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Itaconate/isoprene copolymer type biology base elastomer tread rubber and preparation method thereof

A technology of isoprene and itaconate, applied in special tires, tire parts, transportation and packaging, etc., can solve the problems of high energy consumption, pollution and high price

Active Publication Date: 2015-06-24
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most domestic tire tread rubber is made of natural rubber, styrene-butadiene rubber, and butadiene rubber. Among them, natural rubber resources are scarce and the price is high, while other synthetic rubbers are mainly from petroleum-based raw materials, which have high energy consumption and serious pollution.

Method used

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  • Itaconate/isoprene copolymer type biology base elastomer tread rubber and preparation method thereof
  • Itaconate/isoprene copolymer type biology base elastomer tread rubber and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0042] Dipropyl itaconate monomer was synthesized from itaconic acid and propanol, and then dipropyl itaconate / isoprene copolymer was prepared by emulsion polymerization of dipropyl itaconate monomer and isoprene. Itacon Dipropyl Ester / Isoprene Copolymer Bio-based Engineering Elastomer 100, Zinc Oxide 5, Stearic Acid 1, Antiaging Agent (4020) 1, Antiaging Agent (RD) 1, Silica (VN3) 60, Silane Coupling agent (Si69) 7, carbon black (N330) 5, sulfur 1.5, accelerator (CZ) 1, accelerator (NS) 1, paraffin wax 1.

[0043] Put the dipropyl itaconate / isoprene copolymer bio-based engineering elastomer on the open mixer for 3 minutes, add zinc oxide, stearic acid, and anti-aging agent and mix for 2 minutes, add white carbon black, silane coupling The agent was mixed for 7 minutes. Put one stage of masterbatch into the internal mixer for heat treatment for 8 minutes, the heat treatment temperature is 140°C, the rotor speed is 80r / min, take it out, and usually leave it for 2 hours to obta...

Embodiment 2

[0045] Dibutyl itaconate monomer was synthesized from itaconic acid and butanol, and then dibutyl itaconate / isoprene copolymer was prepared by emulsion polymerization of dibutyl itaconate monomer and isoprene. Itaconic dibutyl ester / isoprene copolymer bio-based engineering elastomer 100, zinc oxide 5, stearic acid 1, antioxidant (4020) 1, antioxidant (RD) 1, white carbon black (VN3) 60, silane Coupling agent (Si69) 7, carbon black (N330) 5, sulfur 1.5, accelerator (CZ) 1, accelerator (NS) 1, paraffin wax 1.

[0046] Put the dibutyl itaconate / isoprene copolymer bio-based engineering elastomer on the open mixer for 3 minutes, add zinc oxide, stearic acid, and anti-aging agent and mix for 2 minutes, add white carbon black, silane coupling The agent was mixed for 7 minutes. Put one stage of masterbatch into the internal mixer for heat treatment for 8 minutes, the heat treatment temperature is 140°C, the rotor speed is 80r / min, take it out, and usually leave it for 2 hours to obta...

Embodiment 3

[0048] Dioctyl itaconate monomer was synthesized from itaconic acid and octanol, and then dioctyl itaconate / isoprene copolymer was prepared by emulsion polymerization of dioctyl itaconate monomer and isoprene. Itaconate / isoprene copolymer bio-based engineering elastomer 100, zinc oxide 5, stearic acid 1, antioxidant (4020) 1, antioxidant (RD) 1, white carbon black (VN3) 60, silane Coupling agent (Si69) 7, carbon black (N330) 5, sulfur 1.5, accelerator (CZ) 1, accelerator (NS) 1, paraffin wax 1.

[0049] Put the dioctyl itaconate / isoprene copolymer bio-based engineering elastomer into the open mixer for 3 minutes, add zinc oxide, stearic acid, and anti-aging agent and mix for 2 minutes, add white carbon black, silane coupling The agent was mixed for 7 minutes. Put one stage of masterbatch into the internal mixer for heat treatment for 8 minutes, the heat treatment temperature is 140°C, the rotor speed is 80r / min, take it out, and usually leave it for 2 hours to obtain the seco...

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Abstract

The invention discloses itaconate / isoprene copolymer type biology base elastomer tread rubber and a preparation method thereof, belonging to the technical field of tires. Every 100 parts of itaconate / isoprene copolymer type biology base elastomer tread rubber can contain 5-40 weight parts of conjugated diene rubber and 60-120 parts of coordination fillers, the above fillers comprise more than 50 parts of silicon dioxide, 1-15 parts of silane coupling agent, 2-6 parts of zinc oxide, 1-3 parts of stearic acid, 1-4 parts of anti-aging agent, 1-4 parts of accelerant, 0-30 parts of fillers except silicon dioxide and 1-3 parts of sulfur. The biology base tire tread rubber is low in rolling obstruction, is proper in abrasion resistance and wet road holding property, and is a novel biology base elastomer 'green tire'.

Description

technical field [0001] The invention belongs to the technical field of tires, in particular to the formulation and processing technology of bio-based engineering elastomer tires based on renewable resources itaconic acid and biomass alcohol as main raw materials. Background technique [0002] The tire industry is a high-pollution and high-energy-consumption industry that relies on petrochemicals. With the massive consumption of non-renewable resources and the gradual improvement of people's awareness of environmental protection, making full use of biomass resources is of great significance to the sustainable development of the global economy and society. The development of biological Basic products are an important part of it. At present, most domestic tire tread rubbers are made of natural rubber, styrene-butadiene rubber, and butadiene rubber. Among them, natural rubber resources are scarce and the price is high, while other synthetic rubbers mainly come from petroleum-bas...

Claims

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Application Information

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IPC IPC(8): C08L35/02C08L7/00C08K13/02C08K3/36C08K3/22C08K5/09B60C1/00
CPCY02T10/86
Inventor 王润国张立群雷巍巍周鑫鑫乔荷姚慧花国智
Owner BEIJING UNIV OF CHEM TECH
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