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Polybutadiene Nano powder rubber toughening polypropylene composite and preparation method thereof

A technology of nano-powder and polybutadiene, which is applied in the field of modified polypropylene, that is, polybutadiene nano-powder rubber-toughened polypropylene composition, which can solve complex modification process, high melting temperature and low toughening efficiency and other problems, to achieve the effect of simplifying the modification process, good thermal stability, and improving toughening efficiency

Inactive Publication Date: 2010-06-23
TECHN PHYSICS INST HEILONGJIANG ACADOF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In the modification of rubber-plastic blends, for incompatible systems, a certain component is usually modified first, and then used as a compatibilizer to increase the interfacial effect in the blend system. The mechanical properties can be improved programmatically, but due to problems such as uniform dispersion, stability, and phase domain size (micron or submicron), the toughening efficiency is low, the modification process is complicated, the melting temperature is high, and the energy consumption is large.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The composition of polybutadiene nano-powder rubber toughened polypropylene comprises: polypropylene and nano-powder rubber, the parts by weight of which are 90-99.5 kg of polypropylene and 0.5-10 kg of nano-powder rubber; The powder rubber comprises polybutadiene nanometer powder latex and crosslinking sensitizer with complete crosslinking structure, and in the described parts by weight of nanometer powder rubber, polybutadiene nanometer powder latex and crosslinking sensitizer The ratio of parts by weight is 95-99.99 parts of polybutadiene nano powder latex and 0.01-5 parts of crosslinking sensitizer; Butadiene and styrene The ratio of parts by weight is 95-100 parts of butadiene and 0-5 parts of styrene.

Embodiment 2

[0024] The composition of the polybutadiene nano powder rubber toughened polypropylene, the crosslinking sensitizer is n-butyl methacrylate or trimethylol propane trimethacrylate or trimethylol propane Triacrylate or n-butyl acrylate.

Embodiment 3

[0026] The preparation method of the composition of polybutadiene nano-powder rubber toughened polypropylene comprises taking 95-99.99 kg of polybutadiene nano-powder latex and 0.01-5 kg ​​of cross-linking sensitizer according to the ratio of parts by weight and uniformly mixing them at room temperature Under the conditions, use cobalt source or electron accelerator radiation vulcanization and vacuum spray drying to make nano powder rubber, weigh 0.5-10 kg of nano powder rubber and 90-99.5 kg of polypropylene in a twin-screw extruder Blending, extrusion and granulation within the temperature range of 180-210°C. The polybutadiene nano-powder latex is pre-radiated and vulcanized by cobalt source irradiation, and an active monomer sensitizer (bifunctional or multifunctional active monomer) is added to reduce the radiation dose and degradation. After vacuum spray drying, fully vulcanized polybutadiene nano powder rubber (gel fraction ≥ 97%) with a particle size of 50-100 nm is pre...

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Abstract

The invention relates to a polybutadiene nano powder rubber toughening polypropylene composite and a preparation method thereof; at present, the correlational research that the polybutadiene nano powder rubber is used for modifying polypropylene in a blending way; the composite comprises the following ingredients by weight parts: 90-99.5 parts of polypropylene and 0.5-10 parts of nano powder rubber; the nano powder rubber comprises polybutadiene nano powder rubber latex with a complete cross-linked structure and crosslinking sensitizing agents, in the weight part ratio of the nano powder rubber, the polybutadiene nano powder rubber latex and the crosslinking sensitizing agents are 95-99.99 parts and 0.01-5 parts respectively by weight part, in the weight part ratio of the polybutadiene nano powder rubber latex, butadiene and styrene are 95-100 parts and 0-5 parts respectively by weight parts; the polybutadiene nano powder rubber toughening polypropylene composite is used for remodeling polypropylene.

Description

Technical field: [0001] The invention relates to a composition of modified polypropylene, that is, polybutadiene nano-powder rubber toughened polypropylene and a preparation method of the composition. Background technique: [0002] Polypropylene (PP) is one of the three major plastics whose output is second only to polyethylene and polyvinyl chloride. It has excellent heat resistance, chemical corrosion resistance and electrical insulation, and has good processing performance, so it is widely used in machinery, chemical industry, electric power and transportation and other fields. However, polypropylene has poor toughness and notch sensitivity due to its high crystallinity and coarse spherulite size, especially at low temperature (the embrittlement temperature is only 8°C), which limits its application in a wider range of fields. Therefore, the research on the toughening modification of polypropylene has always been a research hotspot in this field at home and abroad. [0...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L51/04B29B9/02B29C47/92B29C48/40B29C48/92
CPCB29C48/92B29C2948/92704B29C48/04B29C48/40B29C2948/92895
Inventor 刘宇光侯静张学全高德玉董伟
Owner TECHN PHYSICS INST HEILONGJIANG ACADOF SCI
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