Polybutadiene Nano powder rubber toughening polypropylene composite and preparation method thereof
A technology of nano-powder and polybutadiene, which is applied in the field of modified polypropylene, that is, polybutadiene nano-powder rubber-toughened polypropylene composition, which can solve complex modification process, high melting temperature and low toughening efficiency and other problems, to achieve the effect of simplifying the modification process, good thermal stability, and improving toughening efficiency
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Embodiment 1
[0022] The composition of polybutadiene nano-powder rubber toughened polypropylene comprises: polypropylene and nano-powder rubber, the parts by weight of which are 90-99.5 kg of polypropylene and 0.5-10 kg of nano-powder rubber; The powder rubber comprises polybutadiene nanometer powder latex and crosslinking sensitizer with complete crosslinking structure, and in the described parts by weight of nanometer powder rubber, polybutadiene nanometer powder latex and crosslinking sensitizer The ratio of parts by weight is 95-99.99 parts of polybutadiene nano powder latex and 0.01-5 parts of crosslinking sensitizer; Butadiene and styrene The ratio of parts by weight is 95-100 parts of butadiene and 0-5 parts of styrene.
Embodiment 2
[0024] The composition of the polybutadiene nano powder rubber toughened polypropylene, the crosslinking sensitizer is n-butyl methacrylate or trimethylol propane trimethacrylate or trimethylol propane Triacrylate or n-butyl acrylate.
Embodiment 3
[0026] The preparation method of the composition of polybutadiene nano-powder rubber toughened polypropylene comprises taking 95-99.99 kg of polybutadiene nano-powder latex and 0.01-5 kg of cross-linking sensitizer according to the ratio of parts by weight and uniformly mixing them at room temperature Under the conditions, use cobalt source or electron accelerator radiation vulcanization and vacuum spray drying to make nano powder rubber, weigh 0.5-10 kg of nano powder rubber and 90-99.5 kg of polypropylene in a twin-screw extruder Blending, extrusion and granulation within the temperature range of 180-210°C. The polybutadiene nano-powder latex is pre-radiated and vulcanized by cobalt source irradiation, and an active monomer sensitizer (bifunctional or multifunctional active monomer) is added to reduce the radiation dose and degradation. After vacuum spray drying, fully vulcanized polybutadiene nano powder rubber (gel fraction ≥ 97%) with a particle size of 50-100 nm is pre...
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