High-toughness cadmium-free silver solder and preparation method thereof
A silver solder, high-strength technology, applied in the field of high-strength and tough cadmium-free silver solder and its preparation, can solve the problems of low toughness and fatigue strength, high brazing temperature, containing harmful elements, etc., and achieves good fatigue resistance and brazing. Low temperature, good environmental protection effect
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Embodiment 1
[0020] a, by weight percentage: Ag: 25%; Cu: 32%; Zn: 35%; Ni: 2%; Co: 1%; Mn: 4.75%; B: 0.01%; Nb: 0.01%; V: 0.01 %; Ce: 0.06%; La: 0.09%; Sr: 0.07%;
[0021] B, smelting refractory metal nickel Ni, cobalt Co, vanadium V, niobium Nb and copper Cu respectively to form master alloys A1, A2, A3, A4; Described master alloy A1 is made up of Cu50:Ni50 of weight ratio; The master alloy A2 is composed of Cu70:Co30 by weight ratio; the master alloy A3 is composed of Cu97:V3 by weight ratio; the master alloy A4 is composed of Cu98:Nb2 by weight ratio;
[0022] c, smelting easily oxidizable metals boron B, cerium Ce, lanthanum La, strontium Sr and copper Cu in a vacuum furnace into master alloys B1, B2, B3 respectively; said master alloy B1 is composed of Cu86:B14 in weight ratio; The master alloy B2 is composed of Cu80: La12+Ce8 in weight ratio; the master alloy B3 is composed of Cu80: Sr20 in weight ratio;
[0023] d. Melt the silver and the remaining copper in the intermediate freq...
Embodiment 2
[0027] a, by weight percentage: Ag: 30%; Cu: 26%; Zn: 34%; Ni: 2%; Co: 2%; Mn: 5.8%; B: 0.01%; V: 0.01%; Sr: 0.08 %; Ce: 0.04%; La: 0.06%;
[0028] B, high-melting point metal nickel Ni, cobalt Co, vanadium V are smelted with copper Cu respectively to form master alloy A1, A2, A3; Described master alloy A1 is made up of Cu50:Ni50 of weight ratio; Described master alloy A2 is made up of The composition of Cu70: Co30 of weight ratio; The master alloy A3 is composed of Cu97: V3 of weight ratio;
[0029]c, smelting easily oxidizable metals boron B, cerium Ce, lanthanum La, strontium Sr and copper Cu in a vacuum furnace into master alloys B1, B2, B3 respectively; said master alloy B1 is composed of Cu86:B14 in weight ratio; The master alloy B2 is composed of Cu80:La12+Ce8 in weight ratio; the master alloy B3 is composed of Cu80:Sr20 in weight ratio.
Embodiment 3
[0031] According to weight percentage: Ag: 35%; Cu: 22%; Zn: 32.5%; Ni: 1.5%; Co: 2%; Mn: 6.74%; B: 0.01%; Nb: 0.01%; Ce: 0.06%; La: 0.09%; Sr: 0.09%;
[0032] b. Melting high-melting-point metal nickel Ni, cobalt Co, niobium Nb and copper Cu into master alloys, and melting high-melting-point metal nickel Ni, cobalt Co, niobium Nb and copper Cu into master alloys A1, A2, A4 respectively; The master alloy A1 is composed of Cu50:Ni50 by weight ratio; the master alloy A2 is composed of Cu70:Co30 by weight ratio; the master alloy A4 is composed of Cu98:Nb2 by weight ratio;
[0033] c, smelting easily oxidizable metals boron B, cerium Ce, lanthanum La, strontium Sr and copper Cu in a vacuum furnace into master alloys B1, B2, B3 respectively; said master alloy B1 is composed of Cu86:B14 in weight ratio; The master alloy B2 is composed of Cu80:La12+Ce8 in weight ratio; the master alloy B3 is composed of Cu80:Sr20 in weight ratio.
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