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Rare earth permanent magnetic material and preparation method thereof

A rare-earth permanent magnet and rare-earth element technology, which is applied in the direction of magnetic materials, inorganic material magnetism, and magnetic objects, can solve the problems of high processing costs, inability to diffuse heavy rare-earth elements, and limited diffusion depth of elements, and improve production efficiency. Reduce the cost of preparation and processing, and minimize the effect of remanent magnetism

Active Publication Date: 2014-07-02
宁波金鸡强磁股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] There are obvious shortcomings in the current grain boundary diffusion technology: (1) Due to the limited depth of element diffusion in the grain boundary diffusion technology, heavy rare earth elements cannot diffuse into larger-sized magnets
Therefore, the use of grain boundary diffusion technology is suitable for the preparation of thick sheet magnets (US2010282371, US20080245442), the thickness of the orientation direction can only be controlled within the range of 3.5~10mm, so this technology is not suitable for large magnets
(2) The current heavy rare earth element grain boundary diffusion technology is aimed at the magnet after sintering. Before the diffusion treatment, the magnet needs to be machined. After the diffusion treatment, it needs to be reprocessed due to the change of the magnet size and surface roughness, and the processing cost is high.

Method used

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  • Rare earth permanent magnetic material and preparation method thereof
  • Rare earth permanent magnetic material and preparation method thereof
  • Rare earth permanent magnetic material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 and comparative example 1

[0024] Proportioning is carried out according to the composition ratio, and Nd, Fe, Co, Nb, Cu and BFe alloys with a purity greater than 99% (weight percent) are used. Melt at intermediate frequency in an argon atmosphere, and then cast the molten steel on a water-cooled copper roll with a rolling speed of 1.5m / s to prepare a quick-setting sheet. The average thickness of quick-setting flakes is 0.25mm, and the composition is Nd 13.5 Fe bal co 1 Nb 0.2 Cu 0.3 B 5.5 (atomic percent).

[0025] Use hydrogen crushing or mechanical crushing to first coarsely crush the alloy into particles of about 0.5mm, and then use airflow milling to crush the alloy into a fine powder with an average particle size of 3.8um. ​​The magnetic powder is oriented in a 2T magnetic field and simultaneously applied with The forming is carried out under the pressure perpendicular to the orientation field, the pressure is 70 MPa, and a blank with a thickness direction of 8 mm is obtained.

[0026] The...

Embodiment 2 and comparative example 2

[0036] Proportioning is carried out according to the composition ratio, and Nd, Fe, Co, Nb, Cu and BFe alloys with a purity greater than 99% (weight percent) are used. Melt with intermediate frequency in 0.04MPA argon atmosphere, and then cast the molten steel on a water-cooled copper roller with a rolling speed of 2m / s to prepare quick-setting flakes. The average thickness of the quick-setting flakes is 0.23mm, and the composition is Nd 13.5 Fe bal co 1 Nb 0.2 Cu 0.3 B 5.5 (atomic percent).

[0037] Use hydrogen crushing or mechanical crushing to first coarsely crush the alloy into particles of about 0.5mm, and then use airflow milling to crush the alloy into a fine powder with an average particle size of 3.8um. ​​The magnetic powder is oriented in a 2T magnetic field and simultaneously applied with The orientation field is parallel or perpendicular to the pressure for forming, the pressure is 70MPa, and the blank with the thickness direction of 8mm is obtained.

[0038...

Embodiment 3 and comparative example 3

[0048] Proportioning is carried out according to the composition ratio, and Nd, Fe, Co, Nb, Cu and BFe alloys with a purity greater than 99% (weight percent) are used. Melt with intermediate frequency in 0.04MPA argon atmosphere, and then cast the molten steel on a water-cooled copper roller with a rolling speed of 2m / s to prepare quick-setting flakes. The average thickness of quick-setting flakes is 0.23mm, and the composition is Nd 13.5 Fe bal co 1 Nb 0.2 Cu 0.3 B 5.5 (atomic percent).

[0049] Use hydrogen crushing or mechanical crushing to first coarsely crush the alloy into particles of about 0.5mm, and then use airflow milling to crush the alloy into a fine powder with an average particle size of 3.8um. ​​The magnetic powder is oriented in a 2T magnetic field and simultaneously applied with The orientation field is parallel or perpendicular to the pressure for forming, the pressure is 70MPa, and the blank with the thickness direction of 8mm is obtained.

[0050] T...

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Abstract

The invention provides a rare earth permanent magnetic material and a preparation method thereof. The rare earth permanent magnetic material is characterized in that the rare earth permanent magnetic material is formed in the mode that a composite-structure blank composed of a magnetic phase blank and a non-magnetic phase covering the surface of the magnetic phase blank is pressed and sintered and undergoes tempering heat treatment. During preparation, firstly the magnetic phase blank is prepared in a forming stage, then non-magnetic phase mixtures comprising heavy rare earth compounds are applied to the end face of the blank, then sintering and tempering processing are carried out, and in the heat processing process, by means of grain boundary diffusion, a sintered magnet with low heavy rare earth content and high coercivity is obtained. Compared with an existing grain boundary diffusion technique, production efficiency is improved after the technique is adopted. By means of the method, heavy rare earth elements are in grain boundary of gains in the sintered magnet, and accordingly coercivity is improved and meanwhile residual magnetism is reduced to the smallest degree. By means of the method, a large magnet can be prepared, the defect that a large magnet cannot be prepared in a traditional sintered magnet grain boundary diffusion technique is overcome, and preparation and machining cost of the magnet is reduced.

Description

technical field [0001] The invention belongs to the technical field of manufacturing rare earth permanent magnet materials, in particular to a rare earth permanent magnet material with low weight rare earth and high coercive force and a preparation method thereof. Background technique [0002] As an important metal functional material, sintered NdFeB magnets are widely used in many fields such as aerospace and navigation, information electronics, energy, transportation, communication, medical and health care, etc. In many fields, such as electric vehicles, hybrid vehicles and wind power generation, sintered NdFeB magnets are required to have higher coercive force to meet the use requirements at a certain temperature. At present, the commonly used method is to add heavy rare earth element Dy, and Tb partially replaces Nd to improve the coercive force and temperature stability of the alloy. [0003] Unlike light rare earth elements, heavy rare earth elements and transition gr...

Claims

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Application Information

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IPC IPC(8): H01F1/053H01F1/08B22F3/16
Inventor 王会杰胡元虎赵家成丁海浩唐国团郭林陈福峰沈是茂
Owner 宁波金鸡强磁股份有限公司
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