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A kind of geopolymer-based antibacterial coating and its preparation method and application

An antibacterial coating and geopolymer technology, applied in anti-corrosion coatings, antifouling/underwater coatings, coatings, etc., can solve the problems of restricting the development of new coatings, complex molecular design and synthesis process, etc., to achieve excellent antibacterial properties, Break through the effect of high brittleness and excellent flexibility

Active Publication Date: 2020-09-22
东莞微积分新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above-mentioned coatings are generally based on organic coating systems. In terms of environmental protection and low toxicity, the above-mentioned coatings are difficult to compare with inorganic geopolymer coatings.
On the other hand, organic coatings with both anti-corrosion and anti-bacterial functions often require complex molecular design and synthesis processes, which limits the development of this new type of coating.

Method used

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  • A kind of geopolymer-based antibacterial coating and its preparation method and application
  • A kind of geopolymer-based antibacterial coating and its preparation method and application
  • A kind of geopolymer-based antibacterial coating and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] (1) In the reaction vessel, add 15 parts by weight of octafluoropentyl acrylate, 15 parts by weight of hexafluorobutyl methacrylate, 10 parts by weight of isothiazolinone acrylate, 10 parts by weight of capsaicin acrylate, 20 parts by weight Carboxylic acid betaine methacrylate, 19.9 parts by weight of mercaptomethyltrimethoxysilane, 10 parts by weight of toluene, 0.1 part of azobisisobutyronitrile, reacted for 48 hours under an inert gas atmosphere at 60 ° C, and removed the solvent to obtain antibacterial Telomers.

[0049] (2) Mix 56 parts by weight of metakaolin, 5 parts by weight of titanium dioxide, 10 parts by weight of zinc oxide, 18 parts by weight of glass flakes, and 11 parts by weight of heavy calcium carbonate to obtain component A. Mix 45 parts by weight of sodium water glass with a modulus of 0.8, 15 parts by weight of sodium hydroxide, 0.5 parts by weight of bentonite, and 39.5 parts by weight of water to obtain component B. Mix 77 parts by weight of an...

Embodiment 2

[0052] (1) In the reaction vessel, add 20 parts by weight of tetrafluoropropyl acrylate, 20 parts by weight of octafluoropentyl methacrylate, 30 parts by weight of nonafluorohexyl methacrylate, 0.5 parts by weight of polyethylene glycol acrylate, 0.5 parts by weight of bromopyrrole nitrile acrylate, 8.3 parts by weight of mercaptomethyltrimethoxysilane, 10 parts by weight of ethyl acetate, 10 parts by weight of acetone, and 0.7 parts by weight of phosphazene, reacted for 48 hours at 50 ° C under an inert gas atmosphere, Removal of the solvent yields the antibacterial telomer.

[0053] (2) Mix 40 parts by weight of fly ash, 4 parts by weight of carbon black, 15 parts by weight of cuprous oxide, 15 parts by weight of micaceous iron oxide, and 11 parts by weight of heavy calcium carbonate to obtain component A. Mix 57 parts by weight of sodium water glass with a modulus of 1.2, 7 parts by weight of potassium hydroxide, 3.1 parts by weight of bentonite, and 32.9 parts by weight of...

Embodiment 3

[0056] (1) In the reaction vessel, add 20 parts by weight of nonafluorohexyl acrylate, 20 parts by weight of carboxybetaine acrylate, 20 parts by weight of isothiazolinone methacrylate, 19.95 parts by weight of mercaptomethyltriethoxy Silane, 20 parts by weight of xylene, and 0.05 parts by weight of azobisisovaleronitrile were reacted at 80°C for 24 hours under an inert gas atmosphere, and the solvent was removed to obtain an antibacterial telomer.

[0057] (2) Mix 63 parts by weight of diatomite, 10 parts by weight of cement, 9 parts by weight of titanium dioxide, 7 parts by weight of zinc oxide, and 11 parts by weight of glass flakes to obtain component A. Mix 40 parts by weight of potassium silicate with a modulus of 1.7, 12.5 parts by weight of sodium hydroxide, 2.5 parts by weight of bentonite and 45 parts by weight of water to obtain component B. Mix 90 parts by weight of antibacterial telomer, 5 parts by weight of dimethyldiethoxysilane, and 5 parts by weight of hexadec...

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Abstract

The invention discloses a geopolymer based antibacterial coating and preparation method and application. The coating is composed of, by weight, 15-50 parts of component A, 20-70 parts of component B and 10-50 parts of component C, the component A is composed of 40-80 parts of geopolymer gel base material and 20-60 parts of pigment and filler, the component B is composed of 40-85 parts of alkali activator, 0-15 parts of curing regulator, 0-6 parts of rheological modifier and 12-45 parts of water, and the component C is composed of 70-100 parts of antibacterial telomer and 0-30 parts of silane modifier. The coating is free of VOCs, environment-friendly, healthful and excellent in corrosion-resistant performance; more importantly, the coating can effectively inhibit growth and propagation ofmicroorganisms, has the advantage of being efficient in fouling resistance and is suitable for water resistance, corrosion resistance, bacteria resistance and biofouling resistance of cultural relics,buildings, steel structures for freshwater breeding and concrete surface.

Description

technical field [0001] The invention belongs to the field of functional coatings, in particular to a geopolymer-based antibacterial coating and its preparation method and application. Background technique [0002] Geopolymer is a new type of water-based inorganic gel material produced by the reaction of solid aluminosilicate and high-concentration alkali solution. As an inorganic material, geopolymers have a unique polymer-like bonded structure. Therefore, geopolymer has the advantages of both inorganic materials and polymer materials. It has a dense molecular structure and good corrosion resistance; it has high mechanical strength, good heat resistance, and has excellent compatibility with concrete, stone, ceramics and other substrates. Excellent bonding ability; more importantly, geopolymer has the advantage of zero VOCs, and its raw material mainly comes from natural clay, which is a very potential environment-friendly inorganic coating. At present, as a new type of coa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/16C09D133/14C09D5/16C09D5/14C09D5/08C09D7/61
CPCC08K2003/2241C08K2003/2296C08K2003/265C09D5/08C09D5/14C09D5/1668C09D5/1687C09D7/61C09D7/70C09D133/16C08K13/04C08K3/22C08K7/00C08K3/40C08K3/26C08K7/26C08K3/04C08K3/346C08K3/34C08K13/08C08K11/005
Inventor 张广照马春风张国梁刘鑫军
Owner 东莞微积分新材料科技有限公司
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