Tape member or sheet member, and method of producing tape member or sheet member
a technology of tape or sheet member and production method, which is applied in the direction of inorganic insulators, transportation and packaging, windings, etc., can solve the problems of insufficient heat conductivity of insulating layer in the case of electromagnetic production, and difficult handling of resin, etc., and achieve the effect of easily producing a highly heat conductive tape member or sheet member
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example 1
[0060]FIG. 1 shows a cross-sectional view of a mica tape member or a mica sheet member of the present invention. The mica tape member or the mica sheet member comprises a layer containing mica and a lining material, and the mica-containing layer consists of scaly particles 1, particles 2 having a heat conductivity of 0.5 W / mK or higher and a size of 1 μm or smaller (hereinafter, referred to as heat conductive particles), and a binder 3.
[0061]The scaly particles 1 contain at least one of mica and boron nitride.
[0062]The heat conductive particles 2 contain at least one of boron nitride, alumina, silicon nitride, magnesium oxide, carbon, aluminum nitride, silicon oxide (silica), artificial diamond, and titanium oxide.
[0063]Further, the lining material 6 may be a glass cloth or a polymer film such as a polyester, polyethylene terephthalate, and Nomex (trade name).
[0064]Boron nitride (HP-1CAW, manufactured by Mizushima Ferroalloy Co., Ltd.) was employed as the scaly particles 1, an isopr...
example 2
[0072]A tape member or sheet member of Example 2 of the invention was obtained by using a thermoplastic resin or a thermosetting resin as a binder. In Example 1, the water-soluble polymer was used as the binder. In a conventional method of producing a mica tape member or sheet member, since no water-soluble polymer is used, it results in a cost hike. To solve such a problem, the following mica paper was obtained.
[0073]As shown in FIG. 4, mica was used as the scaly particles 1, and the particles were stirred and mixed in distilled water 10 (S1) and the obtained solution was filtered (S2), after which the resulting paper filter was dried at 25° C. for 24 hours (S3) to obtain mica paper 14. On the other hand, a methyl isobutyl ketone slurry 11 of alumina with a size of 40 (nm) (alumina MIBK slurry) was used in place of a water slurry of alumina used in Example 1, and 20 (g) of liquid epoxy resin 12 (CY 225, manufactured by Ciba Specialty Chemicals Inc.) and 16 (g) of an acid anhydride ...
example 3
[0076]The techniques described in Examples 1 and 2 are techniques for holding nano-alumina with a size of 40 (nm) with the polymer type binders, and although the techniques improve the heat conduction, the heat conductivity of a polymer is at highest 0.5 (W / mK) or so and thus it is limited.
[0077]Therefore, a substance precipitated or synthesized by a sol-gel method and containing an organic type resin was used as a binder in Example 3. Specifically, as shown in FIG. 5, a metal alkoxide, e.g., 10 (ml) of tetraethoxysilane 16 (for example, manufactured by High Purity Chemistry), a water-based alumina slurry 18 obtained by mixing 15 (wt %) of alumina with a size of 40 (nm) in 20 (ml) of distilled water 17, and 10 (ml) of ethanol 19 were put in a beaker and stirred and mixed for 20 minutes by a stirrer (S7). After that, a catalyst, for example, 1 (ml) of hydrochloric acid (2N hydrochloric acid) 20 mixed with distilled water 21 was dropwise added to the obtained slurry mixture under stir...
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