Forming glue and application thereof
A technology of glue and zirconia, applied in the field of optical films, can solve the problems of low impact resistance against falling balls, easy crushing of the composite film, and easy occurrence of white spots, etc.
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Embodiment 1
[0022] This embodiment provides a molding glue, which includes the following components in parts by mass: 30 parts of o-phenylphenoxyethyl acrylate, 15 parts of ethoxylated bisphenol A dimethacrylate, initiator 0.5 parts, 3 parts of silicone additives, 8 parts of tetrahydrofurfuryl alcohol acrylate, 3 parts of trimethylol cyclohexyl acrylate and 4 parts of zirconia organic-inorganic hybrid acrylate;
[0023] Among them, the silicone additive is obtained by silicone emulsion polymerization; zirconia organic-inorganic hybrid acrylate is mainly composed of the following raw materials in parts by weight: 5 parts of zirconia sol, 1 part of organic solvent, 10 parts of acrylic resin; The sol is obtained by the following method: heating the sodium hydroxide solution to 60°C, adding a zirconium oxychloride solution accounting for 0.3 times the mass of the sodium hydroxide solution, and reacting the generated zirconium hydroxide, aging the zirconium hydroxide for 20 minutes, and then Z...
Embodiment 2
[0025] This embodiment provides a molding glue, which includes the following components in parts by mass: 35 parts of o-phenylphenoxyethyl acrylate, 20 parts of ethoxylated bisphenol A dimethacrylate, initiator 1.5 parts, 4 parts of silicone additives, 12 parts of tetrahydrofurfuryl alcohol propylene ester, 4 parts of trimethylol cyclohexyl acrylate and 6 parts of zirconia organic-inorganic hybrid acrylate;
[0026] Among them, the silicone additive is obtained by silicone emulsion polymerization; zirconia organic-inorganic hybrid acrylate is mainly composed of the following raw materials in parts by weight: 10 parts of zirconia sol, 2 parts of organic solvent, 15 parts of acrylic resin; The sol is obtained by the following method: after heating the sodium hydroxide solution to 65°C, adding a zirconium oxycarbonate solution accounting for 0.3 times the mass of the sodium hydroxide solution, and reacting the generated zirconium hydroxide, aging the zirconium hydroxide for 25 min...
Embodiment 3
[0028] This embodiment provides a molding glue, which includes the following components in parts by mass: 40 parts of o-phenylphenoxyethyl acrylate, 25 parts of ethoxylated bisphenol A dimethacrylate, initiator 2 parts, 6 parts of silicone additives, 16 parts of tetrahydrofurfuryl alcohol acrylate, 5 parts of trimethylol cyclohexyl acrylate and 8 parts of zirconia organic-inorganic hybrid acrylate;
[0029] Among them, the silicone additive is obtained by silicone emulsion polymerization; zirconia organic-inorganic hybrid acrylate is mainly composed of the following raw materials in parts by weight: 15 parts of zirconia sol, 3 parts of organic solvent, 20 parts of acrylic resin; The sol is obtained by the following method: after heating the sodium hydroxide solution to 70°C, adding a zirconium oxycarbonate solution accounting for 0.4 times the mass of the sodium hydroxide solution, and reacting the generated zirconium hydroxide, aging the zirconium hydroxide for 30 minutes, and...
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