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Thermal bimetallic material taking electrical pure iron as middle layer and preparation method of thermal bimetallic material

An electrical pure iron and thermal bimetal technology, applied in the field of metal materials, can solve the problems of expensive copper alloy layer and steel alloy layer, high requirements on corrosion resistance, unable to meet the needs of use, etc., and achieves easy large-scale production, Low cost and good corrosion resistance

Inactive Publication Date: 2017-10-03
上海松森特殊金属有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, the annual demand for such thermal bimetal materials with pure nickel as the intermediate layer is about 2,000 tons. Because nickel is an expensive non-ferrous metal, the production cost is very high. In order to reduce the production cost of thermal bimetal, it is necessary to develop low Low-nickel or nickel-free interlayer thermal bimetallic materials
[0004] Chinese patent CN201410157022.9 discloses a layered thermal bimetallic material that can save nickel. The middle layer of the thermal bimetallic material does not use pure nickel, but a layered composite alloy of copper alloy layer and steel alloy layer. Combination layer, the number of layers of the alloy combination layer is 2-4 layers, the thickness of the alloy combination layer accounts for 5%-40% of the total thickness of the thermal bimetallic material, and the material of the copper alloy layer is any of C11000 or C10200 or C10700 The material of the steel alloy layer is either SUS430 or SUS304; although this patent saves the amount of nickel, the price of the copper alloy layer and steel alloy layer used in the middle layer is still relatively expensive, and the production cost is still high
In the above-mentioned patents, the alloy combination layer of electrical pure iron or copper alloy layer and steel alloy layer is used to replace the pure nickel intermediate layer used in bimetallic materials, which saves the amount of nickel, although the production cost is reduced to a certain extent. , but due to the absence of the pure nickel intermediate layer, its corrosion resistance is reduced, and the thermal bimetallic materials used in low-voltage electrical appliances have high requirements for corrosion resistance, which makes the above thermal bimetallic materials unable to meet the use requirements

Method used

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  • Thermal bimetallic material taking electrical pure iron as middle layer and preparation method of thermal bimetallic material
  • Thermal bimetallic material taking electrical pure iron as middle layer and preparation method of thermal bimetallic material
  • Thermal bimetallic material taking electrical pure iron as middle layer and preparation method of thermal bimetallic material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] 1) Raw material selection: choose FeNi 22 Cr 3 The alloy is the active layer 1 material, DT3 pure iron is selected as the middle layer 2 material, and FeNi is selected 36 The alloy is the material of the passive layer 3, and the selected materials are all strips, the width of which is 100 mm, and the annealed state;

[0038] 2) Cleaning: cleaning the surfaces of the active layer material, the intermediate layer material and the passive layer material to remove oil stains and oxides on the surface;

[0039] 3) Roughening: roughen the surfaces of the active layer 1 material, the intermediate layer 2 material and the passive layer 3 material to improve the bonding strength between the thermal bimetallic material layers;

[0040] 4) Drying: drying the active layer 1 material, the intermediate layer 2 material and the passive layer 3 material at 150°C under a nitrogen atmosphere;

[0041] 5) Pre-rolling: Pre-rolling the active layer 1 material, the middle layer 2 material...

Embodiment 2

[0051] In this example, the initial rolling temperature is 215°C, the reduction ratio is 92%, the temperature of diffusion annealing is 815°C, the reduction ratio of finish rolling is 88%, the temperature of stabilizing annealing is 235°C, and the holding time is 70 minutes ; The total thickness of the overall material in the obtained thermal bimetallic material is 1.079mm, the thickness of the active layer 1 is 0.395mm, the thickness of the middle layer 2 is 0.311mm, and the thickness of the passive layer 3 is 0.373mm. All the other contents are the same as in Example 1.

[0052] The thermal bimetal material prepared in this example also has a layered structure, and the bonding interface between the active layer 1, the middle layer 2 and the passive layer 3 is straight, and the thickness uniformity of the active layer 1, the middle layer 2 and the passive layer 3 is good ;Peel off test according to GB / T 5270-2005, bend the thermal bimetallic material into a right angle, the b...

Embodiment 3

[0055] In this example, the initial rolling temperature is 225°C, the reduction ratio is 93%, the temperature of diffusion annealing is 825°C, the reduction ratio of finish rolling is 89%, the temperature of stabilizing annealing is 245°C, and the holding time is 65 minutes ; The total thickness of the overall material in the obtained thermal bimetallic material is 1.082mm, the thickness of the active layer 1 is 0.398mm, the thickness of the middle layer 2 is 0.314mm, and the thickness of the passive layer 3 is 0.370mm. All the other contents are the same as in Example 1.

[0056] The thermal bimetal material prepared in this example also has a layered structure, and the bonding interface between the active layer 1, the middle layer 2 and the passive layer 3 is straight, and the thickness uniformity of the active layer 1, the middle layer 2 and the passive layer 3 is good ;Peel off test according to GB / T 5270-2005, bend the thermal bimetallic material into a right angle, the b...

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Abstract

The invention discloses a thermal bimetallic material taking electrical pure iron as a middle layer and a preparation method of the thermal bimetallic material. The thermal bimetallic material is of a layered structure and comprises an active layer, a passive layer and the middle layer sandwiched between the active layer and the passive layer, wherein the active layer is made from iron-nickel-chromium FeNi22Cr3, the middle layer is made from the electrical pure iron, and the passive layer is made from ferronickel FeNi36. The thermal bimetallic material disclosed by the invention has good flexivity, resistivity, welding performance and corrosion resistance, and perfect balance between low cost and corrosion resistance is achieved; in addition, by the preparation method disclosed by the invention, the bonding strength among the layers of the prepared thermal bimetallic material can be relatively high, and bonded interfaces can be flat and straight and be free of cracking phenomena.

Description

technical field [0001] The invention relates to a thermal bimetal material and a preparation method thereof, in particular to a thermal bimetal material with electrical pure iron as an intermediate layer and a preparation method thereof, belonging to the technical field of metal materials. Background technique [0002] Thermal bimetallic material is a functional temperature-sensitive material, which is composed of two or more materials with different thermal expansion coefficients. Among them, the active layer is made of materials with larger thermal expansion coefficients, and the passive layer is made of materials with smaller thermal expansion coefficients. It can produce shape changes according to temperature changes. It is mainly used in the fields of thermostats, low-voltage electrical appliances and instruments, such as: used for overload protection of low-voltage circuit breakers. When the current is overloaded, the temperature of the material will rise and the bimeta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/01B32B7/08B32B33/00B32B37/10B32B37/06B32B38/16B32B38/00
CPCB32B15/011B32B7/08B32B33/00B32B37/06B32B37/10B32B38/0012B32B38/162B32B38/164B32B2307/20B32B2307/752
Inventor 王名扬杨琪张超
Owner 上海松森特殊金属有限公司
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