White polypropylene tube with high shading performance and production method thereof
A polypropylene pipe, high shading technology, applied in the direction of rigid pipes, pipes, pipes/pipe joints/fittings, etc., can solve the problems of poor dispersion, poor shading performance, and no white polypropylene pipes. Dispersion performance, simple production process, high shading effect
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Embodiment 1
[0020] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 2 parts of rutile titanium dioxide (particle size 100nm), 3 parts of spacer barium sulfate (particle size 1μm) Mix evenly with 0.25 parts of dispersant polyethylene glycol (molecular weight 6000) and 0.1 part of antioxidant 168, then knead and granulate at a melt temperature of 230°C to obtain white polypropylene colored material, and finally white polypropylene colored material Pour it into a single-screw pipe extruder and extrude to obtain a white polypropylene pipe with high light-shielding performance 1.
[0021] The titanium dioxide is processed to be 20% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 1% of the mass, then mix and adjust the pH to 5-6, react at 80°C for 30 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated with alumina ...
Embodiment 2
[0023] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 2.5 parts of rutile titanium dioxide (particle size: 1000nm), 2.5 parts of spacer calcium carbonate and 0.1 part of dispersant hard Zinc fatty acid, 0.2 part of antioxidant 168, and 0.1 part of lubricant are mixed evenly, then kneaded and granulated at a melt temperature of 230°C to obtain a white polypropylene colorant, and finally pour the white polypropylene colorant into a single-screw pipe The extruder is extruded to obtain a white polypropylene pipe 2 with high shading performance.
[0024] The titanium dioxide is processed to be 30% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 5% of the mass, then mix and adjust the pH to 5-6, react at 70°C for 60 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated with alumina 2 Add to the acetone...
Embodiment 3
[0026] 100 parts by weight of polypropylene resin (grade PA14D, melt flow rate 0.29g / 10min), 3 parts of rutile titanium dioxide (particle size 350nm), 3 parts of spacer barium sulfate (particle size 5μm) Mix well with 0.3 parts of dispersant polyethylene glycol (molecular weight 10000) and 0.3 parts of lubricant, then knead and granulate at a melt temperature of 230°C to obtain white polypropylene colored material, and finally pour the white polypropylene colored material into The single-screw pipe extruder is extruded to obtain a white polypropylene pipe with high light-shielding performance 3.
[0027] The titanium dioxide is treated with a concentration of 25% TiO 2 Add soluble aluminum sulfate solution in the slurry, the amount of aluminum added is Al 2 o 3 Calculated, the amount of aluminum added is TiO 2 3% of the mass, then mix and adjust the pH to 5-6, react at 75°C for 40 minutes, wash and dry to obtain TiO coated with alumina on the outer surface 2 ; TiO coated w...
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