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Multi-hole foam glass carrier for fast mass transfer biological fluidized bed and preparation method and application thereof

A biological fluidized bed and porous foam technology, applied in the field of sewage treatment, porous foam glass carrier and its preparation, can solve the problem of poor dynamic turbulence between carrier and liquid phase, lower fluidized bed treatment efficiency, and easy biodegradation of polymers and other issues, to achieve the effect of improving the efficiency of sewage treatment, increasing the contact opportunities between phases, and reducing the price

Inactive Publication Date: 2014-07-02
NANJING TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the preparation process belongs to the synthesis of organic polymers, the process is cumbersome, the reaction requirements are strict, and the cost is high. At the same time, the polymers are easily biodegradable, which limits its wide application.
At the same time, the density of the polymer carrier is close to that of water, the relative flow velocity difference between the carrier and the liquid phase in the upflow zone of the fluidized bed is small, and the friction of the solid-liquid contact surface is weak, which makes the dynamic turbulence between the carrier and the liquid phase Poor, it is easy to cause the boundary layer of the carrier biofilm cell mass transfer concentration to tend to be stable and restrict the mass transfer efficiency
This situation is more prominent in the downflow zone of the fast mass transfer biological fluidized bed. Under the non-dynamic gravity field, the relative velocity difference between the carrier particles and the liquid phase is very small, and the mass transfer efficiency between the phases is lower. It is easy to cause uneven distribution and affect the mass transfer of microorganisms, thereby reducing the treatment efficiency of the fluidized bed

Method used

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  • Multi-hole foam glass carrier for fast mass transfer biological fluidized bed and preparation method and application thereof
  • Multi-hole foam glass carrier for fast mass transfer biological fluidized bed and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Clean the bottle glass, and after drying, ball-mill it into glass powder below 200 mesh; mix 5Kg of bottle glass powder, 1.68Kg of volcanic rock, 0.8Kg of fly ash, 0.2Kg of coal gangue, 0.5Kg of slag, Put 1Kg of iron powder, 0.5Kg of aluminum powder, 0.1Kg of polyethylene glycol-400, 0.1Kg of silicon carbide, 0.06Kg of sodium phosphate and 0.06Kg of mullite into a ball mill jar and mill to 200 mesh The following steps are added to the mold for foaming: in the preheating stage, the temperature is raised from room temperature to 300°C at a rate of 5°C / min and kept for 20 minutes; in the rapid sintering stage, the temperature is raised from 300°C to 730°C at a rate of 15°C / min and Keep warm for 10 minutes; in the foaming stage, raise the temperature from 730°C to 850°C at a rate of 9°C / min and hold for 20 minutes; After annealing to 400°C, the temperature is rapidly lowered at a rate of 12°C / min to obtain a porous foam glass carrier for rapid mass transfer biological fluid...

Embodiment 2

[0052] Clean the flat glass, and after drying, ball-mill it into glass powder below 200 mesh; mix 5Kg of flat glass powder, 1.2Kg of volcanic rock, 0.87Kg of fly ash, 0.2Kg of coal gangue, 0.7Kg of slag, and 1.07Kg of Iron powder, 0.55Kg of aluminum powder, 0.12Kg of polyvinyl alcohol, 0.14Kg of carbon black, 0.07Kg of sodium dihydrogen phosphate and 0.08Kg of borax mixture are put into a ball mill jar, and ball milled to below 200 mesh and added to a mold for Foaming: In the preheating stage, raise the temperature from room temperature to 300°C at a rate of 6°C / min and keep it warm for 25 minutes; In the soaking stage, the temperature was raised from 730°C to 860°C at a heating rate of 10°C / min and held for 25 minutes; in the rapid cooling stage, the cooling rate was 14°C / min, and the temperature was dropped to 615°C for 35 minutes; in the annealing stage, the cooling rate was 1°C / min. min, after annealing to 410°C, the temperature was rapidly lowered at a rate of 18°C / min to...

Embodiment 3

[0057] Clean the glass of discarded laboratory instruments, and ball-mill it into glass powder below 200 mesh after drying; 3Kg of discarded laboratory instrument glass glass powder, 1.5Kg of volcanic rock, 1.6Kg of fly ash, 0.8Kg of coal gangue, Put 0.65Kg of slag, 1.45Kg of iron powder, 0.65Kg of aluminum powder, 0.1Kg of polyvinyl alcohol, 0.1Kg of carbon black, 0.08Kg of sodium dihydrogen phosphate and 0.07Kg of borax mixture into the ball mill tank, and ball mill Fill the mold below 200 mesh for foaming: in the preheating stage, raise the temperature from room temperature to 310°C at a rate of 7°C / min and keep it warm for 25 minutes; in the stage of rapid sintering, raise the temperature from 310°C to 740°C and hold for 15 minutes; in the foaming stage, raise the temperature from 740°C to 870°C at a rate of 11°C / min and hold for 23 minutes; in the rapid cooling stage, cool down to 620°C and hold for 37 minutes at a rate of 15°C / min; in the annealing stage , the cooling ra...

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Abstract

The invention relates to a porous foam glass carrier used in a rapid mass transfer biological fluidized bed and its preparation method and application, and belongs to sewage treatment technology. It is made of waste glass as raw material, mixed with volcanic rock, fly ash, coal gangue, slag, iron powder, aluminum powder, binder, foaming agent, foam stabilizer and flux according to the mass percentage. Through preheating, rapid The sintering, foaming, rapid cooling and annealing stages are porous foam glass. The preparation process route of the present invention is simple, easy to control, and has low production cost. The prepared carrier has stable performance, high porosity, large specific surface area, impact resistance, good mechanical properties, high bioaffinity, and is conducive to the efficient immobilization of microorganisms. It is applicable in a rapid mass transfer biological fluidized bed. It solves the problems of previous biological immobilization carriers in fast mass transfer biological fluidized beds such as easy wear, small amount of film hanging, and low mass transfer effect. This method not only opens up a new way for the preparation of biological carriers, but also fills the gap in the use of foam glass materials in sewage treatment.

Description

technical field [0001] The invention relates to a porous foam glass carrier used for rapid mass transfer biological fluidized bed and its preparation method and application, belonging to the sewage treatment technology. The porous foam glass carrier GM-2 with suitable density is made from waste glass, volcanic rock, slag and other wastes through a simple process. It has low cost and stable performance, and is suitable for rapid mass transfer biological fluidized bed. Background technique [0002] Biological fluidized bed (FBR) wastewater treatment technology is a high-efficiency wastewater biological treatment process developed in the 1970s. It increases the gas-liquid-solid three The relative flow velocity between phases is poor, which accelerates the mass transfer between phases and the replacement of old and new microorganisms, thereby greatly improving the efficiency of biological wastewater treatment. Compared with other bioreactors, the biological fluidized bed has hi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C11/00C02F3/00C02F3/28
Inventor 沈树宝陆蓓蓓陈英文冯杨阳祝社民呼晓明蒋钰
Owner NANJING TECH UNIV
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