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Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof

A solar photovoltaic and acrylate technology, applied in photovoltaic power generation, chemical instruments and methods, adhesives, etc., can solve problems such as unseen technical inspiration and unheard commercial success reports, etc., and meet process requirements and equipment. Not harsh, simple craftsmanship, ideal weather resistance

Active Publication Date: 2010-08-04
江苏明昊新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the published literature, there is no technical inspiration that can be used for reference, and there is no report of commercial success

Method used

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  • Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof
  • Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof
  • Sealant for acrylic ester modified solar photovoltaic module and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A) prepare the base material, 90 parts of α, ω-dihydroxy polydimethylsiloxane, 10 parts of methyl methacrylate and the chemical compound prepared by Changshu Institute of Technology, Jiangsu Province, China are preferably prepared according to the weight ratio or parts by weight. The brand LGHC-A type cadmium telluride mixed catalyst developed with the School of Materials Engineering and sold to the outside world is 0.5 parts of the catalyst A defined in the present invention, which is added to the vacuum kneader for kneading. The temperature is controlled at 120°C, the kneading time is controlled at 120min, and 100.5 parts of the base material are obtained;

[0036] B) prepare sealant, earlier by the base material 100.5 parts that step A) obtains, process through resin acid and be the activated calcium carbonate 20 of XL-3 type by the trade mark that China Henan Province Keli New Material Co., Ltd. produces and sells Parts, 40 parts of silica powder with a particle siz...

Embodiment 2

[0038] A) Prepare the base material, mix 90 parts of α, ω-dihydroxypolydimethylsiloxane, methyl acrylate, ethyl acrylate, and butyl acrylate in a ratio of 4:4:5 Proportioning, a total of 13 parts and preferably developed by the School of Chemistry and Materials Engineering, Changshu Institute of Technology, Jiangsu Province, China and sold to the outside world is LGHC-A type cadmium telluride mixed catalyst, that is, 0.7 parts of catalyst A defined in the present invention are added to the vacuum kneading Kneading in the machine, the vacuum degree of the vacuum kneader is controlled at 0.09MPa, the kneading temperature is controlled at 130°C, and the kneading time is controlled at 150min to obtain 103.7 parts of the base material;

[0039] B) prepare sealant, earlier by the base material 103.7 parts that step A) obtains, through resin acid treatment and the brand that is produced and sold by Henan Keli New Material Co., Ltd., Henan Province, China is the active calcium carbonat...

Embodiment 3

[0041] A) Preparation of base material, 90 parts of α, ω-dihydroxy polydimethylsiloxane, ethyl methacrylate, butyl methacrylate, glycidyl methacrylate Esters are in a ratio of 1:1:1, a total of 12 parts and preferably developed by the School of Chemistry and Materials Engineering, Changshu Institute of Technology, Jiangsu Province, China and sold externally as LGHC-A type cadmium telluride mixed catalyst, which is catalyst A as defined in the present invention. .6 parts were added to a vacuum kneader and kneaded. The vacuum degree of the vacuum kneader was controlled to be 0.08MPa, the kneading temperature was controlled to be 125°C, and the kneading time was controlled to be 145min to obtain 102.6 parts of base material;

[0042] B) prepare sealant, earlier by the base material 102.6 parts that step A) obtains, process through resin acid and be the activated calcium carbonate 25 of XL-3 type by the trade mark that China Henan Province Keli New Material Co., Ltd. produces and s...

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Abstract

The invention relates to a sealant for acrylic ester modified solar photovoltaic module and a preparation method thereof. The sealant is prepared from the following raw materials in parts by weight: 90 parts of alpha, omega-dihydroxy polydimethyl siloxane, 10-15 parts of acrylic ester, 0.5-0.8 part of catalyzer A, 0.8-1.2 parts of catalyzer B, 20-30 parts of activated calcium carbonate, 25-60 parts of silicon powder, 4-6 parts of fumed silica, 11-15 parts of crosslinking agents, 2-3 parts of silane coupling agents and 5-8 parts of plasticizer. The invention has the advantages that the permeation of water vapor can be inhibited effectively, and the permeation rate of the water vapor is less than 1; due to the adoption of ester modification by acrylic ester, no monomer is separated in the process of solidification and after solidification; the resistance to weather and corrosion is ideal; and the process of the recommended preparation method is simple, which is not strict on process requirements and equipment.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a sealant for acrylate-modified solar photovoltaic modules, and also relates to a preparation method of the sealant. Background technique [0002] Solar photovoltaic modules are also called solar cell modules. The sealants used for solar photovoltaic modules have been reported in Chinese patent documents, including two-component and single-component sealants. The condensation-type two-component sealant disclosed in CN1528821A, the one-component sealant such as the one-component silicone sealant for solar cell modules introduced in the invention patent application publication number CN101353563A and its preparation method. [0003] The aforementioned latter patent application has pointed out the deficiency of the previous patent application (the 7th-9th line of the background technology column on the first page of the description of CN101353563A), and is also...

Claims

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Application Information

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IPC IPC(8): C09K3/10C09J4/06C09J183/06H01L31/0203H01L31/049
CPCY02E10/50
Inventor 韩仁明王益昌费志刚
Owner 江苏明昊新材料科技股份有限公司
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