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Ordered mesoporous carbon co-loaded cerium dioxide and binuclear cobalt phthalocyanine material and preparation method thereof

A technology of ceria and nuclear cobalt phthalocyanine, applied in the field of mesoporous materials, can solve the problems of cumbersome operation process, human injury, loss, etc., and achieve the effects of high electrocatalytic activity, loss avoidance and low price

Active Publication Date: 2018-06-29
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the raw materials used in the soft template method are mainly formaldehyde and resorcinol, which are harmful to the human body, and it is easy to cause a lot of losses during the synthesis process, and the operation process is cumbersome.

Method used

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  • Ordered mesoporous carbon co-loaded cerium dioxide and binuclear cobalt phthalocyanine material and preparation method thereof
  • Ordered mesoporous carbon co-loaded cerium dioxide and binuclear cobalt phthalocyanine material and preparation method thereof
  • Ordered mesoporous carbon co-loaded cerium dioxide and binuclear cobalt phthalocyanine material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0044] The preparation of the ordered mesoporous carbon material OMC specifically includes the following steps:

[0045] OMC was prepared by using polyethylene glycol-polypropylene glycol-polyethylene glycol triblock polymer (referred to as P123) as a template and tetraethyl orthosilicate (TEOS) as a silicon source.

[0046] Weigh 4g of P123, 30g of deionized water and 120g of hydrochloric acid (2mol / L) in a beaker and mix them in a beaker, stir for 4 hours under heating in an oil bath at 40°C to make them fully mixed, then add 8.5g of orthosilicic acid dropwise to the mixed solution Ethyl ester, keep the temperature constant and continue to stir for 20 hours; pour the resulting white emulsion into a polypropylene bottle, put it in an oven at 80°C for crystallization for 48 hours; filter the precipitate, wash it with deionized water, and place the solid in Dry in an oven at 60°C for 10 hours; finally put the dried solid into a box-type resistance furnace to raise the temperature...

Embodiment 2

[0050] CeO2-doped ordered mesoporous carbon material 3%CeO 2 The preparation of / OMC (3% is the massfraction that cerium element occupies OMC), specifically comprises the steps:

[0051] OMC was prepared by using polyethylene glycol-polypropylene glycol-polyethylene glycol triblock polymer (referred to as P123) as a template and tetraethyl orthosilicate (TEOS) as a silicon source.

[0052] Mix 4g of P123, 30g of deionized water and 120g of hydrochloric acid (2mol / L) in a beaker, stir for 5 hours under heating in an oil bath at 50°C to make it fully mixed, and then add 8.5g of ethyl orthosilicate dropwise to the mixed solution ester, keep the temperature constant and continue to stir for 18 hours; pour the obtained white emulsion into a polypropylene bottle, put it in an oven at 90°C for crystallization for 50 hours; filter the precipitate, wash it with deionized water, and place the obtained solid in an oven Dry at 70°C for 11 hours; finally put the dried solid into a box-type...

Embodiment 3

[0057] CeO2-doped ordered mesoporous carbon material 6%CeO 2 The preparation of / OMC (6% is the massfraction that cerium element occupies OMC), specifically comprises the steps:

[0058] OMC was prepared by using polyethylene glycol-polypropylene glycol-polyethylene glycol triblock polymer (referred to as P123) as a template and tetraethyl orthosilicate (TEOS) as a silicon source.

[0059] Mix 4g of P123, 30g of deionized water and 120g of hydrochloric acid (1mol / L) in a beaker, stir for 5 hours under heating in an oil bath at 60°C to make it fully mixed, and then add 8.5g of ethyl orthosilicate dropwise to the mixed solution ester, keep the temperature constant and continue to stir for 22 hours; pour the obtained white emulsion into a polypropylene bottle, put it in an oven at 100°C for crystallization for 54 hours; filter the precipitate, wash it with deionized water, and place the obtained solid in an oven Dry at 80°C for 12 hours; finally put the dried solid into a box-typ...

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Abstract

The invention discloses an ordered mesoporous carbon co-loaded cerium dioxide and binuclear cobalt phthalocyanine material and a preparation method thereof. The preparation method comprises the following steps: (1) adding an ordered mesoporous carbon material into de-ionized water, a cerium nitrate solution and a sodium hydroxide solution; mixing and stirring for 3 to 4h; filtering, washing and drying at 100 to 120 DEG C for 1 to 3h; roasting to obtain a cerium dioxide doped ordered mesoporous carbon material; (2) mixing the cerium dioxide doped ordered mesoporous carbon material, de-ionized water and binuclear cobalt phthalocyanine and carrying out ultrasonic treatment for 4 to 6h; drying at 60 to 80 DEG C for 10 to 15h to obtain the ordered mesoporous carbon co-loaded cerium dioxide andbinuclear cobalt phthalocyanine material. The preparation method disclosed by the invention is low in cost; adopted raw materials have no obvious toxicity on human bodies, and influences on a materialmesoporous structure in a synthesis process can be reduced to the greatest extent so that cerium dioxide can be doped into the ordered mesoporous carbon material.

Description

technical field [0001] The invention belongs to the field of mesoporous materials, and in particular relates to an ordered mesoporous carbon co-supported ceria and dinuclear cobalt phthalocyanine material and a preparation method thereof. Background technique [0002] There are 17 rare earth elements in the periodic table, including 15 elements of the lanthanide series plus the closely related elements scandium and yttrium. Cerium (Ce) is the most abundant rare earth element, and it is widely used in solid oxide fuel cells, catalysts, ceramics, and ultraviolet absorption. A prominent feature of cerium is that it can form CeO by releasing and capturing oxygen in an oxygen atmosphere. 2-x Oxide, so that the valence state of cerium element is in Ce 3+ and Ce 4+ Transformation between these compounds leads to the formation of vacancies on the surface of the compound, called "oxygen-deficient sites". It is because of these defect sites that ceria (CeO 2 ) materials have exce...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/90C01B32/05C01F17/00
CPCC01F17/206H01M4/9008H01M4/9016H01M4/9083Y02E60/50
Inventor 王秀军石亚村李白滔
Owner SOUTH CHINA UNIV OF TECH
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