Low-temperature-resistant environment-friendly tire sealant and manufacturing method thereof
An environment-friendly and sealant technology, applied in the direction of adhesive additives, non-polymer adhesive additives, polymer adhesive additives, etc., can solve the problems of aging resistance, high raw material costs, single product types, etc. problems, to achieve the effects of energy saving and environmental protection in the preparation process, excellent barrier properties, and a wide range of sources
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Embodiment 1
[0015] At least one of the polyester diols PEA, PBA, and PCL is vacuum dried and dehydrated at 100~120℃ for 2h, and then the polyester diol, toluene diisocyanate (TDI), catalyst N-methylpyrrolidone (NMP), dilaurin Dibutyl tin acid (DBTDL) was added to the reaction kettle and heated to 75~85℃ to react for 1~2h; then the temperature was lowered to 40~50℃, and 1,4-butanediol (BDO) and dimethylolpropionic acid were added. (DMPA) and trimethylolpropane (TMP) for chain extension reaction; add triethylamine (TEA) at 40℃ for neutralization, then add ethylenediamine (EDA) aqueous solution for emulsification; control the temperature at 20~ Slowly add polyvinyl alcohol (PVA) aqueous solution, propylene glycol, fluorocarbon surfactant, defoamer, leveling agent, and tackifier at 40°C, and stir well to obtain an energy-saving and environmentally-friendly water-soluble tire sealant.
Embodiment 2
[0017] At least one of polyether glycol PTMG and N220 is dried and dehydrated under vacuum at 100~120℃ for 2h, and then the polyether glycol, hexamethylene diisocyanate (HDI), catalyst N-methylpyrrolidone (NMP), two Dibutyltin laurate (DBTDL) was added to the reactor, and the temperature was raised to 75~85℃ to react for 1~2h; then the temperature was lowered to 40~50℃, and 1,4-butanediol (BDO) and dimethylolpropane were added. Acid (DMPA) and trimethylolpropane (TMP) for chain extension reaction; Add triethylamine (TEA) at 40℃ for neutralization, and then add ethylenediamine (EDA) aqueous solution for emulsification; control the temperature to 20 Slowly add polyvinyl alcohol (PVA) aqueous solution, propylene glycol, fluorocarbon surfactant, defoamer, leveling agent, and tackifier at ~40°C, and stir thoroughly to obtain an energy-saving and environmentally-friendly water-soluble tire sealant.
Embodiment 3
[0019] Polyester diol PBA is vacuum dried and dehydrated at 100~120℃ for 2h, then polyester diol PBA, toluene diisocyanate (TDI), catalyst N-methylpyrrolidone (NMP), dibutyl tin dilaurate (DBTDL) Put it into the reaction kettle, increase the temperature to 75~85℃ and react for 1~2h; then lower the temperature to 40~50℃, add 1,4-butanediol (BDO), dimethylolpropionic acid (DMPA), trihydroxyl Methyl propane (TMP) for chain extension reaction; Add methyl methacrylate (MMA) at 40°C, add triethylamine (TEA) for neutralization, and then add ethylenediamine (EDA) aqueous solution for emulsification. The temperature of the emulsion rose to 65~85℃ and continued to add methyl methacrylate (MMA), while adding at least one of the initiator potassium persulfate and azobisisobutyronitrile AIBN; control the temperature to 20~40℃ and slowly add the Vinyl alcohol (PVA) aqueous solution, propylene glycol, fluorocarbon surfactants, defoamers, leveling agents, tackifiers, fully stirred to obtain en...
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