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Soaping agent for polyester/cotton/spandex fabric and preparation method of soaping agent

A kind of soaping agent and fabric technology, which is applied in the field of soaping agent for polyester/cotton/ammonia fabrics and its preparation, and can solve the problems of destroying chromophoric groups, poor penetration cleaning effect, dye bond breaking and hydrolysis, etc.

Active Publication Date: 2021-05-11
TAICANG BAONI IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Regarding the removal of floating color of reactive dyes, soaping agents are used. There are four main categories: surfactant compounded substances, which have good effect but high soaping temperature and are not easy to clean; alkaline substances compounded surfactants, It is easy to cause dye bond breakage and hydrolysis, which will affect the shade; compound laccases can destroy the chromophoric group of dyes, but they are selective to dyes and can easily cause color changes; Neutralize part of the alkali, but the acidity is insufficient, it needs to be compounded with strong acidic substances and the effect of removing floating color is not ideal
For example, the patent "A Low-Temperature Non-foaming Soaping Agent and Its Preparation Method" (publication number: CN102093508B) uses a compound of horse-beta copolymer and protective colloid, which has good dispersibility for dyes, but the copolymer used The molecular weight is relatively large, and the surfactant is not compounded. Under low temperature conditions, it is difficult to enter the interior of the fiber, and the penetration cleaning effect is poor, which reduces the floating color removal effect.
[0005] To sum up, the existing cleaning auxiliaries in the industry are all effective for a single type of dye, and there is a lack of one that is effective for both disperse dyes and reactive dyes. Soaping agent with good removal effect

Method used

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  • Soaping agent for polyester/cotton/spandex fabric and preparation method of soaping agent
  • Soaping agent for polyester/cotton/spandex fabric and preparation method of soaping agent
  • Soaping agent for polyester/cotton/spandex fabric and preparation method of soaping agent

Examples

Experimental program
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preparation example Construction

[0056]The specific preparation process of the acidic trumper copolymer is: mixed with the comonomer represented by the formula (C) and a proper amount of deionized water, stirred at 30-40 ° C for 10-20 min, and the nitrogen gas is heated to 60-95 ° C. At the same time, the copolymer solution represented by the formula (D), the formula (E), as well as the initiator greasehenylmeloyl, acetone is a solvent, and the 1-2 h is added, and the insulation reaction is 1.5-4.5 h, cool to room temperature, The acetone solvent is removed by distillation, that is, acidic terpolymer.

[0057]In a preferred embodiment, the green surfactant is sodium amyl sulfonate, fatty alcohol (C = 10-14) polyoxyethylene ether (EO = 3-10), coconut fatty acid diethanolamide, alkane One or more of the oxosides, α-alkenylsulfonates, polyether foaming agents.

[0058]The present invention also provides the preparation method of the above polyester / cotton / ammonia fabric soapaged, including the steps of:

[0059]1) Add the ...

Embodiment 1

[0064]Soap lotion 1 # 组::

[0065]

[0066]In a four-mouth flask equipped with a stirrer, a thermometer, a reflux condenser, 35 g of dimethylformamide, 99 g (0.10 mol) of 10 hydroxy five-dolla melon, 25.22 g (0.13 mol) phthalic acid, access Nitrogen protection, stirring and warming up to 70 ° C, 0.19 g (0.15% of the total weight of the monomer) titanate, 3.38 g of 2-ethylhexanol, continued to heat up to 215 ° C, heat insulation reaction for 4 h, after cooling Decompression distillation, ie, water-soluble melon ring polymer 1 # (weight average molecular weight: 15890).

[0067]In the four-mouth flask equipped with a stirrer, a thermometer, a reflux condenser, 20.30 g (0.175 mol) maleic acid and 125 g of deionized water, stirred at 35 ° C for 15 min, and the nitrogen gas is warmed to 85 ° C, and add to the nitrogen gas The acetone (20 mL) solution containing 9.36 g (0.045 mol) 3-styrene thiopropate and 36.96 g (0.28 mol) 2-allyl thiionacetic acid, and 2.53 g (3.8% total weight of monomer) The ...

Embodiment 2

[0071]Soap lotion 2 # 组分:

[0072]

[0073]In a four-mouth flask equipped with a stirrer, a thermometer, a reflux condenser, 40 g of dimethylformamide, 118.8 g (0.20 mol) of terephthalic acid, 33.20 g (0.20 mol) of terephthalic acid, After nitrogen protection, stir up to 65 ° C, 0.61 g (0.40% of the total weight of the monomer), 6.24 g of 2-ethylhexanol, continued to warm to 180 ° C, thermal insulation reaction 5.5H After cooling, distillation is reduced pressure, i.e., water-soluble melon ring polymer 2 # (weight average molecular weight: 13587).

[0074]In a four-mouth flask equipped with a stirrer, a thermometer, a reflux condenser, 7.84 g (0.08 mol) of maleic anhydride and 150 g of deionized water were added, stirred at 30 ° C for 10 min, and the nitrogen gas was heated to 65 ° C, and added Acetone (30 mL) solution containing 18.72 g (0.09 mol) 3-styrene thiopropionic acid and 52.80 g (0.33 mol) 2-methyll thiopropionic acid, and 1.11 of the total weight of the monomer %) Acetone (2.5 mL)...

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Abstract

The invention provides a soaping agent for a polyester / cotton / spandex fabric and a preparation method pf the soaping agent. The soaping agent for the polyester / cotton / spandex fabric comprises the following components in percentage by weight of 20-40% of a water-soluble cucurbituril polymer; 15-35% of an acidic terpolymer; 5-15% of a green surfactant; and the balance of deionized water. The soaping agent for the polyester / cotton / spandex fabric has excellent removal and anti-staining effects on flooding of disperse dyes and reactive dyes, is relatively strong in acidity, can fully and effectively neutralize residual alkali after reactive dyeing, omits reduction cleaning and acid neutralization water washing, reduces the traditional nine cleaning procedures to four cleaning procedures, shortens the process, improves the efficiency, and reduces water consumption and wastewater discharge; the soaping temperature is reduced from 95 DEG C to 75 DEG C, so that the damage to spandex is avoided while the energy consumption is reduced; the treated fabric is small in colored light change, good in soaping effect, free of phosphorus, APEO and other substances, environment-friendly, safe and excellent in comprehensive performance, and the rubbing fastness and soaping fastness of the treated fabric reach or are superior to those of a traditional process.

Description

Technical field[0001]The present invention relates to the field of printing and dyeing aids, and more particularly to a potent for a polyester / cotton / ammonia fabric and a preparation method thereof.Background technique[0002]In recent years, as people's living standards are increasing, consumers' demand is also increasing, and spandeous fabrics have high elasticity and excellent resilience, soft feel, very popular in domestic and foreign markets, and develop quickly . Polyester / cotton / ammonia fabric, both polyester wear-resistant wrinkles, and cotton moisture absorption and dressing, and high-elastic and softness of spandex, it is favored by consumers.[0003]Polyester / cotton / ammonia fabric contains a variety of fibers, each of the structural properties of each fiber, is more complex, polyester, and ammonia groups need to be dyed with disperse dyes, cotton components use activated dyes, different components During the dyeing process, it will also be composed to each other, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06P5/08D06P5/10D06P5/04D06P5/06D06P3/872
CPCD06P5/08D06P5/10D06P5/04D06P5/06D06P3/8252D06P3/8219D06P3/8214Y02P70/62
Inventor 杨天乔李正雄
Owner TAICANG BAONI IND CO LTD
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