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Method for preparing high-performance tin phosphorus bronze band

A tin-phosphor bronze strip and high-performance technology, which is applied in the field of preparation of tin-phosphor bronze strips, can solve the problems of increasing production costs, reducing yield, and no obvious improvement in regional segregation, and achieving high quality and yield of finished products, reducing The effect of casting internal stress and shortening production cycle

Inactive Publication Date: 2013-07-10
宁波市鄞州锡青铜带制品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the strip homogenization annealing in the above-mentioned production process is a rather time-consuming and power-consuming process, which is usually carried out in a bell furnace
The uniform annealing temperature of the blank is 670-710°C, generally 16-20 hours. Each ton of tin bronze strip consumes about 100 degrees of electricity, 1.5 liters of liquid nitrogen, and 1.2 kg of liquid ammonia, which greatly improves production costs and economic benefits. relatively poor
[0003] With the existing industrial technology, no matter how high the homogenizing annealing temperature and how long the holding time is used, there is no obvious improvement effect on the regional segregation. The homogenizing annealing of the billet can only eliminate the intragranular segregation and eliminate the casting internal stress.
The intragranular segregation can be completely eliminated by several times of intermediate annealing, but because the plasticity of the general casting strip is too low, the edges are broken after rolling, and there are many broken strips, which reduces the yield. If the processing rate of cold billet rolling is too small, If the thickness after rolling is too large, it will inevitably increase the number of intermediate annealing in the future, and the economic benefit is not very obvious

Method used

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  • Method for preparing high-performance tin phosphorus bronze band

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Production and production of C5102 brand bronze, hard state, strip material with a specification of 0.2×150mm, the ratio of tin, phosphorus and copper is adjusted to make a furnace charge of 4.5% tin, 0.03% phosphorus, and the balance copper.

[0022] Put the furnace material into the melting furnace, melt the furnace material in the atmosphere and raise the temperature to 1180°C, stir and remove the slag for sampling and analysis using a direct-reading spectrometer for analysis, and transfer the ingredients to the holding furnace after the ingredients meet the formula ratio. The temperature of the copper liquid in the holding furnace is 1140°C. The liquid surface of the holding furnace is covered with dry rice bran, and then samples are taken for analysis, and the composition is adjusted. After the composition meets the formula ratio, horizontal continuous casting is carried out. The casting temperature is 1180°C. Pushing the 2.5mm process, the casting speed is 178mm / mi...

Embodiment 2

[0025] Production of C5102 brand bronze, hard state, strip material with a specification of 0.2×150mm, the proportion of tin, phosphorus and copper is adjusted to make a furnace charge of 5.5% tin, 0.05% phosphorus, and the balance copper.

[0026] Put the furnace material into the melting furnace, melt the furnace material in the atmosphere and raise the temperature to 1240 °C, stir the slag for sampling and analysis, and use a direct-reading spectrometer for analysis. The ingredients meet the formula ratio and then transfer to the holding furnace. The temperature of the copper liquid in the holding furnace is 1200°C, and the liquid surface of the holding furnace is covered with dry rice bran, and then samples are taken for analysis, and the composition is adjusted. After the composition meets the formula ratio, horizontal continuous casting is carried out. The casting temperature is 1200°C. Push the 1.6mm process, the casting speed is 160mm / min, the strip outlet temperature i...

Embodiment 3

[0029] Production of C5102 brand bronze, hard state, strip material with a specification of 0.2×150mm, the proportion of tin, phosphorus and copper is adjusted to make a furnace charge of 5.0% tin, 0.35% phosphorus, and the balance copper.

[0030] Put the furnace material into the melting furnace, melt the furnace material in the atmosphere and raise the temperature to 1180°C, stir and remove the slag for sampling and analysis using a direct-reading spectrometer for analysis, and transfer the ingredients to the holding furnace after the ingredients meet the formula ratio. The temperature of the copper liquid in the holding furnace is 1140°C, and the liquid surface of the holding furnace is covered with dry rice bran, and then samples are taken for analysis, and the composition is adjusted. After the composition meets the formula ratio, horizontal continuous casting is carried out. The casting temperature is 1140°C. Push the 3.2mm process, the casting speed is 190mm / min, the st...

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Abstract

The invention provides a method for preparing a high-performance tin phosphorus bronze band. The method comprises the following steps of: dosing, melting, stirring, removing slag, analyzing by sampling and regulating ingredients; then carrying out horizontal continuous casting, thus a tin phosphorus bronze band coil billet with the thickness of 14.0-16.5mm, the width of 210-430mm, and the length of 45-68m is obtained by pulling, stopping and reversely returning; carrying out face milling, reducing the thickness of each face by 0.5-0.8mm through milling, rolling the coil band until the thickness of 3.4-9mm through primary direct cogging; carrying out crude rolling until the thickness of 1.2-4.5mm on the coil band after the primary intermediate annealing; carrying out acid pickling and passivation on the coil band after secondary intermediate annealing; and finally carrying out cold precision rolling, low-temperature thermal treatment of a finished product, surface acid pickling and passivation and stretch bending and leveling, wherein the band thickness after the cold precision rolling is 0.06-1.2mm, namely the band thickness of the finished product. Through utilizing the method provided by the invention, the billet uniform annealing working procedure is omitted, the production cost is lowered, and the production cycle is shortened.

Description

technical field [0001] The invention relates to a preparation method of a tin-phosphorus bronze strip, in particular to a method for producing a high-performance tin-phosphorus bronze strip by direct cold blanking. Background technique [0002] Tin phosphor bronze containing more than 4% tin is usually not hot-rolled because of its narrow thermoplastic temperature range and severe hot-rolling cracking. Mainly due to the characteristics of the chemical composition of tin phosphor bronze, the cast tin phosphor bronze strip blank has serious reverse segregation phenomenon and casting internal stress. The reverse segregation leads to uneven chemical composition and plasticity decline of the strip, and casting stress leads to obvious plasticity decline and deformation. Resistance has also increased. However, the traditional methods both at home and abroad use strip uniform annealing to eliminate segregation, improve strip plasticity, and reduce rolling force. That is to say, mo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22F1/08B22D11/16
Inventor 祝福泉唐存国
Owner 宁波市鄞州锡青铜带制品有限公司
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