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Preparation of carbon fiber reinforced carbon-silicon carbide double matrix friction material

A technology of silicon carbide double and friction materials, applied in friction linings, mechanical equipment, etc., can solve the problems of low material density, large density gradient, poor material performance, etc. performance effect

Active Publication Date: 2013-03-20
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chemical vapor infiltration is one of the most promising methods for preparing fiber-reinforced ceramic matrix composites. Its notable feature is that it can be prepared at a lower temperature, but the preparation of thick-walled parts is prone to "bottleneck" effects. A large density gradient is generated inside the material, and the process preparation cycle is long and the cost is high
The polycarbosilane conversion method does not require special equipment, and the process is relatively simple, but the amorphous matrix obtained by this method has poor material properties
The molten silicon impregnation method has a short preparation cycle and low cost, but the molten silicon is easy to react with the carbon fiber during the impregnation process and cause damage to it, resulting in low mechanical properties. Therefore, other methods are generally used to prepare the carbon fiber in the material after the protective layer Silicon carbide matrix was prepared by molten silicon impregnation method
The temperature-pressing-in-situ reaction method has a short preparation cycle and low cost, and the prepared C / C-SiC friction material has a high friction coefficient, but the material has low density, low mechanical properties, and poor toughness

Method used

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  • Preparation of carbon fiber reinforced carbon-silicon carbide double matrix friction material
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  • Preparation of carbon fiber reinforced carbon-silicon carbide double matrix friction material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] (1) Adopting the PAN type T700 (12K) chopped carbon fiber with a length of 15mm produced by Japan Toray Corporation (Toray), the graphite powder with a particle size of 0.1mm, the industrial silicon powder with a particle size of 0.05mm and the graphite powder with a particle size of 0.2mm Phenolic resin powder is the raw material. The volume content of the raw materials is 18% carbon fiber, 35% graphite powder, 7% industrial silicon powder and 40% phenolic resin powder. After mixing them, they are cold pressed at room temperature to form a density of 1.15g / cm 3 The C / C-Si block, the pressure is 2.0Mpa, and the holding time is 15min;

[0031] (2) Mechanically crush and granulate the C / C-Si block to obtain 70-80% of the C / C-Si particles whose particle size is mainly distributed between 5-15 mm, and the appearance of the particles is irregular ;

[0032] (3) Preheat the C / C-Si particles in step (2) at 120°C in an oven and keep it warm for 1.0h;

[0033] (4) Put the preh...

Embodiment 2

[0042] (1) Use PAN type XK-24 (24K) chopped carbon fiber with a length of 2mm produced by Dalian Xingke Carbon Fiber Co., Ltd., graphite powder with a particle size of 0.2mm, industrial silicon powder with a particle size of 0.05mm and a particle size of 0.05 mm of furan resin powder. The volume content of raw materials is 15% carbon fiber, 45% graphite powder, 10% industrial silicon powder and 30% phenolic resin powder, which are mixed and cold pressed at room temperature to form a density of 1.30g / cm 3 The C / C-Si block, the pressure is 2.0Mpa, and the holding time is 5min;

[0043] (2) Mechanically crush and granulate the C / C-Si block to obtain 70-80% of the C / C-Si particles whose particle size is mainly distributed between 5-15 mm, and the appearance of the particles is irregular ;

[0044] (3) Evenly spread the C / C-Si particles in step (2) and preheat in an oven at 100°C for 1.0h;

[0045] (4) Put the preheated C / C-Si particles into the mold and warm press to a density ...

Embodiment 3

[0053] (1) Adopting the PAN type T700 (12K) chopped carbon fiber, the graphite powder with a particle size of 0.075mm and the epoxy resin powder with a particle size of 0.01mm as the raw materials for the length of 15mm produced by Japan's Toray Corporation (Toray), the raw material The volume content is 10% carbon fiber, 35% graphite powder and 25% phenolic resin powder, which are mixed and cold pressed at room temperature to form a density of 1.10g / cm 3 The C / C-Si block, the pressure is 5.0Mpa, and the holding time is 10min;

[0054] (2) Mechanically crush and granulate the C / C-Si block to obtain 70-80% of the C / C-Si particles whose particle size is mainly distributed between 5-15 mm, and the appearance of the particles is irregular ;

[0055] (3) Preheat the C / C-Si particles in step (2) at 80°C in an oven and keep it warm for 1.5h;

[0056] (4) Put the preheated C / C-Si particles into the mold and warm press to a density of 1.40g / cm 3 The C / C-Si biscuit, the pressing pres...

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Abstract

The invention discloses a preparation method for a carbon fiber enhanced carbon-carborundum double-matrix abrasive material. Short chopped carbon fiber, graphite powder, industrial silicon powder and caking agent are employed to be pressed into the block material of carbon fiber enhanced graphite powder and silicon powder (C / C-Si) in a cooling way; then mechanical cracking and pelleting are carried out to the prepared C / C-Si block material; next, the grains are thermally pressed into a C / C-Si biscuit; and then the C / C-Si biscuit is carbonized to prepare a C / C-Si porous body; and finally non-dipping directional fused silica impregnating is carried out to the C / C-Si porous body to prepare the carbon fiber enhanced carbon-carborundum double-matrix (C / C-SiC) abrasive material. The invention relates to a preparation method for a carbon fiber enhanced carbon-carborundum double-matrix abrasive material having higher mechanical property and excellent abrasion resistance and wear performances, with the advantages of short preparation cycle, low cost, and being capable of engineering.

Description

technical field [0001] The invention relates to a preparation method of carbon fiber reinforced carbon-silicon carbide double-matrix (C / C-SiC) friction material, specifically a "warm pressure-carbonization-melting silicon impregnation" process, which can be used to prepare high-performance C / C-SiC friction material. Background technique [0002] Carbon fiber reinforced carbon-silicon carbide double matrix (C / C-SiC) composite material is a new generation of high-performance friction material developed at the end of the 20th century. It has a series of excellent properties such as low density, anti-oxidation, corrosion resistance, high and stable friction coefficient, small wear, large braking specific pressure, small volume of braking system and good thermal conductivity, etc., especially can overcome the static state of C / C braking materials. And the shortcomings of low friction coefficient in wet state can guarantee the braking safety of power machinery at high speed and h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/80C04B35/52C04B35/565C04B35/622F16D69/02
Inventor 肖鹏李专韩团辉熊翔
Owner CENT SOUTH UNIV
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