceeds 2 billion yuan. It has been exhibited in many countries and regions and more than 500 large and medium-sized cities in China, and the cumulative number of viewers has reached more than 1 billion times. [0003] The manual production process and expression techniques of Zigong lanterns include wire frame welding, butt welding modeling, color separation and pasting, internal light transmission, hand-painted p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J153/02C09J109/06C09J11/08C09J11/06
CPCC08L2205/025C08L2205/035C09J11/06C09J11/08C09J153/025C08L53/025C08L9/06C08L45/00C08L57/02C08L93/04C08K5/1345
Inventor 王大剑万红李新跃朱雅琳柳钦迅李明田
Owner 自贡彩灯之乡文化产业集团有限公司
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