A low-temperature anti-sulfur denitrification catalyst and preparation method thereof

Abstract

The invention discloses a low-temperature anti-sulfur denitrification catalyst and a preparation method thereof. The catalyst is formed by mixing components containing the following weight percentages: active site 1-15%; carbon-based carrier 85-99%; wherein, active site by Ag 2 O, K 2 O, BaO, SnO 2 、 Bi 2 o 3 Or one or more mixed compositions of vanadium-based alloy oxides improved by PbO. The preparation method is to prepare a low-temperature anti-sulfur denitrification catalyst by mixing active sites and carbon-based supports. Due to the surface hydrophobic treatment of the catalyst prepared by the present invention, the water molecules contained in the flue gas are difficult to attach to the pore structure of the catalyst to form capillary condensation or with the adsorbed NH 3 and SO 2 or SO 3 Formation of sulfuric acid or ammonium sulfite leads to catalyst deactivation.

Description

【Technical field】 [0001] The invention relates to the field of treatment of fossil fuel combustion tail gas, in particular to a low-temperature sulfur-resistant denitrification catalyst and a preparation method thereof. 【Background technique】 [0002] It is well known that nitrogen oxides (NO x ) is a harmful gas, the main air pollutant, not only can cause acid rain, photochemical smog, greenhouse effect and the destruction of the ozone layer; it can also cause serious water quality and soil quality deterioration, urban haze weather (PM2.5) and other environmental pollution problem, which poses a great threat to human health. 90% SO in air pollutants 2 and 70% NO x From the combustion of coal, the energy structure dominated by coal has led to a high total amount of air pollutant emissions. Potential environmental problems continue to emerge. Air pollution in the Yangtze River Delta, Pearl River Delta, and Beijing-Tianjin-Hebei region and other urban agglomerations has gra...

AI Technical Summary

Problems solved by technology

90% SO in air pollutants 2 and 70% NO x From the combustion of coal, the energy structure dominated by coal has led to a high total amount of air pollutant emissions. Potential environmental problems continue to emerge. Air pollution in the Yangtze River Delta, Pearl River Delta, and Beijing-Tianjin-Hebei region and other urban agglomerations has gradually become obvious. regional characteristics, the type of acid rain has changed from sulfuric acid type to sulfuric acid and nitric acid compound type, and the pollution of nitrogen oxides has not been effectively controlled

(2) Molecular sieve catalysts selectively reduce NO at higher temperatures x Has high catalytic activity, and the active temperature range is relatively wide, but resistant to H 2 O and SO 2 Poor ability

(3) Carbon-based catalysts exhibit good SCR activity at low temperatures, but their ability to resist sulfur poisoning is not strong, especially unstable and flammable at temperatures above 250 °C, which hinders their use in SCR research. development in

However, the problem is that the medium temperature catalyst must be operated at a temperature higher than 350°C to avoid SO 2 Weaken the activity, which requires that the SCR catalyst system must be placed above the desulfurization and dust removal devices (such as figure 1 shown) to take advantage of the high temperature of the flue gas, otherwise an air preheating device is required

However, such an installation position will greatly reduce the allowable operating temperature of the SCR reactor (150-200°C).

Such a reaction temperature makes all currently used high-temperature SCR catalysts significantly reduce their activity and cannot complete the task of denitrification.

At the same time, at such low temperatures, the SO present in the flue gas 2 Will react with added ammonia to form ammonium sulfate or ammonium sulfite which deposits on the catalyst surface leading to its deactivation

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