Preparation method of waterproof suit fabric
A technology for fabrics and suits, which is applied in the field of preparation of waterproof suit fabrics, can solve the problems of destroying the molecular structure of water-based polyurethane, affecting the performance of the coating, and decreasing the mechanical strength, and achieves the effects of easy control, improved waterproofness and less side reactions.
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Embodiment 1
[0040] Preparation of polyether diols:
[0041] Add 50g of phthalic anhydride, 25g of 1,3-propanediol and 1g of DMC catalyst into the reaction flask, raise the temperature to 100°C for dehydration under reduced pressure for 0.5h, then replace with nitrogen for 3 times, then add 30g of propylene oxide after raising the temperature to 120°C , reacted for 6h, and removed small molecular impurities under reduced pressure to obtain polyether diol.
Embodiment 2
[0043] Preparation of fluorine-containing silicone oil:
[0044] Under nitrogen protection, add 1g of ethylenediamine and 0.5g of deionized water into the reaction flask, heat to 50-60°C and stir for 0.5h, then add 100g of trifluoropropylmethylcyclotrisiloxane (D3F) and heat up to 110°C, react for 6 hours, and remove water and ethylenediamine under reduced pressure to obtain fluorine-containing silicone oil.
Embodiment 3
[0046] Preparation of modified polyurethane emulsion:
[0047] A1. Under the protection of nitrogen, add 50g of polyether diol into the reaction flask, heat to 60°C, and add 80g of isophorone diisocyanate dropwise, then raise the temperature to 90°C, and keep it warm for 2 hours to obtain Polymer 1;
[0048] A2. Under nitrogen protection, add 5g of dimethylolpropionic acid, 5g of 1,4-butanediol and 1g of stannous octoate to Polymer 1, raise the temperature to 75°C, and keep warm for 5 hours to obtain Polymer 2;
[0049] A3. Under the protection of nitrogen, the temperature of Polymer 2 was lowered to 60°C, and 15g of fluorine-containing silicone oil was added to the reaction bottle, reacted for 3 hours, and then 10g of acetone was added to obtain Polymer 3;
[0050] A4. Under the protection of nitrogen, lower the temperature of Polymer 3 to 35°C, add 5g of triethylamine, stir for 0.5h, then dropwise add 200g of deionized water, and continue stirring for 2h to obtain modified p...
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