Environment-friendly iminodisuccinic acid chelate metal salt
An iminodisuccinic acid, environment-friendly technology, applied in the field of chemical fertilizers and green fertilizers, can solve the problems of reducing the content of active ingredients, increasing the production process, and the corrosion effect of chloride ions, so as to improve the utilization rate of raw materials and no pollutant discharge. , the effect of reducing production costs
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[0028] The preparation method of metal chelate salt comprises the steps:
[0029] Add 0.8-1.2 molar parts of raw material A and 0.8-1.2 molar parts of raw material B into 20-25 molar parts of solvent, then slowly add 1-2 molar parts of raw material C and stir, and heat to 80-110 ℃, heating and reflux reaction under normal pressure for 25-40 hours, and cooling down to room temperature after the reaction, to prepare iminodisuccinic acid chelated metal salt.
[0030]The dissolving solvent is water, and auxiliary agents can be added when raw materials are added to the solvent, and the auxiliary agent types are any one of ammonia water, polysorbates, polyoxyethylene fatty acid esters, salicylic acid, cresol, and fatty acids. The mixture of one or more kinds promotes the dissolution of raw materials in the solvent, and the added amount of the auxiliary agent is 0.5-1.5% in mass fraction in the solvent.
Embodiment 1
[0032] An environment-friendly iminodisuccinic acid chelated metal salt, comprising the product of raw material A, raw material B and raw material C reaction, raw material A is maleic acid, raw material B is L-aspartic acid, and raw material C is copper hydroxide.
[0033] The preparation method of metal chelate salt comprises the steps:
[0034] The raw material A of 0.8 molar part, the raw material B of 0.8 molar part are added in the water of 20 molar parts, then add ammoniacal liquor, the add-on of ammoniacal liquor is 0.5% of the mass fraction of water, then slowly add the copper hydroxide of 1 molar part and Stir, heat to 80°C after the raw materials are completely dissolved, heat and reflux under normal pressure for 25 hours, cool down to room temperature after the reaction, and prepare iminodisuccinic acid chelated metal salt.
[0035] The iminodisuccinic acid content in the iminodisuccinic acid chelated metal salt is 70%, and the copper ion content is 15%.
[0036] ...
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