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Rare-earth/rubber composite material easily subjected to laser engraving

A technology for laser engraving and composite materials, applied in the field of rare earth/rubber composite materials, can solve the problems of reducing the degree of carbonization of the engraving surface, increasing the cost of rubber composite materials, and increasing the cost.

Inactive Publication Date: 2015-02-11
中国印刷科学技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are two conventional methods: one is to reduce the incident power of the laser. This method can ensure that the laser engraving surface is smooth and reduce the degree of carbonization of the engraving surface, but the engraving depth decreases, and the time required for engraving the same depth increases, reducing the processing time. efficiency and increase cost; another method is to fill a large amount of flame-retardant fillers, which can improve the heat resistance of rubber and reduce the degree of carbonization of the engraved surface, but too much filling will cause the performance of rubber materials to decline and improve the performance of rubber. The cost of composite materials, and in order to achieve a good engraving effect, it is necessary to increase the power of the incident laser, which increases the cost of the equipment
Both approaches will reduce the absorption rate of the laser, and at the same time increase the product cost to a large extent

Method used

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  • Rare-earth/rubber composite material easily subjected to laser engraving
  • Rare-earth/rubber composite material easily subjected to laser engraving
  • Rare-earth/rubber composite material easily subjected to laser engraving

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] At room temperature, wrap 100 parts of natural rubber on double rollers on the rubber mixer, then add 5 parts of zinc oxide and 2 parts of stearic acid in sequence, and mix for 0.5 minutes; then add 0.5 parts of anti-aging agent RD, and add anti-aging agent 4010NA to 0.5 1 part, mixed for 2 minutes; then add 1 part of VN3 white carbon black, 1 part of N220 carbon black and 0.5 part of Si69 in batches, then mix for 5 minutes, then add 1 part of chlorinated paraffin, mix for 0.5 minutes, then add 1 part of nano-lanthanum oxide, and then knead for 0.5 minutes, and finally add 1.5 parts of accelerator CZ and 3 parts of sulfur into the open mill, thin pass 5 times, and then stop for 4 hours, then re-mill for 5 minutes and vulcanize molding get composites.

[0028] The accelerator CZ is N-cyclohexyl-2-benzothiazole sulfenamide; Si69 is bis(triethoxysilylpropyl) tetrasulfide; antioxidant RD is 2,2,4-trimethyl -1,2-dihydroquinoline polymer (belongs to ketone-amine reaction pro...

Embodiment 2

[0030]At room temperature, wrap 100 parts of natural rubber on double rollers on the rubber mixer, then add 5 parts of zinc oxide and 2 parts of stearic acid in sequence, and mix for 0.5 minutes; then add 4 parts of anti-aging agent RD, add anti-aging agent 4010NA to 5 and 1 part of protective wax, mixed for 5 minutes; then add 10 parts of VN3 silica, 10 parts of carbon nanotubes and 10 parts of N234 carbon black and 4 parts of Si69, and then add 10 parts of brominated epoxy resin , 10 parts of alumina and 5 parts of red phosphorus, then mixed for 10 minutes, added 10 parts of nano-cerium oxide, and mixed for 2 minutes, and finally added 1.5 parts of accelerator CZ, 0.2 parts of accelerator TT and Sulfur 3 parts, thin pass 5 times, and then park for 4 hours, then re-mill for 5 minutes and vulcanize to obtain a composite material.

[0031] The accelerator TT is tetramethylthiuram disulfide; the protective wax is a kind of anti-aging agent, which plays the role of anti-ozone agi...

Embodiment 3

[0033] At room temperature, wrap 100 parts of natural rubber on double rollers on the rubber mixer, then add 4 parts of zinc oxide and 1 part of stearic acid in sequence, and mix for 0.5 minutes; then add 4 parts of antioxidant MB, and add antioxidant 445 to make 5 and 4 parts of protective wax, mix for 5 minutes; then add 50 parts of T383 white carbon black, 5 parts of nylon staple fiber and 4 parts of Si75 in batches, then mix for 10 minutes, then add 20 parts of hydrotalcite and 2 parts Then add 5 parts of nano-cerium oxide, 5 parts of nano-neodymium oxide, 10 parts of nano-gadolinium carbonate, 10 parts of nano-lanthanum hydroxide and 20 parts of nano-samarium nitrate, mix for 5 minutes, and then add 5 parts 1 part of paraffin oil, kneaded for 10 minutes, finally added 1.5 parts of accelerator DM, 3 parts of accelerator DTDM and 2 parts of sulfur in the open mill, thinly passed 5 times of sheeting, then parked for 4 hours, and then re-milled for 5 Minutes and vulcanization...

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PUM

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Abstract

The invention relates to a rare-earth / rubber composite material easily subjected to laser engraving. The rare-earth / rubber composite material easily subjected to laser engraving, provided by the invention, has the advantages that the quality of laser engraving can be guaranteed, the speed of engraving can be increased, the cost is reduced, and the absorption rate of laser is increased. The composite material is mainly prepared from the following ingredients in parts by weight: 100 parts of rubber, 1-200 parts of inorganic nano rare-earth compound, 0.5-80 parts of coupling agent, 0-10 parts of zinc oxide, 0-10 parts of stearic acid, 0-100 parts of reinforcing filler, 0-200 parts of flame retardant, 0-200 parts of flame-retardant synergist, 0.1-15 parts of cross-linking agent, 0-20 parts of accelerant, 0-20 parts of anti-aging agent and 0-100 parts of plasticizer, wherein the inorganic nano rare-earth compound is one or a randomly-proportioned mixture of more than two of nano rare-earth oxide, nano rare-earth chloride, nano rare-earth sulfide, nano rare-earth carbonate, nano rare-earth nitrate, nano rare-earth sulfate and nano rare-earth hydroxide, and rare-earth elements are selected from scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.

Description

technical field [0001] The invention relates to a rare earth / rubber composite material that is easy to laser engrave. It is used to prepare a rare earth / rubber composite material that is easy to laser engrave. Medical treatment, etc., this kind of industry must involve laser engraving technology in the process of use. Background technique [0002] Laser has the advantages of good directionality, high energy density, and good monochromaticity, and is very suitable for material processing, so it has always been valued by scientific research and industry. [0003] Laser engraving refers to the use of laser beams to act on materials to cause changes in the shape or properties of samples. It is a high-power-density spot formed by focusing the laser beam. Within a few microseconds, the temperature of the spot area rises to the melting point or even the boiling point of the material, so that the material at the irradiated place is melted, vaporized, ablated or reached the ignition...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08K13/02C08K3/22C08K3/26C08K3/28C08K3/30C08L23/16C08L33/04C08L9/02C08K3/16C08L15/00C08L9/06C08L23/22C08L9/00C08K13/06
CPCC08L7/00C08K3/02C08K3/04C08K3/06C08K3/22C08K3/36C08K5/12C08K13/02C08K2003/026C08K2003/221C08K2003/2224C08K2003/2227C08K2201/011C08K2201/014C08L9/00C08L9/02C08L9/06C08L15/00C08L23/16C08L23/22C08L33/04C08L2205/02C08L2205/03C08L2205/035C08L2205/16
Inventor 张法忠褚庭亮欧阳芸张竞
Owner 中国印刷科学技术研究院有限公司
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