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Preparation method of environment-friendly double-component high-temperature-resisting fireproof coating

A fire-resistant coating and high-temperature-resistant technology, applied in the field of coatings, can solve the problems of harmfulness to human body, unsatisfactory temperature resistance and heat insulation effect, and insufficient environmental protection, and achieve the effect of excellent fire resistance, excellent fire and heat insulation performance, and low VOC emission.

Inactive Publication Date: 2015-06-24
HAILONG EMERSON ZHENJIANG ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Silicone high-temperature-resistant coatings have good heat resistance, water resistance, electrical insulation and good mechanical properties, but their heat-resistant and heat-insulating effects are not ideal, and organic solvents are required, which are harmful to the human body and not environmentally friendly.

Method used

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  • Preparation method of environment-friendly double-component high-temperature-resisting fireproof coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Each component in this embodiment is measured in parts by mass.

[0035] First, mix 48 parts of 800 mPa·s hydroxyl silicone oil, 34 parts of N-P expansion flame retardant, 5 parts of mica powder, 3 parts of wollastonite powder, 3 parts of low temperature glass powder, 1 part of selenium hydroxide, 1 part of boron-containing compound, 3 parts Add expanded perlite and 2 parts of sepiolite powder into a sand mill under stirring, gradually disperse until uniform, and sand-mill to 300 mesh to obtain component A.

[0036] Next, 34 parts of methyl tributylketoxime silane, 22 parts of vinyl tributylketoxime silane, 14 parts of tetrabutylketoxime silane, 22 parts of γ-glycidyl ether oxypropyltrimethoxysilane, 8 parts Add one part of organotin-based catalyst into the high-speed disperser, and mix uniformly to obtain component B;

[0037] Finally, when in use, the prepared component A and component B are uniformly mixed at a mass ratio of 10:1 to obtain a high temperature resista...

Embodiment 2

[0039] Each component in this embodiment is measured in parts by mass.

[0040] First, 40 parts of 900 mPa·s hydroxyl silicone oil, 35 parts of N-P expansion flame retardant, 5 parts of expanded graphite, 4 parts of mica powder, 3 parts of kaolin, 3 parts of talcum powder, 4 parts of low-temperature glass powder, 1 part of iron octoate, 3 parts Add one part of silica sand, one part of expanded perlite, and one part of sepiolite powder into the sand mill under stirring, gradually disperse until uniform, and get A component after sand grinding to 300 mesh.

[0041] Secondly, 44 parts of phenyl tributylketoxime silane, 16 parts of vinyl tributyl ketoxime silane, 28 parts of γ-aminopropyl triethoxysilane, 7 parts of γ-glycidyl etheroxypropyl trimethoxy Add base silane and 5 parts of organotin-based catalysts into the high-speed disperser, and mix them uniformly to obtain component B;

[0042] Finally, when in use, the prepared component A and component B are uniformly mixed at a ...

Embodiment 3

[0044] Each component in this embodiment is measured in parts by mass.

[0045] First, 60 parts of 900 mPa·s hydroxyl silicone oil, 15 parts of N-P intumescent flame retardant, 5 parts of expanded graphite, 4 parts of wollastonite powder, 1 part of talcum powder, 1 part of selenium hydroxide, 1 part of silica sand, 10 parts Add expanded perlite and 3 parts of sepiolite powder into a sand mill under stirring, gradually disperse until uniform, and sand grind to 300 mesh to obtain component A.

[0046] Next, 40 parts of phenyl tributylketoxime silane, 33 parts of tetrabutylketoxime silane, 7 parts of methyl tributyl ketoxime silane, 15 parts of γ-glycidyl etheroxypropyl trimethoxysilane, 5 parts Add one part of organotin-based catalyst into the high-speed disperser, and mix uniformly to obtain component B;

[0047] Finally, when in use, the prepared component A and component B are uniformly mixed at a mass ratio of 10:1 to obtain a high temperature resistant fireproof coating. ...

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Abstract

The invention discloses a preparation method of an environment-friendly double-component high-temperature-resisting fireproof coating. The preparation method comprises the following steps: adding hydroxyl silicone oil, a flame retarding agent, magnetic filler and a ceramic additive into a grinding machine D under the stirring condition until the mixture is gradually and uniformly dispersed; grinding to a specified fineness to obtain a component A; adding a cross-linking agent, a coupling agent and a catalyst into a high-speed disperser; uniformly mixing to obtain a component B; when in use, uniformly mixing the prepared component A and the prepared component B in a mass ratio of 10 to 1; curing at the temperature of 10 to 50 DEG C to form a film namely high temperature-resisting fireproof coating, wherein the component A contains a hydroxyl silicone oil flame retarding agent, the magnetic filler, the ceramic additive and other heat insulating fillers, the component B contains the cross-linking agent, the coupling agent and the catalyst; when in used, mixing the component A and the component B in a mass ratio of 10 to 1 and curing at the temperature of 10 to 50 DEG C to form a film. The environment-friendly double-component high-temperature-resisting fireproof coating disclosed by the invention is free of an organic solvent and has the characteristics of good expansion performance when meeting fire, high expansion carbonization layer strength, long fire retarding time and the like; the coating is good in heat insulation property and high temperature resistance; the temperature resistance is 800 DEG C or more; the operation is convenient.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an environment-friendly two-component high-temperature-resistant fireproof coating and a preparation method thereof. Background technique [0002] High temperature resistant coatings, also known as heat resistant coatings, generally refer to coatings that can maintain proper physical and mechanical properties without discoloration or falling off of the paint film above 200°C, so that the protected objects can function normally in high temperature environments Special functional coatings. Silicone resin, because it has an organic-inorganic main chain structure "Si-O-Si", greatly enhances the bond energy, and endows silicone resin with higher heat resistance and fire resistance than all pure organic resins. Silicone high-temperature-resistant coatings have good heat resistance, water resistance, electrical insulation and good mechanical properties, but their heat-resistant and he...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/06C09D7/12C09D5/18
Inventor 严玉沃洛科卡尼段佳巍郑家青戴金华
Owner HAILONG EMERSON ZHENJIANG ENERGY TECH
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