Zr-Ni brazing filler metal used for nuclear reactor core structure brazing and preparing method and application of Zr-Ni brazing filler metal
A core structure, a technology for nuclear reactors, applied in welding equipment, welding/cutting media/materials, welding media, etc., can solve problems such as the toxicity of Be element, avoid grain growth, easy to process production and use, low heat The effect of the neutron absorption cross section
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specific Embodiment approach 1
[0029] Embodiment 1: In this embodiment, the Zr-Ni solder used for brazing the nuclear reactor core structure is prepared from 82% to 84% Zr and the remainder Ni in mass percentage.
[0030] This embodiment has the following beneficial effects:
[0031] 1. Both Zr and Ni elements in the Zr-Ni solder in this embodiment have a low thermal neutron absorption cross section and good corrosion resistance, which can meet the requirements of the reactor internal environment for material radiation resistance and corrosion resistance;
[0032] Two, when the content of Ni in the present embodiment Zr-Ni solder is 16~18%, the liquidus temperature of solder is 960~980 ℃, close with Zr-Be solder melting point; Compared with Zr-24Zn solder, Zr-29Mn solder can reduce the brazing temperature and avoid the decrease in the performance of the base metal caused by grain growth;
[0033] 3. The Ni element in the Zr-Ni solder of this embodiment is non-toxic, compared with the Be-containing solder, ...
specific Embodiment approach 2
[0034] Specific embodiment two: present embodiment is used for the preparation method of the Zr-Ni solder of nuclear reactor core structure brazing, carries out according to the following steps:
[0035] 1. Weighing 82% to 84% of metal Zr and the rest of metal Ni as raw materials according to the mass percentage of the elements, cleaning and drying the raw materials, and then placing them in a copper crucible of an electric arc melting furnace;
[0036] 2. Gas washing treatment of electric arc melting furnace;
[0037] ①. First, evacuate the arc melting furnace to (0.9~1)×10 -1 Pa, and then pass argon gas to the vacuum degree of 0.9 ~ 1MPa;
[0038] ②. Repeat step ① for 2 to 4 times, and finally inject argon until the vacuum degree is 4.5 to 5 MPa;
[0039] 3. Carry out arc melting for 3 to 4 times, and perform magnetic stirring during the arc melting process to obtain brazing filler metal ingots, and finally cut the brazing filler metal alloy into pieces and polish them wit...
specific Embodiment approach 3
[0044] Embodiment 3: This embodiment is different from Embodiment 2 in that: the cleaning agent used in the cleaning of the raw materials described in step 1 is alcohol. Other steps and parameters are the same as in the second embodiment.
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