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Thermal-activated adhesive film and method of producing the same

A technology of heat activation and adhesive film, which is applied in the direction of adhesives, epoxy resin glue, natural rubber adhesive, etc., can solve the problems of curing time in polluted environment, poor storage stability, high cost, etc., and achieve simple and environmentally friendly preparation process and convenient operation , low cost effect

Inactive Publication Date: 2012-05-30
YANTAI DARBOND TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The invention mainly solves the problems of the existing glue film that the environment is polluted by solvent volatilization, the curing time is long, the storage stability is poor, the glue overflow phenomenon exists in curing, and the cost is high.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1, accurately weigh 1000g of nitrile-40 rubber, 1000g of active calcium carbonate powder, 70g of zinc oxide, 100g of F-44, 350g of E-20, 250g of phenolic resin, 100g of benzoxazine, 30g of dinitrile amine, and a film package Sealed propylene-based thiourea 30g, first roll the rubber on the open mill, then add filler, vulcanized rubber composition, resin and mix evenly on the open mill, finally add crosslinking agent and accelerator to disperse evenly, and then calender Formed into a film with a thickness of 0.15 mm.

[0019] Put the above film between 45# steel sheets, hot press at 180°C and 3MPa pressure for 10s to obtain a sample, the shear strength of which is measured to be 13Mpa; the storage period at 40°C exceeds 20 days, and the storage period at room temperature is 10 months.

Embodiment 2

[0023] Example 2, accurately weigh 3500g of natural rubber, 2000g of mica powder, 1000g of alumina powder, 180g of stearic acid, 10g of N-cyclohexylbenzothiazole sulfenic acid amine, 10g of anti-aging D, 1500g of FB resin, bisphenol A Novolac resin 1500g, hexamethoxymethyl melamine 100g, methylol melamine 200g, ethylene thiourea 100g, first rubber is rolled on the open mill, then add filler, vulcanized rubber composition, resin in the open Mix evenly on the mill, and finally add cross-linking agent and accelerator to disperse evenly, and then calender to form a film with a thickness of 0.15mm.

Embodiment 3

[0024] Embodiment 3, accurately weigh 1500g of butadiene rubber, 1500g of carboxylated nitrile rubber, 2500g of bentonite, 80g of magnesium oxide, 10g of N,N-diethyl-dithiocarbamate benzothiazolyl, antioxidant MBZ10g, F- 44 Novolak epoxy resin 2500g, boron trifluoride piperidine complex 100g, first roll the rubber on the open mill, then add filler, vulcanized rubber composition, resin and mix evenly on the open mill, and finally add The cross-linking agent and accelerator are uniformly dispersed, and then calendered to form a film with a thickness of 0.10 mm.

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PUM

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Abstract

The invention discloses a thermal activating glue film. The thermal activating glue film is characterized by consisting of resin, rubbers, fillings, a cross linker, a perduren compound and a promoter which are melted and mixed by a mixing mill and then calendered into a film. The thermal activation glue film is a thermal activating glue film which has the advantages of fast solidifying speed, excellent storage stability and high solidifying intensity, temperature resistance, environment protection and low cost.

Description

Technical field: [0001] The invention relates to the technical field of adhesive films, in particular to a thermally activated adhesive film and a preparation method thereof, in particular to a thermally activated adhesive film with fast curing speed, temperature resistance and stable storage under hot pressing. Background technique: [0002] The adhesive film is usually non-tacky at room temperature, but it melts or cross-links and solidifies under heat and pressure to bond the adherend. There are many types of existing adhesive films according to different raw materials and uses, some have a long curing time, some have poor storage stability, some have glue overflow after curing, some have high cost, and as we all know, there are many adhesive films at present. It is a solvent method process, that is, all substances are first dissolved in a solvent, mixed evenly and then coated, and the required film is formed after the solvent volatilizes. This process is relatively compl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/00C09J163/00C09J171/10C09J161/06C09J179/02C09J107/00C09J109/00C09J133/04C09J123/22C09J109/06C09J109/02
Inventor 庄恒冬王建斌解海华
Owner YANTAI DARBOND TECH
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