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A graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO/hips alloy material and preparation method thereof

A technology of continuous glass fiber and alloy materials, applied in the field of polymer materials, can solve the problems of not meeting the design requirements of high-strength parts and limited mechanical strength, etc., achieve good appearance, reduce material costs, improve brittleness and difficulty in processing Effect

Active Publication Date: 2021-05-25
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The material has limited mechanical strength and cannot meet the design requirements of high-strength parts

Method used

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  • A graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO/hips alloy material and preparation method thereof
  • A graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO/hips alloy material and preparation method thereof
  • A graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO/hips alloy material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0038] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the cutting length of the material is 6-25mm, the particle size is 4.0mm, and it includes the following components by weight: PPO 480 320 parts of HIPS, 200 parts of continuous glass fiber, 5 parts of graphene, 10 parts of compatibilizer, 80 parts of toughening agent, 80 parts of flame retardant, 6 parts of antioxidant, 5 parts of compound light stabilizer, lubrication Agent PETS 6 parts, zinc oxide 5 parts;

[0039] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0040] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0041] B, mixing preparation: the sil...

Embodiment 2

[0054] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the cutting length of the material is 6-25mm, the particle size is 4.0mm, and it includes the following components by weight: PPO 420 280 parts of HIPS, 300 parts of continuous glass fiber, 10 parts of graphene, 15 parts of compatibilizer, 65 parts of toughening agent, 100 parts of flame retardant, 8 parts of antioxidant, 4 parts of compound light stabilizer, lubricating Agent A-C540A 6 parts, calcium oxide 10 parts;

[0055] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0056] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0057] B, mixing preparation...

Embodiment 3

[0065] (1), a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, the material has a cutting length of 6-25mm and a particle size of 3.0mm, including the following components by weight: PPO:360 parts, HIPS: 240 parts, continuous glass fiber: 400 parts, graphene 15 parts, compatibilizer 20 parts, toughening agent 50 parts, flame retardant 120 parts, antioxidant: 10 parts, compound light stabilizer: 3 parts, lubricant GM-100: 8 parts, zinc oxide 15 parts;

[0066] (2), a method for preparing graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material, comprising the following steps:

[0067] a. Drying preparation: the preheating and drying conditions of PPO are dried at 100-110°C for 3-4 hours, and the preheated drying conditions of HIPS are dried at 80-90°C for 1-2 hours;

[0068]B, mixing preparation: the silane coupling agent KH...

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Abstract

The invention discloses a graphene-coordinated continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material. The material is prepared from the following components in parts by weight: PPO: 360-480 parts, HIPS: 240-320 parts parts, continuous glass fiber: 200-400 parts, graphene 5-15 parts, compatibilizer 10-20 parts, toughening agent 50-80 parts, flame retardant 80-120 parts, antioxidant 6-10 parts, 3-5 parts of composite light stabilizer, 4-8 parts of lubricant, metal oxide: 5-15 parts. In the present invention, the PPO / HIPS alloy is reinforced by adding pre-dispersed graphene in coordination with continuous glass fiber, and compounding various functional additives, so that the material not only has excellent rigidity and impact toughness, but also has excellent weather resistance and flame retardant. It can meet the application of glass fiber reinforced PPO / HIPS alloy in different fields. The material can be directly molded by injection molding, and the production efficiency is high. The used parts can be recycled after being crushed. .

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a graphene synergistic continuous glass fiber reinforced halogen-free flame-retardant and weather-resistant PPO / HIPS alloy material and a preparation method thereof. Background technique [0002] Polyphenylene oxide (PPO) is an excellent thermoplastic engineering plastic. It has good mechanical properties, thermal properties and electrical properties, but has the disadvantages of high melting temperature, high melt viscosity, poor thermoplastic formability and poor resistance to organic solvents (such as halogenated aliphatic hydrocarbons), which limit its application range. In order to improve the performance of PPO and expand its application field, it is necessary to modify PPO, and the modified PPO is called MPPO. The modified polyphenylene ether alloy has excellent comprehensive performance and many varieties, and is widely used in various fields, such as: automobi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L71/12C08L51/04C08L51/08C08K13/06C08K9/06C08K3/04C08K7/14C08K3/22
Inventor 杨桂生蒋超杰姚晨光
Owner HEFEI GENIUS NEW MATERIALS
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