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A Zinc Alloy Zipper Chain Tooth

A zinc alloy and sprocket technology, applied in the field of metallurgical electroplating, can solve the problems of poor adhesion between the nickel plating layer and the substrate, the application range is not very wide, and the large-scale application is limited, and the production cost is low, easy to control, and less components. Effect

Active Publication Date: 2019-01-22
宁夏鼎辉科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Neutral nickel pre-plating is mainly used for the rack plating process of zinc alloy die castings, and the main component of the plating solution is NiSO 4 , sodium citrate, etc., do not contain cyanide, but the bonding force between the nickel plating layer and the substrate is far inferior to the performance of cyanide copper plating pre-plating, and the product qualification rate is low
Moreover, due to the poor activation ability of the neutral nickel plating solution on zinc alloy die castings, there are higher requirements for its pretreatment
The neutral nickel plating process generally cannot be used for barrel plating of zinc alloy die castings, therefore, the range of industrial applications is not very wide
In addition, the cost of neutral nickel plating solution is high, and wastewater treatment is difficult, which limits its large-scale application in industry.
[0007] Other zinc alloy die casting pre-plating processes include chemical copper plating, HEDP copper plating, copper-tin alloy electroplating, etc., all of which have not been practically applied in industry due to problems such as bonding force, cost, and wastewater treatment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A zinc alloy zipper sprocket, the sprocket is a European tooth type, including a meshing end and a mounting end; the zipper sprocket is made of 5# zinc alloy die-casting, and the two ends are formed by 5# zinc alloy one-time die-casting Integral structure, sprocket length 10mm, width 8mm, thickness 3.5mm, the surface of the sprocket has a coating; wherein, the coating is formed by the following process:

[0021] (1) Pre-plating treatment: including surface degreasing and degreasing, pickling and rust removal, and activation treatment process to improve the bonding force of the coating;

[0022] (2) Cyanide-free pre-plating of copper: the composition of the plating solution is copper pyrophosphate 100g / L; sodium pyrophosphate 50g / L, trisodium citrate 280g / L, potassium sodium tartrate 30g / L, HEDP30g / L, ethylenediamine 280g / L; ammonium bifluoride 2g / L; sodium fluoride 3g / L, lithium fluoride 6g / L; ammonia water to adjust the pH value to 9.5, the electroplating process is ca...

Embodiment 2

[0026] A zinc alloy zipper sprocket, the sprocket is a European tooth type, including a meshing end and a mounting end; the zipper sprocket is made of 5# zinc alloy die-casting, and the two ends are formed by one-time die-casting of 5# zinc alloy Integral structure, sprocket length 10mm, width 8mm, thickness 3.5mm, the surface of the sprocket has a coating; wherein, the coating is formed by the following process:

[0027] (1) Pre-plating treatment: including surface degreasing and degreasing, pickling and rust removal, activation treatment process to improve the bonding force of the coating;

[0028] (2) Cyanide-free pre-plating of copper: the composition of the plating solution is copper pyrophosphate 120g / L; sodium pyrophosphate 40g / L, trisodium citrate 300g / L, potassium sodium tartrate 26g / L, HEDP50g / L, ethylenediamine 260g / L; ammonium bifluoride 3g / L; sodium fluoride 2g / L, lithium fluoride 8g / L; ammonia water to adjust the pH value to 8.5, the electroplating process is cat...

Embodiment 3

[0032]A zinc alloy zipper sprocket, the sprocket is a European tooth type, including a meshing end and a mounting end; the zipper sprocket is made of 5# zinc alloy die-casting, and the two ends are formed by one-time die-casting of 5# zinc alloy Integral structure, sprocket length 10mm, width 8rmm, thickness 3.5mm, the surface of the sprocket has a coating; wherein, the coating is formed by the following process:

[0033] (1) Pre-plating treatment: including surface degreasing and degreasing, pickling and rust removal, and activation treatment process to improve the bonding force of the coating;

[0034] (2) Cyanide-free pre-plating of copper: the composition of the plating solution is copper pyrophosphate 110g / L; sodium pyrophosphate 45g / L, trisodium citrate 290g / L, potassium sodium tartrate 28g / L, HEDP40g / L, ethylenediamine 270g / L; ammonium bifluoride 2.5g / L; sodium fluoride 2.5g / L, lithium fluoride 7g / L; ammonia water to adjust the pH value to 9.0, the electroplating proces...

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PUM

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Abstract

The invention discloses zinc alloy zipper teeth. The zipper teeth are in the form of Swiss zipper teeth, and comprise an engaged end and a mounted end, wherein the zipper teeth are formed by die-casting 5# zinc alloy and two ends are integrated structure which is molded through one-time die-casting of 5# zinc alloy; the zipper teeth are 10mm long, 8mm wide and 3.5mm thick; a coating is arranged on the surfaces of the zipper teeth; and the coating is formed by the following processes: (1) processing before coating; (2) pre-coating copper without cyanogen; (3) chemical nickel-plating; (4) passivating and hole sealing.

Description

technical field [0001] The invention relates to the field of metallurgy and electroplating, in particular to a zinc alloy zipper element. Background technique [0002] Due to its cheap price, low melting point, and especially good die-casting process performance, zinc alloy has been widely used in the manufacture of small hardware accessories, and can also be used to manufacture decorative and practical metal parts. Such as various zippers, belt buckles, luggage accessories, car nameplates and military badges, etc. [0003] The appearance of zinc alloy die castings is gray and white, and there are various defects on the surface, such as: slag inclusions, shrinkage cavities, etc. Therefore, without surface treatment, its usability and decoration are very poor. A common surface treatment method is electroplating. According to the different decorative and functional requirements, there are certain differences in the electroplating process. For example, there are gold-plated,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A44B19/24C23C28/02C25D3/38C23C18/36
CPCA44B19/24C23C18/36C23C28/023C25D3/38
Inventor 张颖
Owner 宁夏鼎辉科技有限公司
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