A kind of solid-state fluorescent carbon dots based on nanoporous glass and preparation method thereof

A nanoporous, solid-state fluorescence technology, applied in the direction of nano-carbon, chemical instruments and methods, luminescent materials, etc., can solve the problems of limited preparation process, high preparation cost, and low carbon dot loading, and achieve high fluorescence intensity and method Simple, glow-steady effect

Active Publication Date: 2021-12-03
HUAZHONG UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, most of the carbon dots reported in the current literature have good luminescent properties in solution, while solid carbon dots are subject to aggregation quenching effects, and in the solid state, due to Π electron accumulation or energy transfer between carbon nuclei, they tend to fade. fluorescence quenching
Although there are methods for the preparation of solid-state carbon dots, they are mostly limited by the complex preparation process, high preparation cost, and low carbon dot loading, which limits the application of carbon dots in lighting, energy, optoelectronic devices, and biomedicine.

Method used

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  • A kind of solid-state fluorescent carbon dots based on nanoporous glass and preparation method thereof
  • A kind of solid-state fluorescent carbon dots based on nanoporous glass and preparation method thereof
  • A kind of solid-state fluorescent carbon dots based on nanoporous glass and preparation method thereof

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preparation example Construction

[0032] The embodiment of the present invention provides a method for preparing solid-state fluorescent carbon dots based on nanoporous glass, such as figure 1 shown, including the following steps:

[0033] S1, adopt a one-step high temperature method, stir a certain proportion of the carbon source molecular precursor evenly, then put it into the inner tank of the polytetrafluoroethylene hydrothermal kettle, and react at a reaction temperature of 160 ° C ~ 200 ° C for 6 ~ 12 hours to obtain Reactant;

[0034] Preferably, the carbon source molecular precursor is p-phenylenediamine and anhydrous aluminum chloride, and the molar ratio is 50:3 to 25:6, more preferably 50:3 or 35:3 or 25:6; or , the carbon source molecular precursor is citric acid and urea, and its mass ratio is 1:1 to 1:3, more preferably 1:2; or, the carbon source molecular precursor is citric acid and o-phenylenediamine , its mass ratio is 1:1 to 1:8, more preferably 1:6, so that it can fully react.

[0035] S...

Embodiment 1

[0046] Weigh 1 g of citric acid and 2 g of urea into a beaker, grind evenly, add 30 mL of deionized water, stir evenly, put it into the inner tank of a polytetrafluoroethylene reactor, put the reactor into an oven, and set the reaction temperature to 160 ℃, the reaction time is 6 hours; after the reaction is over, put it into a 3500D dialysis bag, and dialyze for 36 hours to further purify the reactant; collect the liquid in the dialysis bag, put it into a freeze dryer, and obtain a powder sample.

[0047] Dissolve 0.0078 g of powdered carbon dots in 10 ml of deionized water, and sonicate for 30 minutes to obtain a uniform carbon dot solution; take 1 piece of nanoporous glass sheet, and immerse the nanoporous glass sheet into the carbon dot solution by liquid phase method for 72 hours; then , and naturally dried for 1 day in a clean room environment to obtain solid carbon dots based on nanoporous glass sheets.

Embodiment 2

[0049] Weigh 0.2g of citric acid and 1.2g of o-phenylenediamine into a beaker, grind it evenly, put it into the inner tank of a polytetrafluoroethylene reaction kettle, put the reaction kettle into an oven, set the reaction temperature to 170 ° C, and the reaction time After the reaction is over, put it into a 3000D dialysis bag, and dialyze for 48 hours to further purify the reactant; collect the liquid in the dialysis bag, put it into a freeze dryer, and obtain a powder sample.

[0050] Dissolve 0.018g of powdered carbon dots in 20ml of deionized water, and sonicate for 30 minutes to obtain a uniform carbon dot solution; take 1 piece of nanoporous glass sheet, and immerse the nanoporous glass sheet into the carbon dot solution by liquid phase method for 72 hours; then , and naturally dried for 1 day in a clean room environment to obtain solid carbon dots based on nanoporous glass sheets.

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Abstract

The invention belongs to the field of fluorescent carbon nanomaterials, and specifically discloses a solid-state fluorescent carbon dot based on nanoporous glass and a preparation method thereof, comprising the following steps: preparing carbon dot powder into a carbon dot solution, and then soaking a nanoporous glass sheet In the carbon dot solution, the carbon dots in the carbon dot solution are dispersed and incorporated into the nanopores of the nanoporous glass, and the nanopores inhibit the aggregation of the carbon dots. After the nanoporous glass with carbon dots has been naturally dried, Solid-state fluorescent carbon dots based on nanoporous glass were obtained. The invention incorporates carbon dots into nanoporous glass, the method is simple, green and environmentally friendly, and can be prepared in batches, achieving good compatibility between carbon dots and glass, and the prepared solid fluorescent carbon dots have stable luminescence and high fluorescence intensity.

Description

technical field [0001] The invention belongs to the field of fluorescent carbon nanomaterials, and more particularly relates to a solid fluorescent carbon dot based on nanoporous glass and a preparation method thereof. Background technique [0002] Carbon dots are one-dimensional nanomaterials with fluorescent properties, which have the advantages of unique optical properties, good water solubility, stable luminescence properties, easy synthesis and environmental protection. This area has received great attention. [0003] However, most of the carbon dots reported in the literature have good luminescence properties in solution, while solid carbon dots are subject to the aggregation quenching effect, and in the solid state, due to the accumulation of Π electrons or energy transfer between carbon nuclei. Fluorescence quenching occurs. At present, although there are preparation methods for solid carbon dots, they are mostly limited by the complex preparation process, high pre...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C23/00C09K11/65C03C15/00C01B32/15
CPCC03C15/00C03C23/0085C03C23/0095C09K11/65C01B32/15
Inventor 徐鸣马云秀
Owner HUAZHONG UNIV OF SCI & TECH
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