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A kind of modified chitosan crude oil demulsifier and preparation method thereof

A crude oil demulsifier, chitosan technology, applied in chemical dehydration/demulsification, treatment of hydrocarbon oil, petroleum industry, etc., can solve the problems of poor environmental friendliness and secondary pollution of demulsifier, and achieve strong competitive adsorption capacity , the use of good safety, the effect of a wide range of sources

Active Publication Date: 2020-11-27
WUHAN INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These demulsifiers are poor in environmental friendliness and are likely to cause irreversible secondary pollution; in addition, there are more or less differences in the composition and properties of crude oil production fluids in each oilfield, and there is no demulsifier that can handle all types of crude oil production fluids. emulsion

Method used

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  • A kind of modified chitosan crude oil demulsifier and preparation method thereof
  • A kind of modified chitosan crude oil demulsifier and preparation method thereof
  • A kind of modified chitosan crude oil demulsifier and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Prepare the N-n-butyrylation carboxymethyl chitosan of polyethylene glycol monomethyl ether graft, concrete steps are as follows:

[0042] (1) Synthesis of N-acylated chitosan: 2g chitosan (CS) (M w =179.17kDa, degree of deacetylation >95%, viscosity 100-200mPa·s) dissolved in 40mL of 10% acetic acid aqueous solution, added 160mL of methanol to dilute, added 5.9mmol of n-butyric anhydride under stirring condition, left at room temperature for 24h, then added 260mL of acetone was used as precipitant, and the precipitate was washed three times with methanol and ether respectively, and freeze-dried to obtain white water-soluble solid N-n-butyrylated chitosan (A 4 CS).

[0043] Wherein the consumption of n-butyric anhydride is 0.5 times of the amount of amino substance contained in chitosan, and concrete calculation method is as follows:

[0044] The sugar unit of chitosan is glucosamine residue, and the molecular weight of this residue (sugar unit of chitosan) is 161, an...

Embodiment 2

[0049] Prepare the N-n-hexanoylated carboxymethyl chitosan grafted with polyethylene glycol monomethyl ether, the specific steps are as follows:

[0050] (1) Synthesis of N-acylated chitosan: 2g chitosan (CS) (M w =179.17kDa, degree of deacetylation >95%, viscosity 100-200mPa·s) dissolved in 40mL of 10% acetic acid aqueous solution, added 160mL of methanol to dilute, under stirring conditions, added 5.9mmol of n-hexanoic anhydride according to 0.5 times the amount of amino substances, and at room temperature Put 260mL acetone under the conditions and add 260mL acetone as precipitating agent, respectively wash three times through methanol and ether, lyophilize and obtain white water-soluble solid N-n-hexanoylated chitosan (A 6 CS). Wherein the calculation method of n-hexanoic anhydride consumption is described in step (1) with reference to embodiment 1.

[0051] (2) Carboxymethylation of N-n-hexanoylated chitosan: get 1.128g A 6 Add 100mL of distilled water to CS in a 250mL ...

Embodiment 3

[0055] Prepare the N-octanoyl carboxymethyl chitosan grafted with polyethylene glycol monomethyl ether, and the specific steps are as follows:

[0056] (1) Synthesis of N-acylated chitosan: 2g chitosan (CS) (M w =179.17kDa, deacetylation degree>95%, viscosity 100~200mPa·s) was dissolved in 40mL10% acetic acid aqueous solution, added 160mL methanol to dilute, under stirring condition, add n-octylic anhydride 5.9mmol according to the amount of amino substance 0.5 times, in After standing at room temperature for 24 h, 260 mL of acetone was added as a precipitating agent, and the precipitate was washed three times with methanol and ether, and freeze-dried to obtain a white water-soluble solid N-n-octanoyl chitosan (A 8 CS). Wherein the calculating method of n-octanoic anhydride consumption is described with reference to step (1) among the embodiment 1.

[0057] (2) Carboxymethylation of N-octanoyl chitosan: get 1.256g A 8 Add 100mL of distilled water to CS in a 250mL three-neck...

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Abstract

The invention relates to a modified chitosan type crude oil demulsifier and a preparation method thereof. The structural general formula of the demulsifier is shown as formula I; the preparation method comprises the following steps: 1) performing acylation modification on chitosan to obtain N-acylated chitosan; 2) performing carboxyl alkylation on the N-acylated chitosan to obtain modified N-acylated carboxyl alkyl chitosan; 3) performing p-nitrobenzene esterification modification on the terminal hydroxyl of polyethylene glycol monomethyl ether to obtain p-nitrobenzene esterified polyethyleneglycol monomethyl ether; 4) enabling the modified polyethylene glycol monomethyl ether to react with the N-acylated carboxyl alkyl chitosan to obtain a target product polyethylene glycol monomethyl ether grafted N-acylated carboxyl alkyl chitosan. With chitosan type natural high-molecular compounds as raw materials, the modified chitosan type crude oil demulsifier provided by the invention has theadvantages of wide source, natural property, no toxicity, high biocompatibility, degradability and the like. A series of efficient demulsifiers suitable for oil-in-water (O / W) type emulsion are obtained by introducing carboxyl alkyl, acyl and polyether side chain to a chitosan molecular chain and controlling the position and substitution degree of each substituent.

Description

technical field [0001] The invention relates to a modified chitosan crude oil demulsifier and a preparation method thereof, belonging to the field of petrochemical industry. Background technique [0002] In the process of oilfield exploitation, with the implementation of oil recovery technologies such as steam flooding, surfactant, polymer and ASP flooding, the water content of crude oil emulsion increases, and the stability is enhanced, making it more difficult to break the emulsion of crude oil. The formation of emulsion will bring a series of serious hazards to the exploitation, transportation and processing of petroleum. The emulsification of crude oil and water will make the extraction of crude oil more difficult; when transporting water-containing crude oil by pipeline or tanker truck, it will increase the load of the pump and the transportation cost. Therefore, it is very necessary to desalt and dehydrate the crude oil emulsion before crude oil transportation and pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G33/04C08G81/00
CPCC08G81/00C10G33/04C10G2300/1033
Inventor 吕仁亮张成梁成王存文徐彩丽王为国徐汶张俊峰马家玉吴再坤
Owner WUHAN INSTITUTE OF TECHNOLOGY
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