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Composite zinc and gadolinium added neodymium iron boron bonded magnet powder and preparation method thereof

A composite addition, NdFeB technology, applied in the direction of metal processing equipment, magnetic materials, magnetic objects, etc., can solve problems such as adverse effects

Active Publication Date: 2017-09-05
成都银磁材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the different crystallization behaviors of different metal elements, the various effects and mechanisms of NdFeB permanent magnet materials are also different. Usually, multiple metal elements are required to be added in combination to improve the comprehensive performance of NdFeB permanent magnet materials. Moreover, the addition amount of metal elements has a decisive effect on the performance modification of NdFeB permanent magnet materials. If the addition amount is not selected properly, it may even lead to adverse effects. Therefore, how to choose the appropriate metal elements and the appropriate addition amount to achieve Increasing the Curie temperature of NdFeB at low cost, improving its heat resistance and comprehensive magnetic properties has become a technical problem to be solved urgently.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of neodymium-iron-boron bonded magnetic powder compounded with zinc and gadolinium. The weight percentage composition of each element in the bonded magnetic powder is: Nd 10.5%, Gd 2%, B 6%, Zn 0.5%, and the balance is Fe .

[0026] The preparation method of the above-mentioned bonded magnetic powder includes the following steps:

[0027] 1) According to the weight percentage composition of each element, take each raw material and put it into the vacuum melting furnace. -2 Under Pa vacuum, smelt into alloy ingot;

[0028] 2) The alloy ingot smelted in step 1) is crushed and then added to a vacuum induction rapid quenching furnace, and the vacuum degree reaches 5×10 -2 After Pa, fill with argon gas, and melt the broken alloy ingot at a temperature of 1500℃ in an argon atmosphere into a molten metal, control the rapid quenching speed to 25~33m / s, and quickly quench the molten metal to a thickness of 50 ±5μm uniform band;

[0029] 3) The uniform strip prepared in step 2) i...

Embodiment 2

[0032] A composite NdFeB bonded magnetic powder with zinc and gadolinium. The weight percentage of each element in the bonded magnetic powder is composed of: Nd 10%, Gd 2.6%, B 6.5%, Zn 0.4%, and the balance is Fe .

[0033] The preparation method of the above-mentioned bonded magnetic powder includes the following steps:

[0034] 1) According to the weight percentage composition of each element, take each raw material and put it into the vacuum melting furnace, in the -2 Under Pa vacuum, smelt into alloy ingot;

[0035] 2) The alloy ingot smelted in step 1) is crushed and then added to a vacuum induction rapid quenching furnace, and the vacuum degree reaches 5×10 -2 After Pa, fill with argon gas. Under argon atmosphere, the broken alloy ingots are melted into molten metal at a temperature of 1450℃. The rapid quenching speed is controlled to 25~33m / s, and the molten metal is quickly quenched to a thickness of 50 ±5μm uniform band;

[0036] 3) Crush the uniform strip prepared in step ...

Embodiment 3

[0039] A kind of neodymium-iron-boron bonded magnetic powder compounded with zinc and gadolinium. The weight percentage composition of each element in the bonded magnetic powder is: Nd 11%, Gd 1.0%, B 7%, Zn 0.2%, and the balance is Fe.

[0040] The preparation method of the above-mentioned bonded magnetic powder includes the following steps:

[0041] 1) According to the weight percentage composition of each element, take each raw material and put it into the vacuum melting furnace. -2 Under Pa vacuum, smelt into alloy ingot;

[0042] 2) The alloy ingot smelted in step 1) is crushed and then added to a vacuum induction rapid quenching furnace, and the vacuum degree reaches 5×10 -2 After Pa, fill with argon gas, and melt the broken alloy ingots at 1480℃ in an argon atmosphere into molten metal. Control the rapid quenching speed to 25~33m / s, and quickly quench the molten metal to a thickness of 50 ±5μm uniform band;

[0043] 3) Crush the uniform strip prepared in step 2) to 40 mesh mag...

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PUM

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Abstract

The invention relates to the technical field of permanent magnet material processing, and particularly relates to composite zinc and gadolinium added neodymium iron boron bonded magnet powder and a preparation method thereof. The magnet powder comprises the following elements: 10-11% of Nd, 1.0-2.6% of Gd, 6-7% of B, 0.2-0.5% of Zn, and the balance Fe. According to the composite zinc and gadolinium added neodymium iron boron bonded magnet powder, zinc and gadolinium are added, so that the temperature coefficients of a magnet can be reduced; the alpha-Fe crystallizing temperature increases; alpha-Fe and Nd2Fe14B can be synchronously separated out while rapidly-quenched NdFeB alloy is crystallized, so that alpha-Fe can be prevented from being separated out and growing firstly; crystal seeds are refined; the exchanging and coupling effects of crystal seeds are improved; effective nailing positions are increased, and the Hcj and Hk of the bonded magnet powder can be effectively increased; in addition, zinc and gadolinium coordinately act, the internal and external combination is realized, and the corrosion resistance of the prepared bounded magnet powder can be improved. With the adoption of the method, the parameters such as the smelting temperature, the vacuum degree, the quenching speed and the crystallizing temperature are limited, and the comprehensive performances of the magnet powder are further improved.

Description

Technical field [0001] The invention relates to the technical field of permanent magnet material processing, in particular to a neodymium iron boron bonded magnetic powder compounded with zinc and gadolinium and a preparation method thereof. Background technique [0002] NdFeB permanent magnet materials have received extensive research and attention due to their high magnetic energy product and coercivity. They have been widely used in electronics, electricity, machinery, medical equipment and other fields, but due to their hard magnetic phase Nd 2 Fe 14 The Curie temperature of B is relatively low, and the temperature coefficient of remanence and coercivity are relatively large, which limits its application in some areas of higher working temperature. [0003] Both theory and practice show that adding certain alloying elements can not only improve the magnetic properties of the product, but also significantly improve the temperature characteristics of the neodymium-iron-boron perma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/057C22C38/00B22F1/00
CPCB22F1/0003H01F1/0571H01F1/0577C22C38/002C22C38/005B22F1/142
Inventor 张卫华
Owner 成都银磁材料有限公司
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