Diblock copolymer containing full-fluorine cyclobutyl aryl aether block and uses thereof
A technology of perfluorocyclobutyl aryl ether and block copolymer, which is applied in the field of two-block polymers and can solve the problems of difficulty in preparing block copolymers, limitations in design and synthesis, etc.
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Embodiment 1
[0055] The synthesis of embodiment 1.poly-tert-butyl acrylate 3
[0056]
[0057] After the reaction tube was baked dry with gas fire and the nitrogen was replaced, cuprous bromide (39.2 mg, 0.28 mmol) was added, and the nitrogen was replaced three times. After tert-butyl acrylate (4.0 mL, 27.6 mmol), PMDETA (0.06 mL, 0.28 mmol) and anisole (1 mL) were added to the reaction tube, the reaction system was frozen with liquid nitrogen, vacuumized for 5 minutes, and thawed with nitrogen gas. After repeating three times, methyl 2-bromopropionate (0.06mL, 0.55mmol) was added, frozen again-vacuumized-nitrogen-filled thawed three times, put into an oil bath at 70°C and stirred for 2h. Put the reaction tube into liquid nitrogen to freeze and quench the reaction, add THF to dissolve, and pass through a neutral alumina column to remove copper salt. After the solvent was removed by rotary evaporation, 5 mL of THF was added to dissolve, precipitated in cold n-hexane, and filtered by suc...
Embodiment 2
[0061] Example 2. Polytert-butyl acrylate-b-polymethacrylic acid
[0062] Synthesis of (4-((2-(4-methylphenoxy))hexafluorocyclobutoxy))phenyl ester diblock polymer 5
[0063]
[0064] After drying the reaction tube with gas fire and replacing the nitrogen, polymer 3 (525mg, 0.04mmol, M n = 12,500 g / mol, M w / M n =1.10), monomer 4 (0.7mL, 2.1mmol) and CuBr (6mg, 0.04mmol) were added to the reaction tube, and the nitrogen was replaced three times. After adding 1 mL of anisole, freeze with liquid nitrogen, vacuumize for 5 minutes, and fill with nitrogen to thaw. After repeating three times, PMDETA (0.017mL, 0.084mmol) was added, and then frozen-pumped-nitrogen gas was thawed three times, and then placed in an oil bath at 70°C and stirred for 24h. Put the reaction tube into liquid nitrogen to freeze and quench the reaction, add THF to dissolve, and pass through a neutral alumina column to remove copper salt. After the solvent was removed by rotary evaporation, 1 mL THF was...
Embodiment 3
[0069] Embodiment 3. the synthesis of polyethylene oxide macroinitiator 6
[0070]
[0071] Polyethylene oxide (5g, 2.5mmol, M n =2,000g / mol) into a dry three-necked flask, dissolved in freshly distilled dichloromethane (150mL), added triethylamine (1.5mL, 12.5mmol), and placed in an ice-water bath. 2-Bromopropionyl chloride (1.3 mL, 12.5 mmol) was slowly added dropwise, and stirred for 2 h after the addition was complete. The generated salt was removed by suction filtration, the solvent was removed by rotary evaporation, dissolved in 20 mL of THF, precipitated three times in cold ether, and dried in vacuum to obtain 4.23 g of a white powdery polymer.
[0072] FT-IR (KBr): v (cm -1 ) 2929, 1751, 1610, 1503, 1318, 1197, 1104, 962, 818.
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