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Thermosensitive high-performance polyurethane adhesive convenient for construction

A polyurethane glue, high-performance technology, applied in the direction of polyurea/polyurethane adhesive, adhesive, adhesive type, etc., can solve the problem of easy blockage of gun tip, poor mechanical properties and bonding strength, and cross-linking reaction rate Fast and other problems, to achieve the effect of good leveling time and curing time, good mechanical properties and bonding strength, prolonging the active period and open time

Inactive Publication Date: 2020-07-10
SHANGHAI JINQIANG ADHESIVE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, traditional polyurethane adhesives on the market usually add catalysts such as N,N-dimethylcyclohexylamine and triethylamine to improve the bonding strength of the colloids, but the problem is that after the colloids are mixed, the crosslinking reaction rate is too fast and the activity The period is short, the opening time is short, and the process error tolerance rate is low; continuous and uninterrupted production is required. Once the spraying process stops, the spraying glue can easily block the gun head
Therefore, it is necessary to manually clean the gun head frequently, which not only wastes glue and cleaning agent, but also increases waste disposal costs and labor costs
In addition, the existing polyurethane glue also has the problems of poor mechanical properties and bonding strength, and the quality of the board cannot be effectively guaranteed in the actual use process; and the mismatch between the leveling time and the curing time leads to poor leveling, and after curing There are often wrinkles or pores on the surface of the glue, which affects the further use of the product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0092] The second aspect of the present invention provides a method for preparing the heat-sensitive high-performance polyurethane adhesive that is convenient for construction. The preparation of the A component includes the following steps: by weight, first diazabicyclo Compounds, compounds containing hydroxyl and / or carboxyl groups are mixed, and then mixed with the remaining raw materials to form a gel.

[0093] In a preferred embodiment, the preparation method of the heat-sensitive high-performance polyurethane glue that is convenient for construction, the preparation of the A component includes the following steps: by weight, first diazabicyclic compound, Compounds containing hydroxyl and / or carboxyl groups were stirred and mixed at 35-45°C for 20-40 minutes, then polyol resin and pre-crosslinking agent were added to it, reacted at 55-65°C for 2-4 hours, then cooled to 35-45 ℃ Add fillers, lubricants, coupling agents and mix to form a gel.

[0094] In a more preferred em...

Embodiment 1

[0102] Example 1 of the present invention provides a heat-sensitive high-performance polyurethane adhesive that is convenient for construction, including component A and component B. In parts by weight, the A component includes 50 parts of polyol resin, 0.3 part of diazabicyclic compound, 0.6 part of hydroxyl-containing compound, 44 parts of filler, 2 parts of lubricant, 1 part of coupling agent, pre-crosslinked 1 part of joint agent; the B component is diphenylmethane diisocyanate.

[0103] The polyol resin is a mixture of polypropylene glycol, polyethylene adipate, and castor oil, and the weight ratio of the three is 2:1:2; the polypropylene glycol is Haishihua from Jiangsu Haian Petrochemical Plant PPG400, the number average molecular weight is 400, and the hydroxyl value is 255~312mgKOH / g (the average value is 283.5mgKOH / g); The polyethylene adipate is POL-1180 of Qingdao Xinyutian Chemical Co., Ltd., the number The average molecular weight is 600, and the hydroxyl value ...

Embodiment 2

[0107] Example 2 of the present invention provides a heat-sensitive high-performance polyurethane adhesive that is convenient for construction, including component A and component B. In parts by weight, the A component includes 40 parts of polyol resin, 0.2 part of diazabicyclic compound, 0.2 part of hydroxyl-containing compound, 40 parts of filler, 1 part of lubricant, 0.5 part of coupling agent, pre-crosslinked 0.4 parts of joint agent; the B component is diphenylmethane diisocyanate.

[0108] The polyol resin is a mixture of polypropylene glycol, polyethylene adipate, and castor oil, and the weight ratio of the three is 2:0.5:1.5; the polypropylene glycol is Haishihua from Jiangsu Haian Petrochemical Factory PPG400, the number average molecular weight is 400, and the hydroxyl value is 255~312mgKOH / g (the average value is 283.5mgKOH / g); The polyethylene adipate is POL-1180 of Qingdao Xinyutian Chemical Co., Ltd., the number The average molecular weight is 600, and the hydro...

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Abstract

The invention discloses a thermosensitive high-performance polyurethane adhesive convenient for construction. The thermosensitive high-performance polyurethane adhesive comprises a component A and a component B, wherein the component A is prepared from the following components in parts by weight: 40 to 60 parts of polyol resin, 0.2 to 0.8 part of a diazabicyclo compound, 0.2 to 0.8 part of a compound containing hydroxyl and / or carboxyl, 40 to 50 parts of a filler, 1 to 3 parts of a lubricant and 0.5 to 2 parts of a coupling agent; and the component B is isocyanate of which the isocyanate functionality is greater than or equal to 2. The obtained polyurethane adhesive shows good mechanical properties and bonding strength, the active period and the opening time of the adhesive can be remarkably prolonged, the process error-tolerant rate is high, the gun head blockage condition does not occur after shutdown, and continuous production can be achieved; and meanwhile, the surface is smooth and free of air holes through naked eye observation after gluing is conducted for 1 min. Besides, the polyurethane adhesive is good in leveling time and curing time matching, good in leveling property and ductility, capable of being used for spraying, curtain coating and other processes besides the traditional use mode of the adhesive, and extremely high in actual popularization significance.

Description

technical field [0001] The invention relates to the field of polyurethane adhesives, in particular to a heat-sensitive high-performance polyurethane adhesive that is convenient for construction. Background technique [0002] Polyurethane spray glue is a kind of glue that can be sprayed by machine. It is cured by hot pressing to ensure fast board release. It is suitable for customer groups with tight order delivery and large output. The application of polyurethane gluing can save the space of the industrial site and reduce manual operation, so as to avoid the frequent mistakes of personnel operation, uneven gluing amount, resulting in glue opening and bulging, etc., and ensure the stable quality of the final finished board. [0003] At present, traditional polyurethane adhesives on the market usually add catalysts such as N,N-dimethylcyclohexylamine and triethylamine to improve the bonding strength of the colloids, but the problem is that after the colloids are mixed, the cro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/14C09J175/06C09J175/08C09J11/04C09J11/06C08G18/48C08G18/42C08G18/67C08G18/30C08G18/66C08G18/20
CPCC08G18/2063C08G18/2815C08G18/36C08G18/4018C08G18/4238C08G18/4825C08G18/4833C08G18/66C08K2003/265C09J11/04C09J11/06C09J175/06C09J175/08C09J175/14C08K13/04C08K7/26C08K3/26C08K5/053C08K5/544
Inventor 方珍英方玉来
Owner SHANGHAI JINQIANG ADHESIVE
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