Compound rubidium phosphomolybdate, rubidium phosphomolybdate nonlinear optical crystals, and preparation method and applications of compound rubidium phosphomolybdate and rubidium phosphomolybdate nonlinear optical crystals
A nonlinear optics, rubidium phosphomolybdate technology, applied in nonlinear optics, chemical instruments and methods, optics, etc., can solve problems such as nonlinear optics crystals that have not yet been obtained
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Embodiment 1
[0036] According to the chemical formula: 2Rb 2 CO 3 +5MoO 3 +2NH 4 h 2 PO 4 =Rb 4 Mo 5 P 2 o 22 +3H 2 O↑+2CO 2 ↑+2NH 3 ↑, Rubidium phosphomolybdate (Rb 4 Mo 5 P 2 o 22 ) compound:
[0037] Weigh the raw materials according to the proportion of the reaction formula and put them into a mortar, mix and grind them carefully, put them into a corundum crucible with an opening of Φ400mm×400mm, press them tightly, put them into a muffle furnace, slowly raise the temperature to 400°C, and keep the temperature constant for 24 hours , take out the crucible after cooling, at this time the sample is relatively loose, then take out the sample and grind it evenly, then put it in the crucible, keep it in the muffle furnace at a temperature of 500°C for 48 hours, take it out, put it in a mortar and grind it Grind to get Rb 4 Mo 5 P 2 o 22 compound, the product is subjected to X-ray analysis, and the resulting X-ray spectrum and Rb 4 Mo 5 P 2 o 22 The X-ray spectra of s...
Embodiment 2
[0045] According to the reaction formula 2Rb 2 O+5MoO 3 +P 2 o 5 =Rb 4 Mo 5 P 2 o 22 Synthetic Rb 4 Mo 5 P 2 o 22 Compound, specific operation steps are carried out according to embodiment 1;
[0046] Preparation of Rb by pulling method 4 Mo 5 P 2 o 22 the crystal
[0047] The synthesized Rb 4 Mo 5 P 2 o 22 Put the compound into a Φ90mm×90mm open platinum crucible, then put the crucible into a crystal growth furnace, raise the temperature to 650°C, keep the temperature for 10 hours, then cool it down to 540°C to obtain a rubidium phosphomolybdate compound melt;
[0048] Slowly cool down to room temperature at a rate of 0.5°C / h, and crystallize to obtain seed crystals;
[0049]Rb 4 Mo 5 P 2 o 22 The seed crystal is fixed on the lower end of the seed rod with a platinum wire, and the seed crystal is introduced into the crucible from the small hole on the top of the furnace, so that the seed crystal is in contact with the liquid surface of the rubidium pho...
Embodiment 3
[0053] According to the reaction formula 2Rb 2 CO 3 +5(NH 4 ) 2 MoO 4 +2NH 4 h 2 PO 4 =Rb 4 Mo 5 P 2 o 22 +2CO 2 ↑+12NH 3 ↑+8H 2 O ↑ synthesis of Rb 4 Mo 5 P 2 o 22 Compound, specific operation steps are carried out according to embodiment 1;
[0054] Preparation of Rb by Kyropoulos method 4 Mo 5 P 2 o 22 the crystal
[0055] The synthesized Rb 4 Mo 5 P 2 o 22 Put the compound into a Φ80mm×80mm open platinum crucible, then put the crucible into a crystal growth furnace, raise the temperature to 650°C, keep the temperature for 4 hours, then cool down to 520°C to obtain a rubidium phosphomolybdate compound melt;
[0056] Slowly cool down to room temperature at a rate of 1°C / h, and use the platinum wire suspension method to obtain small crystals as seed crystals during the cooling;
[0057] Rb 4 Mo 5 P 2 o 22 The seed crystal is fixed on the lower end of the seed rod with a platinum wire, and the seed crystal is introduced into the crucible from the...
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