Thermal-activated adhesive film and method of producing the same
A technology of heat activation and adhesive film, which is applied in the direction of adhesives, epoxy resin glue, natural rubber adhesive, etc., can solve the problems of curing time in polluted environment, poor storage stability, high cost, etc., and achieve simple and environmentally friendly preparation process and convenient operation , low cost effect
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Embodiment 1
[0018] Example 1, accurately weigh 1000g of nitrile-40 rubber, 1000g of active calcium carbonate powder, 70g of zinc oxide, 100g of F-44, 350g of E-20, 250g of phenolic resin, 100g of benzoxazine, 30g of dinitrile amine, and a film package Sealed propylene-based thiourea 30g, first roll the rubber on the open mill, then add filler, vulcanized rubber composition, resin and mix evenly on the open mill, finally add crosslinking agent and accelerator to disperse evenly, and then calender Formed into a film with a thickness of 0.15 mm.
[0019] Put the above film between 45# steel sheets, hot press at 180°C and 3MPa pressure for 10s to obtain a sample, the shear strength of which is measured to be 13Mpa; the storage period at 40°C exceeds 20 days, and the storage period at room temperature is 10 months.
Embodiment 2
[0023] Example 2, accurately weigh 3500g of natural rubber, 2000g of mica powder, 1000g of alumina powder, 180g of stearic acid, 10g of N-cyclohexylbenzothiazole sulfenic acid amine, 10g of anti-aging D, 1500g of FB resin, bisphenol A Novolac resin 1500g, hexamethoxymethyl melamine 100g, methylol melamine 200g, ethylene thiourea 100g, first rubber is rolled on the open mill, then add filler, vulcanized rubber composition, resin in the open Mix evenly on the mill, and finally add cross-linking agent and accelerator to disperse evenly, and then calender to form a film with a thickness of 0.15mm.
Embodiment 3
[0024] Embodiment 3, accurately weigh 1500g of butadiene rubber, 1500g of carboxylated nitrile rubber, 2500g of bentonite, 80g of magnesium oxide, 10g of N,N-diethyl-dithiocarbamate benzothiazolyl, antioxidant MBZ10g, F- 44 Novolak epoxy resin 2500g, boron trifluoride piperidine complex 100g, first roll the rubber on the open mill, then add filler, vulcanized rubber composition, resin and mix evenly on the open mill, and finally add The cross-linking agent and accelerator are uniformly dispersed, and then calendered to form a film with a thickness of 0.10 mm.
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