Silicate long-persistence luminescent material and preparation method thereof
A long afterglow luminescence, silicate technology, applied in luminescent materials, chemical instruments and methods, etc., can solve the problem of short afterglow time, and achieve the effect of simple synthesis method, obvious energy saving effect, and water stability
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Embodiment 1
[0061] Press Ba 0.98 ZrSi 3 o 9 : 0.01Eu 2+ , 0.01Pr 3+ Stoichiometric ratio shown in molecular formula, weigh 0.1934g BaCO 3 , 0.1232g ZrO 2 , 0.1803g SiO 2 , 0.0018g Eu 2 o 3 and 0.0017g Pr 6 o 11 As a raw material, the weighed raw materials are ground and mixed evenly, put into an alumina crucible, and pre-fired in an air atmosphere. The pre-fired temperature is 800 ° C, and the pre-fired time is 2 hours. Calcined in a reducing atmosphere for 6 hours in an environment of 1400°C, the reducing atmosphere is composed of 95% nitrogen and 5% hydrogen by volume, and the calcined powder is cooled to room temperature with the furnace to obtain a calcined product; after grinding, the A cyan long afterglow luminescent material was obtained. figure 1 Shown is the XRD pattern of the long-lasting luminescent material, indicating that the phase of the material is BaZrSi 3 o 9 , only a small amount of impurity phase is produced. The excitation and emission spectra of the lon...
Embodiment 2
[0063] Press Ba 0.98 wxya3 o 9 : 0.01Eu 2+ , 0.01Pr 3+ Stoichiometric ratio shown in molecular formula, weigh 0.1934g BaCO 3 , 0.2105g HfO 2 , 0.1803g SiO 2 , 0.0018g Eu 2 o 3 and 0.0017g Pr 6 o 11 As a raw material, the weighed raw materials were mixed and ground evenly, then put into an alumina crucible, pre-sintered in an air atmosphere, the pre-sintering temperature was 800°C, and the pre-sintering time was 2 hours to obtain a mixture. The mixture was naturally cooled, ground evenly, and then Calcined in a reducing atmosphere at a temperature of 1400°C for 6 hours. The reducing atmosphere is composed of 95% nitrogen and 5% hydrogen by volume. The calcined powder is cooled to room temperature with the furnace to obtain a calcined product; after grinding, the A cyan long afterglow luminescent material was obtained. Figure 5 Shown is the XRD spectrum of the long-lasting luminescent material, indicating that the phase of the material is BaHfSi 3 o 9 , only a small...
Embodiment 3
[0065] Press Ba 0.98 wxya 3 o 9 : 0.01Eu 2+ , 0.01Yb 3+ Stoichiometric ratio shown in molecular formula, weigh 0.1934g BaCO 3 , 0.2105g HfO 2 , 0.1803g SiO 2 , 0.0018g Eu 2 o 3 and 0.0020g Yb 2 o 3 As a raw material, mix and grind the weighed raw materials evenly, put them into an alumina crucible, and pre-fire in an air atmosphere. , and then calcined in a reducing atmosphere at a temperature of 1400°C for 6 hours. The reducing atmosphere is composed of 95% nitrogen and 5% hydrogen by volume. The calcined raw material powder is cooled to room temperature with the furnace to obtain a calcined product; grinding Finally, a cyan long-lasting luminescent material is obtained. Figure 9 0.0010g sample Ba 0.98 wxya 3 o 9 : 0.01Eu 2+ , 0.01Yb 3+ The pyrolysis spectrum measured after 10 seconds of simultaneous irradiation of light sources with a wavelength of 254nm and a wavelength of 365nm shows that there are three strong pyrolysis peaks in the sample, which are loca...
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