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Liquid photosensitive solder resist ink for LEDs

A photosensitive solder resist ink, liquid technology, which is applied in the field of liquid photosensitive solder resist ink for LEDs, can solve the problems affecting the usability, reliability and durability of printed circuit boards, high scrap rate, and easy aging of products, and achieve the preparation process Efficient and controllable, ensuring the time of use, improving efficiency and quality

Inactive Publication Date: 2020-06-16
江苏海田电子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous advancement and development of the modern electronics industry, my country's printed board solder resist resin began in the late 1970s. At that time, it was mainly heat-cured solder resist resin, which began to be transferred from imports to domestic production. Type character resin, due to the influence of precision, it finally develops into liquid photosensitive solder resist resin, which has both light curing and thermal curing resins. It is prepared by reacting with an acid anhydride. The resin has excellent heat resistance after curing, but because of the large shrinkage after curing, the solder mask is easy to become brittle, and the scrap rate is high in the production process.
Therefore, its product quality is not only related to the external resistance of the finished printed circuit board, but also directly affects the usability, reliability and durability of the printed circuit board product. The existing photosensitive solder resist resin has poor yellowing resistance , causing the product to be easily aged and affecting the use time of the product, and the existing photosensitive solder resist resin has poor photosensitivity, poor anti-corrosion performance, and easy foaming, which reduces the use efficiency and quality, and is difficult to meet the needs of production and use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A liquid photosensitive solder resist ink for LEDs, said liquid photosensitive solder resist ink for LEDs comprising the following raw materials in parts by weight: 100 parts of photosensitive resin, 20 parts of methacrylic monomer, 5 parts of resorcinol epoxy resin , 1 part of pigment, 3 parts of dibenzoyl peroxide, 1 part of sodium lauryl sulfate, 10 parts of acrylic resin emulsion, 30 parts of propylene glycol monomethyl ether, 0.5 parts of nano-titanium dioxide, 0.2 parts of low-polymerized linseed oil, polyoxyethylene poly 0.4 part of oxypropylene pentaerythritol ether, 0.03 part of p-hydroxyanisole, 0.8 part of UV ink preservative LF-519; the ratio of the weight part of the diluent to the defoamer is 1:2.

[0019] The methacrylic monomer contains 5 parts of methyl methacrylate monomer and 20 parts of glycidyl methacrylate.

Embodiment 2

[0021] A liquid photosensitive solder resist ink for LEDs, said liquid photosensitive solder resist ink for LEDs comprising the following raw materials in parts by weight: 100 parts of photosensitive resin, 30 parts of methacrylic monomer, 10 parts of resorcinol epoxy resin , 2 parts of pigments, 6 parts of dibenzoyl peroxide, 2 parts of sodium lauryl sulfate, 15 parts of acrylic resin emulsion, 40 parts of propylene glycol monomethyl ether, 0.8 parts of nano-titanium dioxide, 0.4 parts of low-polymerized linseed oil, polyoxyethylene poly 0.8 part of oxypropanolamine ether, 0.03 part of p-hydroxyanisole, 1 part of UV ink preservative LF-519; the ratio of the weight part of the diluent to the defoamer is 1:2.

[0022] The methacrylic monomer includes 10 parts of methyl methacrylate monomer and 15 parts of glycidyl methacrylate.

Embodiment 3

[0024] A liquid photosensitive solder resist ink for LEDs, said liquid photosensitive solder resist ink for LEDs comprising the following raw materials in parts by weight: 100 parts of photosensitive resin, 25 parts of methacrylic monomer, 7.5 parts of resorcinol epoxy resin , 1.5 parts of pigment, 4.5 parts of dibenzoyl peroxide, 1.5 parts of sodium lauryl sulfate, 12.5 parts of acrylic resin emulsion, 35 parts of propylene glycol monomethyl ether, 0.65 parts of nano-titanium dioxide, 0.3 parts of low-polymerized linseed oil, polyoxypropylene glycerin 0.6 part of ether, 0.03 part of p-hydroxyanisole, 0.9 part of UV ink preservative LF-519; the ratio of the weight part of the diluent to the defoamer is 1:2.

[0025] The methacrylic monomer contains 7.5 parts of methyl methacrylate monomer and 17.5 parts of glycidyl methacrylate.

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PUM

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Abstract

The invention discloses a liquid photosensitive solder resist ink for LEDs. The liquid photosensitive solder resist ink for LEDs comprises the following raw materials in parts by weight: 100 parts ofphotosensitive resin, 20-30 parts of methacrylic acid monomers, 5-10 parts of resorcinol epoxy resin, 1-2 parts of pigment, 3-6 parts of a polymerization thermal initiator, 1-2 parts of a surfactant,10-15 parts of acrylic resin emulsion, 30-40 parts of a solvent, 0.5-0.8 parts of a catalyst, 0.2-0.4 parts of a diluent, 0.4-0.8 parts of a defoaming agent, 0.03 parts of a polymerization inhibitor and 0.8-1 part of a UV preservative, wherein the weight part ratio of the diluent to the defoaming agent is 1: 2. The problems of brittleness of photosensitive resin taking linear novolac epoxy resin as an initial raw material and insufficient heat resistance, chemical resistance, corrosion resistance and foaming of photosensitive resin synthesized by taking bisphenol A epoxy resin or bisphenol F epoxy resin or hydroxymethyl bisphenol A epoxy resin as an initial raw material are solved.

Description

technical field [0001] The invention relates to the technical field of inks, in particular to a liquid photosensitive solder resist ink for LEDs. Background technique [0002] With the continuous advancement and development of the modern electronics industry, my country's printed board solder resist resin began in the late 1970s. At that time, it was mainly heat-cured solder resist resin, which began to be transferred from imports to domestic production. Type character resin, due to the influence of precision, it finally develops into liquid photosensitive solder resist resin, which has both light curing and thermal curing resins. It is prepared by reacting with acid anhydride. The resin has excellent heat resistance after curing, but because of the large shrinkage after curing, the solder mask is easy to become brittle, and the scrap rate is high in the production process. Therefore, its product quality is not only related to the external resistance of the finished printed c...

Claims

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Application Information

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IPC IPC(8): C09D11/101C09D11/033C09D11/03G03F7/027G03F7/004
CPCC09D11/101C09D11/033C09D11/03G03F7/027G03F7/004
Inventor 王琦
Owner 江苏海田电子材料有限公司
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