Technique for treating synergism coat of aluminium alloy material and fluorine polymer
A technology of aluminum alloy materials and fluoropolymers, applied in the direction of coating, pretreatment surface, surface reaction electrolytic coating, etc., can solve the problems of high friction coefficient, poor corrosion resistance, difficulty in lubrication, etc., and achieve good matting performance, The possibility of carbonization and decomposition is small, and the effect of not being easily deformed
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example 1
[0027] Example 1: The aluminum alloy material is a 7A04T6 test plate, 50mm×50mm×3mm, polished to a surface roughness of Ra1.6~Ra0.8, spare; or samples of aluminum alloy parts for optoelectronic instruments that need to be processed. ① Degreasing the sample with alkaline degreasing solution at 60~75℃ for 5~10min; rinsing with tap water for 30S and running water cleaning for 15S; then etching and washing at 60~75℃ for 2~5min in 40~50g / l sodium hydroxide solution, Remove the oxide film on the surface of aluminum alloy; rinse with tap water for 30S, rinse with running water for 30S; ②Acid pickling treatment in 20-30% nitric acid liquid for 2-10min at room temperature to remove the ash and residue on the surface caused by etching; rinse with tap water for 30S , Running water cleaning for 15S; ③Hard anodizing treatment: Carry out hard anodizing treatment according to the hard anodizing bath and process conditions given in Table 1; the thickness of the film is controlled at 20-50μm, and ...
example 2
[0032] Example 2: Prepare hard anodized samples according to the process given in Example 1; carry out electrochemical AC reaming treatment according to the reaming solution and process conditions given in Table 2; rinse with tap water for 30S and wash with running water for 15S; use after reaming Dry in cold air for later use.
[0033] Composition of electrochemical hole expanding solution
Reaming process conditions
Material
Content (g / l)
Electrochemical reaming: the workpiece is the anode and the cathode is
Lead plate, temperature 20~25℃, voltage 8~15V,
Time 5min;
Phosphoric acid (85%)
150
20
[0034] After reaming, the surface is uniformly brown to black, with no ash, no film loss, and no corrosion on the substrate. The pores on the surface are uniform, clear and neatly arranged by scanning electron microscope microscopic analysis.
[0035] Hot dipping fluoropolymer and vacuum precision heat tr...
example 3
[0037] Example 3: Prepare hard anodized samples according to the process given in Example 1; chemically expand the hole in 100g / l sulfuric acid expansion solution, the process conditions are 20~25℃, 5min; rinse with tap water for 30S, rinse with running water 15S; After reaming, blow dry with cold air for use.
[0038] After reaming, the surface is uniformly brown to black, with no ash, no film loss, and no corrosion on the substrate. The pores on the surface are uniform, clear and neatly arranged by scanning electron microscope microscopic analysis.
[0039] Hot dipping fluoropolymer and vacuum precision heat treatment: the hard anodized reamed sample is hot dipped in 70g / l polytetrafluoroethylene emulsion solution at 80~90℃ for 15min, taken out and dried in the air, then put into heat treatment In the furnace, treat at 370-380°C for 60 minutes under a vacuum of 0.5-0.05 Pa. After cooling to a temperature below 150°C, close the vacuum system, take out the sample and cool it to ro...
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