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Hydrophobic treatment method for material surface

A treatment method and hydrophobization technology, applied in fiber raw material treatment, fiber treatment, metal material coating process, etc., can solve problems that are not conducive to the control of surface hydrophobic modification conditions and modification costs, the inability to precisely control the chemical structure of the film, Functional groups are not easy to preserve and other problems, to achieve the effect of good hydrophobic modification, good hydrophobic effect and mild conditions

Inactive Publication Date: 2018-02-23
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the plasma generation process will be accompanied by high energy, which will have a greater destructive effect on the fluorine-containing groups required for surface hydrophobic modification. The chemical structure of the film cannot be precisely controlled and the required functional groups are not easy to preserve; The temperature resistance requirements of the permanent material are also higher
In addition, the energy required for the PECVD reaction is high, which is not conducive to the control of surface hydrophobic modification conditions and modification costs

Method used

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  • Hydrophobic treatment method for material surface
  • Hydrophobic treatment method for material surface
  • Hydrophobic treatment method for material surface

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The laboratory dust-free paper is used as the material of the coating to be plated in this embodiment. Put the 21.5cm*11cm dust-free paper into the incubator for drying treatment, and then place it on the sample stage of the conformal coating system for the microscopic surface of the material. The initiator is di-tert-butyl peroxide, the molecular formula is C 8 h 18 o 2 ; The reactant monomer is perfluorodecanoic acid (PFDA), and the molecular formula is C 10 HF 19 o 2 . The pressure of the control reaction chamber is 1200Pa; the temperature of the initiator container is kept at room temperature; the DC power supply current of the reactant monomer inlet device is adjusted to 0.7A, and the voltage is 7.1V; the temperature of the reactant monomer water bath heating device is controlled to be 82 °C; adjust the DC power supply current of the electrothermal alloy wire heating system to 3.6A, the voltage to 19.0V, and control the temperature of the electrothermal alloy...

Embodiment 2

[0048] A flat glass sheet is used as the material to be coated in this embodiment. Wash the 7.5cm*2.5cm glass piece and put it into the incubator for drying treatment, and then place it on the sample stage of the nanoscale thickness conformal hydrophobic film coating device. The initiator is di-tert-butyl peroxide, the molecular formula is C 8 h 18 o 2 ; The reactant monomer is perfluorodecanoic acid (PFDA), and the molecular formula is C 10 HF 19 o 2 . The pressure of the reaction chamber is controlled at 3200Pa, and the temperature of the initiator container is kept at room temperature; the DC power supply current of the reactant monomer inlet device is adjusted to 0.7A, and the voltage is 7.5V; the temperature of the reactant monomer water bath heating device is controlled at 83 ℃; adjust the DC power supply current of the electrothermal alloy wire heating system to 3.8A, the voltage to 19.5V, and the temperature of the electrothermal alloy wire is controlled at 225 °...

Embodiment 3

[0051] A single crystal silicon wafer is used as the material of the coating to be plated in this embodiment. A 0.5cm*1.5cm single crystal silicon wafer is washed with absolute ethanol, dried naturally, and then placed on the sample stage of a nanoscale thickness conformal hydrophobic film coating device. The initiator is di-tert-butyl peroxide, the molecular formula is C 8 h 18 o 2 ; The reactant monomer is perfluorodecanoic acid (PFDA), and the molecular formula is C 10 HF 19 o 2 . The pressure of the reaction chamber is controlled at 2700Pa, the temperature of the initiator container is controlled at room temperature, the DC power supply current of the reactant monomer inlet device is adjusted to 0.60A, and the voltage is 7.5V; the temperature of the reactant monomer water bath heating device is controlled at 81 ℃, adjust the DC power supply current of the electrothermal alloy wire heating system to 3.5A, the voltage to 18.0V, the temperature of the electrothermal all...

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Abstract

The invention discloses a hydrophobic treatment method for a material surface, and relates to the technical field of surface conformal coating. The method is completed in a material microscopic surface conformal coating system and specifically comprises the steps that 1) a to-be-plated material is pretreated; 2) the to-be-plated material subjected to pretreatment is placed on a sample table; 3) acirculating water cooling system is started; 4) a vacuum control system is started; 5) an electric heating alloy wire heating system is started; and 6) an air inlet supply system is started, reactantmonomers subjected to gasification and initiators are separately introduced into a reaction chamber according to a preset flow rate, the reaction time is set, and the material surface is plated with anano-scale hydrophobic film coating through reactants. The method has the effects and the advantages that 1) the film formed by the method is nano-scale, and the thin film coating can be conformal with raw materials, is compact and uniform, and is controllable in thickness; 2) a high-vacuum environment is not needed, and the operation range is wide; 3) the operation is simple and convenient; and4) the hydrophobic modification effect is good.

Description

technical field [0001] The invention belongs to the technical field of surface conformal coating, and in particular relates to a material surface hydrophobic treatment method. Background technique [0002] Hydrophobicity is one of the important characteristics of the material surface, which is determined by the chemical composition of the material and the surface geometry. Its properties are usually evaluated by water contact angle. In general, a surface whose contact angle of water on a solid surface exceeds 90° is called a hydrophobic surface. When the contact angle of water on a solid surface exceeds 150°, the surface is called a superhydrophobic surface. [0003] With the development of society, the requirements for the hydrophobicity of materials in industry and life are getting higher and higher. For many applications such as waterproof clothing, packaging materials, waterproof electronics, self-cleaning surfaces, anti-fog surfaces, etc., a high water contact angle ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C26/00D21H19/10C09D5/16D06M15/19D06M15/233D06M101/28C03C17/28
CPCC03C17/28C03C2217/70C03C2218/152C09D5/1662C23C26/00D06M15/19D06M15/233D06M2101/28D06M2200/12D21H19/10
Inventor 郭飞从硕蔡景成
Owner DALIAN UNIV OF TECH
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