Thermosensitive high-performance polyurethane adhesive convenient for construction
A polyurethane glue, high-performance technology, applied in the direction of polyurea/polyurethane adhesive, adhesive, adhesive type, etc., can solve the problem of easy blockage of gun tip, poor mechanical properties and bonding strength, and cross-linking reaction rate Fast and other problems, to achieve the effect of good leveling time and curing time, good mechanical properties and bonding strength, prolonging the active period and open time
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preparation example Construction
[0092] The second aspect of the present invention provides a method for preparing the heat-sensitive high-performance polyurethane adhesive that is convenient for construction. The preparation of the A component includes the following steps: by weight, first diazabicyclo Compounds, compounds containing hydroxyl and / or carboxyl groups are mixed, and then mixed with the remaining raw materials to form a gel.
[0093] In a preferred embodiment, the preparation method of the heat-sensitive high-performance polyurethane glue that is convenient for construction, the preparation of the A component includes the following steps: by weight, first diazabicyclic compound, Compounds containing hydroxyl and / or carboxyl groups were stirred and mixed at 35-45°C for 20-40 minutes, then polyol resin and pre-crosslinking agent were added to it, reacted at 55-65°C for 2-4 hours, then cooled to 35-45 ℃ Add fillers, lubricants, coupling agents and mix to form a gel.
[0094] In a more preferred em...
Embodiment 1
[0102] Example 1 of the present invention provides a heat-sensitive high-performance polyurethane adhesive that is convenient for construction, including component A and component B. In parts by weight, the A component includes 50 parts of polyol resin, 0.3 part of diazabicyclic compound, 0.6 part of hydroxyl-containing compound, 44 parts of filler, 2 parts of lubricant, 1 part of coupling agent, pre-crosslinked 1 part of joint agent; the B component is diphenylmethane diisocyanate.
[0103] The polyol resin is a mixture of polypropylene glycol, polyethylene adipate, and castor oil, and the weight ratio of the three is 2:1:2; the polypropylene glycol is Haishihua from Jiangsu Haian Petrochemical Plant PPG400, the number average molecular weight is 400, and the hydroxyl value is 255~312mgKOH / g (the average value is 283.5mgKOH / g); The polyethylene adipate is POL-1180 of Qingdao Xinyutian Chemical Co., Ltd., the number The average molecular weight is 600, and the hydroxyl value ...
Embodiment 2
[0107] Example 2 of the present invention provides a heat-sensitive high-performance polyurethane adhesive that is convenient for construction, including component A and component B. In parts by weight, the A component includes 40 parts of polyol resin, 0.2 part of diazabicyclic compound, 0.2 part of hydroxyl-containing compound, 40 parts of filler, 1 part of lubricant, 0.5 part of coupling agent, pre-crosslinked 0.4 parts of joint agent; the B component is diphenylmethane diisocyanate.
[0108] The polyol resin is a mixture of polypropylene glycol, polyethylene adipate, and castor oil, and the weight ratio of the three is 2:0.5:1.5; the polypropylene glycol is Haishihua from Jiangsu Haian Petrochemical Factory PPG400, the number average molecular weight is 400, and the hydroxyl value is 255~312mgKOH / g (the average value is 283.5mgKOH / g); The polyethylene adipate is POL-1180 of Qingdao Xinyutian Chemical Co., Ltd., the number The average molecular weight is 600, and the hydro...
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