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Color-fixing anti-wrinkle finishing agent as well as preparation method and application thereof

An anti-wrinkle finishing agent and finishing agent technology, applied in the field of textile printing and dyeing, can solve the problems of deviation of treatment effect, yellowing of processed products, poor reaction stability, etc., and achieve the effects of low cost, improved color fastness, and simple synthesis.

Inactive Publication Date: 2014-09-17
YANCHENG PRINTING & DYEING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In addition, cotton fabric anti-wrinkle often uses amide-formaldehyde finishing agents and polycarboxylic acid finishing agents. Amide-formaldehyde finishing agents mainly use methylol to react with hydroxyl groups on cotton fibers, but in the process of production and consumption harmful substances such as formaldehyde
There are mainly three types of polycarboxylic acid finishing agents, one is BTCA (1,2,3,4-tetracarboxylic butane), which is expensive and the synthesis process is complicated; the other is CA (citric acid), which has only three carboxyl groups , the treatment effect is biased, and it is easy to generate unsaturated by-products, resulting in yellowing of the processed product; its three PMA-AC (polymaleic acid-acrylic acid), difficult to synthesize, and poor reaction stability

Method used

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  • Color-fixing anti-wrinkle finishing agent as well as preparation method and application thereof
  • Color-fixing anti-wrinkle finishing agent as well as preparation method and application thereof
  • Color-fixing anti-wrinkle finishing agent as well as preparation method and application thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Preparation of color-fixing anti-wrinkle finishing agent:

[0038] Using maleic acid, acrylamide and dimethyl diallyl ammonium chloride as raw materials, the molar ratio of anionic monomer, nonionic monomer and cationic monomer is 10: 10: 80, and dissolved in 0.1-0.5M In the NaCl aqueous solution, the total concentration of the monomer salt solution is 10-35%, adjust the pH value to 10, catch the oxygen with nitrogen for 10-30 minutes, raise the temperature to 60-80°C under the protection of nitrogen, add ammonium persulfate-bisulfite Sodium redox initiator, its dosage is 0.001-0.008 mole fraction of the total amount of monomers, to initiate copolymerization for 3h-5h, to obtain an aqueous solution of amphoteric color-fixing agent, to precipitate with acetone, and to obtain the product after vacuum drying. Utilize the Ubbelohde viscometer to measure its intrinsic viscosity according to the one-point method to be 312.20 mL / g.

[0039] To treat the fabric:

[0040...

Embodiment 2

[0052] Preparation of color-fixing anti-wrinkle finishing agent:

[0053] Anionic monomer maleic anhydride, nonionic monomer styrene and cationic monomer methacryloyloxyethyltrimethylammonium chloride were selected for radical copolymerization, and the molar ratio of the three was 20:10:70. Dissolve methacryloyloxyethyltrimethylammonium chloride with a small amount of absolute ethanol first, use acetone as solvent, and mix ethanol solution of methacryloyloxyethyltrimethylammonium chloride, styrene and horse Add toric anhydride into the three-necked flask, raise the temperature to 60°C, add azobisisobutyronitrile, react for 4 hours, and cool down to obtain the polymer product. The polymer is dissolved in water, and then the acetone is distilled off to obtain a high polymer solution. Utilize the Ubbelohde viscometer to measure its intrinsic viscosity according to the one-point method to be 283.60 mL / g.

[0054] To treat the fabric:

[0055] First, configure the color-f...

Embodiment 3

[0067] Preparation of color-fixing anti-wrinkle finishing agent:

[0068] Determine that anion monomer maleic anhydride and cationic monomer dimethyl diallyl ammonium chloride mol ratio are 50: 50, respectively and dissolve in the NaCl aqueous solution of 0.1-0.5M, mix in three-necked flask, monomer The total concentration of the brine solution is 10-35%, adjust the pH value to 10, nitrogen gas catches oxygen for 10-30 minutes, heat up to 60-80°C under the protection of nitrogen gas, add ammonium persulfate-sodium bisulfite redox initiator, The amount used is 0.001-0.008 mole fraction of the total amount of monomers, and the copolymerization is initiated for 3h-5h to obtain an aqueous solution of amphoteric color-fixing agent, which can be precipitated with acetone and dried in vacuum to obtain the product. Utilize the Ubbelohde viscometer to measure its intrinsic viscosity according to the one-point method to be 185.71 mL / g.

[0069] To treat the fabric:

[0070] First,...

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Abstract

The invention relates to a color-fixing anti-wrinkle finishing agent which is amphoteric water-soluble polymer; the molecular formula of the polymer is (A)x(B)y(C), wherein A refers to an anionic link, B refers to a nonionic link and B refers to a cationic link; x, y and z respectively refer to polymerization degrees of the anionic link, the nonionic link and the cationic link; the ratio of x to y to z is (10-50) to (0-30) to (50-90); the anionic link is derived from a monomer containing adjacent carboxylic acid groups; the nonionic link is derived from a nonionic monomer; the cationic link is derived from a monomer containing cationic quaternary ammonium groups. The invention also relates to a preparation method and application of the color-fixing anti-wrinkle finishing agent. The finishing agent is capable of effectively improving the wet rubbing fastness, the soaping fastness and wrinkle recovery angle (WRA) of the dyed material; the finishing agent is simple and convenient to synthesize, low in cost, good in storage stability, free of release of formaldehyde in the producing and using process, green and applicable to good color-fixation anti-wrinkle treatment on textiles such as colored cotton, hemp, regenerated cellulose and the like.

Description

technical field [0001] The invention belongs to the field of textile printing and dyeing, and in particular relates to a color-fixing anti-wrinkle finishing agent and a preparation method and application thereof. Background technique [0002] Color-fixing finishing and wrinkle-resistant finishing are conventional post-finishing processes for dyed cotton fabrics. Direct dyes and reactive dyes can be used for the dyeing of cellulose materials. They all belong to the category of anionic dyes, with complete color spectrum and low price. However, in the chemical structure of direct dyes, most of them have hydrophilic sulfonic acid groups and carboxylic acid groups, which are relatively hydrophilic, and are only combined with fibers through hydrogen bonds and van der Waals forces, so the wet fastness is low, and fading, The staining phenomenon is also very serious, and although reactive dyes can form covalent bonds with cotton fibers, many dyes and fiber bonds are not stable, are...

Claims

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Application Information

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IPC IPC(8): D06P5/08C08F226/02C08F220/34C08F222/06C08F222/02C08F220/56C08F212/08D06P5/10
Inventor 曹志美周天池何雪梅郑成辉
Owner YANCHENG PRINTING & DYEING
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