581results about "Petroleum wax recovery" patented technology

A premium synthetic lubricating oil base stock having a high VI and low pour point is made by hydroisomerizing a Fischer-Tropsch synthesized waxy, paraffinic feed wax and then dewaxing the hydroisomerate to form a 650-750 DEG F.+ dewaxate. The waxy feed has an initial boiling point in the range of about 650-750 DEG F., from which it continuously boils up to at least 1050 DEG F. and has a T90-T10 temperature difference of at least 350 DEG F. The feed is preferably hydroisomerized without any pretreatment, other than optional fractionation. The 650-750 DEG F.+ dewaxate is fractionated into two or more base stocks of different viscosity.

A lubricating base stock useful for forming lubricants such as a multigrade automotive oils, automatic transmission oils, greases and the like is prepared by hydroisomerizing a waxy hydrocarbon feed fraction having an initial boiling point in the 650-750 DEG F. range and an end point of at least 1050 DEG F., synthesized by a slurry Fischer-Tropsch hydrocarbon synthesis process. The hydroisomerization forms a hydroisomerate containing the desired base stock which is recovered, without dewaxing the hydroisomerate. The hydroisomerization is conducted at conditions effective to convert at least 67 wt. % of the 650-750 DEG F.+ waxy feed hydrocarbons to lower boiling hydrocarbons. When combined with a standard lubricant additive package, these base stocks have been formed into multigrade automotive crankcase oils, transmission oils and hydraulic oils meeting the specifications for these oils.

A process for dewaxing waxy hydrocarbonaceous materials, such as hydrocarbon fuel and lubricating oil fractions to reduce their cloud and pour points comprises reacting the material with hydrogen in the presence of a dewaxing catalyst comprising at least one metal catalytic component and ferrierite in which at least a portion of its cation exchange positions are occupied by one or more trivalent rare earth metal cations. The rare earth ion exchanged ferrierite catalyst has good selectivity for lubricating oil production, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate. Preferably at least 10% and more preferably at least 15% of the ferreirite cation exchange capacity is occupied by one or more trivalent rare earth metal cations.

The invention discloses an efficient paraffin sweatbox. The sweatbox comprises an inner cavity, a heating layer, a heating tube, an outer water inlet tube, a feeding tube, an inner water inlet tube, an inner water outlet tube, an outer water outlet tube and a discharging tube, wherein a heating tube which is arranged in a rotating mode is arranged inside the inner cavity; the feeding tube is arranged on the upper part of the inner cavity; the discharging tube is arranged on the lower part of the inner cavity; the heating layer is arranged outside the inner cavity; the external water inlet tube is arranged on the upper part of the heating layer; the outer water outlet tube is arranged on the lower part of the heating layer; the inner water inlet tube connected to the outer side of the inner cavity is arranged on the upper part of the heating tube; and the inner water outlet tube connected to the outer side of the inner cavity is arranged at the lower side of the heating tube. The heating tube which is extended like a spring in a rotating mode is arranged inside the effective paraffin sweatbox, so that the paraffin is heated uniformly; and the efficient paraffin sweatbox is used in the industry.

A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.

A process for manufacturing a finished lubricant by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an isomerized oil; and d) hydrofinishing said isomerized oil, whereby a lubricating base oil is produced having specific desired properties; and e) blending the lubricating base oil with at least one lubricant additive.

A dewaxing process for lowering the haze point of a bright stock which includes contacting a bright stock in the presence of added hydrogen gas with a Zeolite EU-1 catalyst in combination with a ZSM-48 and / or SSZ-32 catalyst.

A high VI and low pour point lubricant base stock is made by hydroisomerizing a high purity, waxy, paraffinic Fischer-Tropsch synthesized hydrocarbon fraction having an initial boiling point in the range of 650-750° F., followed by catalytically dewaxing the hydroisomerate using a dewaxing catalyst comprising a catalytic platinum component and an H-mordenite component. The hydrocarbon fraction is preferably synthesized by a slurry Fischer-Tropsch using a catalyst containing a catalytic cobalt component. This combination of the process, high purity, waxy paraffinic feed and the Pt / H-mordenite dewaxing catalyst, produce a relatively high yield of premium lubricant base stock.

The present invention is a process for producing a high viscosity index and low pour point lubricating oil base stock which comprises catalytically converting a hydrotreated hydrocarbon lube oil feedstock containing waxy paraffins in the presence of hydrogen and in the presence of a low acidity ZSM-5 catalyst having a highly dispersed noble metal component. The ZSM-5 catalyst is subjected to controlled acidity reduction to an alpha value below 15 prior to incorporation of the noble metal component.

A wide-cut lubricant base stock is made by hydroisomerizing and then catalytically dewaxing a waxy Fischer-Tropsch synthesized hydrocarbon fraction feed and comprises the entire dewaxate having an initial boiling point in the 650-75O° F.+ range. Formulated lubricating oils made by admixing the base stock with a commercial automotive additive package meet all specifications, including low temperature properties, for multigrade internal combustion engine crankcase oils. The waxy feed has an initial boiling point in the 650-750° F. range and continuously boils to an end point of at least 1050° F.+. Lower boiling hydrocarbons produced by the process are separated from the base stock by simple flash distillation. The base stock comprises the entire dewaxate having an initial boiling point in the 650-750° F. range.

A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.

A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.

Blended lubricant base oils and blended finished lubricants comprising ≧70 weight percent Fischer-Tropsch derived lubricant base oils comprising ≧6 weight % molecules with monocycloparaffinic functionality and less than 0.05 weight % molecules with aromatic functionality; at least one polyalphaolefin lubricant base oil with a kinematic viscosity at 100° C. greater than about 30 cSt and less than 150 cSt are provided. These blended lubricant base oils and blended finished lubricants exhibit superior friction and wear properties, in addition to other highly desired properties. Also provided are processes for making these blended lubricant base oils and blended finished lubricants.

A premium synthetic lubricating oil base stock having a high VI and low pour point is made by hydroisomerizing a Fischer-Tropsch synthesized waxy, paraffinic feed wax and then dewaxing the hydroisomerate to form a 650-750° F.+ dewaxate. The waxy feed has an initial boiling point in the range of about 650-750° F., from which it continuously boils up to at least 1050° F. and has a T90-T10 temperature difference of at least 350° F. The feed is preferably hydroisomerized without any pretreatment, other than optional fractionation. The 650-750° F.+ dewaxate is fractionated into two or more base stocks of different viscosity.

A process for producing one or more white oils, by: a) hydroisomerization dewaxing a waxy feed with a defined composition over a highly selective and active wax hydroisomerization catalyst with a defined composition under conditions sufficient to produce a white oil; and b) collecting one or more white oils, wherein the yield of white oils is high, and they have a low pour point and a good Saybolt color. Also, a process for producing medicinal grade white oils, by a)hydroisomerization dewaxing a waxy feed with a defined composition over a highly selective and active wax hydroisomerization catalyst with a defined composition under conditions sufficient to produce a white oil, b) collecting technical grade white oils having a low pour point and good Saybolt color in high yield, and c) hydrofinishing the technical grade white oils at conditions sufficient to produce medicinal grade white oils that pass the RCS test.

A method for producing lubricant base oils is provided comprising the steps of: (a) separating a feedstock into a light lubricant base oil fraction and a heavy fraction; (b) hydroisomerizing the fractions over a medium pore size molecular sieve catalyst under hydroisomerization conditions to produce an isomerized light lubricant base oil fraction having a pour point less than or equal to a target pour point of the lubricant base oils and an isomerized heavy fraction having a pour point of equal to or greater than the target pour point of the lubricant base oils and a cloud point greater than the target cloud point of the lubricant base oils; and (c) dehazing the isomerized heavy fraction to provide a heavy lubricant base oil having a pour point less than or equal to the target pour point of the lubricant base oils and a cloud point less than or equal to the target cloud point of the lubricant base oils.

This invention relates to processes of producing lubricant base oils comprising paraffinic hydrocarbon components that have optimized branching. The lubricant base oils comprising paraffinic hydrocarbon components with optimized branching have low amounts of branching with the branching concentrated toward the center of the lubricant base oil molecules. The lubricant base oils comprising paraffinic hydrocarbon components with optimized branching have low pour points and extremely high viscosity indexes. The invention further relates to processes of producing commercial lubricants comprising the lubricant base oils comprising paraffinic hydrocarbon components with optimized branching from waxy feeds.

The invention disclosed a catalyst to lower the freezing point of the diesel oil. The catalyst includes carrier that contains reshaped molecular sieve and hydrogenated metal. The molecular sieve is reshaped by VIB group metal, the content of which in the molecular sieve is 1wt%-40wt% (by oxidation state). The content of the molecular sieve and the metal are 10wt%-90wt% (by oxidation state) and 0.1wt%-40wt% (by oxidation state) respectively. The reshaping agent can modify the acid substance and the bore size on the surface of the molecular sieve so as to match the catalyst's isomerizing function and structure-selective splitting function well; it can make the splitting reaction proceeds according to the lock-and-key mechnanism and ensure the reaction proceeds properly without over splitting; it can improve the quality of the diesel oil and increase its yield. The invention can be used in the deparaffinage of the material that contains wax, especially in the process to lower the freezing point of the diesel oil distillate. It can not only lower the freezing point, but also increase the diesel oil yield substantially.

A process for manufacturing a lubricating base oil by: a) performing Fischer-Tropsch synthesis on syngas to provide a product stream; b) isolating from said product stream a substantially paraffinic wax feed having less than about 30 ppm total nitrogen and sulfur, and less than about 1 wt % oxygen; c) dewaxing said feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, wherein the hydroisomerization temperature is between about 600° F. (315° C.) and about 750° F. (399° C.), to produce an is dimerized oil; and d) hydrofinishing said isomerized oil to produce a lubricating base oil having specific desired properties.

The invention discloses a diesel oil hydrogenation pour point depressing method. A series flow of hydrofining and hydrogenation pour point depressing is adopted in the method, wherein a hydrogenation pour point depressing catalyst is modified by metal auxiliary agent and silicon, effectively regulates the acidity and orifice shape of the inner surface and the outer surface of a shape-selective cracking molecular sieve, is favorable for dispersing wax molecules in a diesel oil raw material into pore canals of the molecular sieve to perform shape-selective cracking reaction, and has high catalytic activity and selectivity of a target product; and because the acidity of the outer surface of the molecular sieve is weak, side reactions such as secondary cracking and the like are reduced, the pour point depressing effect of the diesel oil is good, and the fraction yield of the diesel oil is high.

This invention relates to processes of producing lubricant base oils comprising paraffinic hydrocarbon components that have optimized branching. The lubricant base oils comprising paraffinic hydrocarbon components with optimized branching have low amounts of branching with the branching concentrated toward the center of the lubricant base oil molecules. The lubricant base oils comprising paraffinic hydrocarbon components with optimized branching have low pour points and extremely high viscosity indexes. The invention further relates to processes of producing commercial lubricants comprising the lubricant base oils comprising paraffinic hydrocarbon components with optimized branching from waxy feeds.

A process for manufacturing a lubricating base oil, comprising dewaxing a substantially paraffinic wax feed by hydroisomerization dewaxing using a shape selective intermediate pore size molecular sieve under hydroisomerization conditions including a hydrogen to feed ratio from about 712.4 to about 3562 liter H2 / liter oil, whereby a lubricating base oil is produced having a)a total weight percent of molecules with cycloparaffinic functionality greater than 10, and b) a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality greater than 30. Also a method for producing a base oil having a high ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality by hydroisomerization dewaxing a selected Fischer-Tropsch wax under hydroisomerization conditions including a hydrogen to feed ratio from about 712.4 to about 3562 liter H2 / liter oil. Also a lubricating base oil manufacturing plant.

Lubricant blends and finished gear oils comprising a lubricant base oil fraction derived from highly paraffinic wax, a petroleum derived base oil, and a pour point depressant are provided. The lubricant base oil fraction derived from highly paraffinic wax comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at −40° C.

The present application relates to methods for producing a lubricant base oil from a waxy hydrocarbon feed using a pre-sulfided shape selective, intermediate pore size, noble metal-containing molecular sieve catalyst. According to the present invention, a shape selective, intermediate pore size, noble metal-containing molecular sieve catalyst is pre-sulfided to provide a sulfided catalyst, wherein the molar ratio of sulfur to noble metal in the sulfided catalyst is greater than one, and a waxy hydrocarbon feed is hydroisomerized by contacting the waxy hydrocarbon feed with the sulfided catalyst at hydroisomerization conditions, to produce a lubricant base oil.

A process for producing a product slate, which includes at least three base oil grades having kinematic viscosities at 100° C. within the range between about 1.8 cSt and 30 cSt, from a waxy feed having an initial boiling point of about 340° C. or less and a final boiling point of about 560° C. or higher, said process comprising (a) isomerizing at least a portion of the waxy feed, whereby the amount of isoparaffins present are increased; (b) distilling a first portion of the isomerized waxy feed in light block mode operation into at least three base oil fractions having different boiling ranges; (c) distilling a second portion of the isomerized waxy feed in medium block mode operation into at least three base oil fractions having different boiling ranges; and (d) blending at least one base oil fraction produced from light block mode with at least one base oil fraction produced from medium block mode to produce a lubricating base oil blend meeting a target value for at least one pre-selected property.

Blended lubricant base oils and blended finished lubricants comprising ≧70 weight percent Fischer-Tropsch derived lubricant base oils comprising ≧6 weight % molecules with monocycloparaffinic functionality and less than 0.05 weight % molecules with aromatic functionality; at least one polyalphaolefin lubricant base oil with a kinematic viscosity at 100° C. greater than about 30 cSt and less than 150 cSt are provided. These blended lubricant base oils and blended finished lubricants exhibit superior friction and wear properties, in addition to other highly desired properties. Also provided are processes for making these blended lubricant base oils and blended finished lubricants.

A process for recovering paraffinic solvent from tailings produced in the treatment of bitumen froth comprising introducing the tailings into a tailings solvent recovery unit (TSRU), the TSRU having internals, and distributing the tailings over the internals. An inert gas or steam is then introduced below the internals and above the liquid pool for enhancing the vaporization of the contained solvent. Solvent is vaporized from asphaltene agglomerates. In one embodiment, the process is affected in the absence of mechanical means used to substantially break up asphaltene agglomerates or to prevent the agglomeration of asphaltene. In another aspect, the process comprises introducing the tailings into a first TSRU as described above and then into a second TSRU operated at a lower pressure. In another aspect, internals are optionally present and steam or inert gas is injected in the liquid pool.

Discloses novel biodegradable high performance hydrocarbon base oils useful as lubricants in engine oil and industrial compositions, and process for their manufacture. A waxy, or paraffinic feed, particularly a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions, at 700° F.+ conversion levels ranging from about 20 to 50 wt. %, preferably about 25-40 wt. %, sufficient to produce a crude fraction, e.g., a C5-1050° F.+ crude fraction, containing 700° F.+ isoparaffins having from about 6.0 to about 7.5 methyl branches per 100 carbon atoms in the molecule. The methyl paraffins containing crude fraction is topped via atmospheric distillation to produce a bottoms fraction having an initial boiling point between about 650° F. and 750° F. which is then solvent dewaxed, and the dewaxed oil is then fractionated under high vacuum to produce biodegradable high performance hydrocarbon base oils.

A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.