Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

White polypropylene tube with high shading performance and production method thereof

A polypropylene pipe, high shading technology, applied in the direction of rigid pipes, pipes, pipes/pipe joints/fittings, etc., can solve the problems of poor dispersion, poor shading performance, and no white polypropylene pipes. Dispersion performance, simple production process, high shading effect

Active Publication Date: 2014-08-06
WUHAN KINGBULL ECONOMIC DEV
View PDF2 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the poor shading performance of the white pipe, there is a problem of light transmission in the pipe, which leads to the easy breeding of algae and bacteria inside the pipe, which is harmful to human health.
[0004] At present, foreign pipe manufacturers generally use polypropylene colored materials to produce pipes. Since foreign petrochemical plants do not provide white polypropylene colored materials, foreign pipe manufacturers do not produce white polypropylene pipes.
However, domestic pipe manufacturers generally use the method of adding white masterbatch to polypropylene to produce white polypropylene pipes. Due to the insufficient hiding power and poor dispersion of the pigment titanium dioxide in the masterbatch, the shading performance of the pipes generally does not meet the standards. Require

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 2 parts of rutile titanium dioxide (particle size 100nm), 3 parts of spacer barium sulfate (particle size 1μm) Mix evenly with 0.25 parts of dispersant polyethylene glycol (molecular weight 6000) and 0.1 part of antioxidant 168, then knead and granulate at a melt temperature of 230°C to obtain white polypropylene colored material, and finally white polypropylene colored material Pour it into a single-screw pipe extruder and extrude to obtain a white polypropylene pipe with high light-shielding performance 1.

[0021] The titanium dioxide is processed to be 20% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 1% of the mass, then mix and adjust the pH to 5-6, react at 80°C for 30 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated with alumina ...

Embodiment 2

[0023] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 2.5 parts of rutile titanium dioxide (particle size: 1000nm), 2.5 parts of spacer calcium carbonate and 0.1 part of dispersant hard Zinc fatty acid, 0.2 part of antioxidant 168, and 0.1 part of lubricant are mixed evenly, then kneaded and granulated at a melt temperature of 230°C to obtain a white polypropylene colorant, and finally pour the white polypropylene colorant into a single-screw pipe The extruder is extruded to obtain a white polypropylene pipe 2 with high shading performance.

[0024] The titanium dioxide is processed to be 30% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 5% of the mass, then mix and adjust the pH to 5-6, react at 70°C for 60 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated with alumina 2 Add to the acetone...

Embodiment 3

[0026] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 3 parts of rutile titanium dioxide (particle size 350nm), 3 parts of spacer barium sulfate (particle size 5μm) Mix well with 0.3 parts of dispersant polyethylene glycol (molecular weight 10000) and 0.3 parts of lubricant, then knead and granulate at a melt temperature of 230°C to obtain white polypropylene colored material, and finally pour the white polypropylene colored material into The single-screw pipe extruder is extruded to obtain a white polypropylene pipe with high light-shielding performance 3.

[0027] The titanium dioxide is treated with a concentration of 25% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 3% of the mass, then mix and adjust the pH to 5-6, react at 75°C for 40 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated w...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle diameteraaaaaaaaaa
particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention provides a white polypropylene tube with high shading performance and a production process thereof. The white polypropylene tube comprises polypropylene resin serving as a raw material, and is characterized in that the raw material comprises titanium dioxide, a spacer and a dispersing agent, wherein the titanium dioxide is 2 to 5 percent of the mass of the polypropylene resin; after the titanium dioxide is processed, an aluminum oxide layer and an organic layer wrap the outer surfaces of TiO2 particles sequentially from inside to outside; the spacer is 100 to 150 percent of the mass of the titanium dioxide; and the dispersing agent is 0.1 to 0.5 percent of the mass of the polypropylene resin. According to the white polypropylene tube, the raw materials for producing the white polypropylene tube are improved, so that the white polypropylene tube achieves a high-shading effect; and the production process is simple and high in practicality.

Description

technical field [0001] The invention belongs to the technical field of polypropylene pipes, in particular to a white polypropylene pipe with high shading performance and a production method thereof. Background technique [0002] Polypropylene pipes have the characteristics of low density, hygiene, non-toxicity, good corrosion resistance and easy processing, and are widely used in construction, chemical pipelines and other fields. [0003] There are strict requirements on the shading performance of polypropylene pipes at home and abroad. For example, the ISO 15874-2:2003 standard clearly requires that the light transmittance of the pipes should be less than 0.2%. In the national standard GB / T 18742.2-2002, it is also required that the pipe should be opaque. In order to make polypropylene pipes meet the requirements of light-tightness, most pipe manufacturers will choose to produce gray or green polypropylene pipes, because these two colors of pipes have strong light-shieldin...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/10C08K13/06C08K9/04C08K9/02C08K3/22C08K3/30C08K3/26C08K5/098C08L71/08F16L9/12
Inventor 陈厚忠
Owner WUHAN KINGBULL ECONOMIC DEV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products