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Bi-color antibacterial EVA footwear and preparation method thereof

An antibacterial agent and raw material technology, applied in the field of organic polymer compounds, can solve the problems of no antibacterial function, complex use process, large specific surface area of ​​inorganic antibacterial powder, etc. Production, the effect of enhancing visual aesthetics

Active Publication Date: 2015-08-26
茂泰(福建)新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If it is EVA sandals, slippers, and indoor shoes that are in direct contact with human skin, these shoes are light, comfortable, and cost-effective.
[0003] Due to the high injection or molded foaming temperature (165-180°C) in the production process of EVA foam materials, the heat resistance of organic small molecule antibacterial agents and natural antibacterial agents is poor, and it is difficult to meet the processing requirements; silver-based inorganic antibacterial agents have resistance Good thermal performance, strong antibacterial persistence, high safety, etc., but there are disadvantages such as large specific surface area of ​​inorganic antibacterial powder, heavy metal ions silver and copper dissolved are harmful to people's health, silver-based antibacterial agents are easy to change color, and the use process is complicated. Therefore, Most of the EVA foam materials currently on the market do not have antibacterial function

Method used

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  • Bi-color antibacterial EVA footwear and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] In the present embodiment, the two-color antibacterial EVA shoes consist of the following components by weight:

[0051] EVA 5110 15 parts

[0052] EVA 7470 35 parts

[0053] Ethylene-butylene copolymer ENR7256 20 parts

[0054] 1,2-polybutadiene RB820 17 parts

[0055] Tributylphosphonium antimicrobial agent of tributylvinylbenzyl chloride-methyl methacrylate copolymer 4 parts

[0056] Chlorinated polyethylene 135B 4 parts

[0057] Foaming agent Ac 2.4 parts

[0058]Cross-linking agent BIBP 0.8 parts

[0059] Zinc stearate 1.2 parts

[0060] Stearic acid 1.2 parts

[0061] Anti-wear agent AG209 3 parts

[0062] Talc powder 13 parts

[0063] Pigment phthalocyanine blue 0.4 parts.

[0064] The preparation method of two-color antibacterial EVA shoes, comprises steps:

[0065] Step 1: To prepare two different colors of antibacterial EVA rice, first mix other raw materials in the above formula except crosslinking agent and foaming agent for banburying, adjust the...

Embodiment 2

[0070] In the present embodiment, the preparation method of a kind of two-color antibacterial EVA shoes is identical with the preparation method in embodiment 1, difference is:

[0071] Part of the composition of antibacterial EVA material rice A is changed to: EVA 7470 50 parts, ethylene-butylene copolymer ENR7256

[0072] 20 parts, 15 parts of 1,2-polybutadiene RB830, 6 parts of tributylphosphine salt antibacterial agent of tributylvinylbenzyl chloride-methyl methacrylate copolymer, 0.8 parts of carbon black (pigment);

[0073] The pigment of antibacterial EVA material rice B is 0.2 parts of fluorescent blue.

[0074] The two-color antibacterial EVA shoe that above-mentioned preparation obtains, density 0.23g / cm 3 , hardness 55, DIN wear resistance 266 mm 3 , dimensional shrinkage 1.5%, rebound rate 55%, tear strength 5.8N / mm, dynamic anti-slip coefficient smooth dry type 0.63 wet type 0.49, static anti-slip coefficient dry type 0.50 wet type 0.42, antibacterial rate again...

Embodiment 3

[0076] In the present embodiment, the preparation method of a kind of two-color antibacterial EVA shoes is identical with the preparation method in embodiment 1, difference is:

[0077] Part of the composition of antibacterial EVA material rice A is changed to: 15 parts of EVA E210F, 35 parts of EVA PA470, 20 parts of ethylene-butylene copolymer ENR7086, 6 parts of quaternary ammonium salt polymer antibacterial agent ASQA, 3 parts of chlorinated polyethylene, 10 parts of talcum powder, obtain antibacterial EVA material rice A;

[0078] The two-color antibacterial EVA shoe that above-mentioned preparation obtains, density 0.21g / cm 3 , hardness 54, DIN wear resistance 282 mm 3 , dimensional shrinkage 1.5%, rebound rate 56%, tear strength 5.3N / mm, dynamic anti-slip coefficient smooth dry type 0.55 wet type 0.43, static anti-slip coefficient dry type 0.47 wet type 0.38, antibacterial rate against Escherichia coli 99.9%, The antibacterial rate against Staphylococcus aureus is 99....

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Abstract

The invention relates to organic polymer compound technical field, and provides a bi-color antibacterial EVA footwear and a preparation method thereof, two different colors of antibacterial EVA material grains are prepared from raw material EVA, ethylene-butene copolymer, 1, 2-polybutadiene, an antibacterial agent, chlorinated polyethylene, a foaming agent, a crosslinking agent, zinc stearate, stearic acid, a wear-resisting agent, talcum powder and a pigment by smelting, open milling and granulation, two different colors of antibacterial EVA material grains are respectively pouring into different material absorption barrels of an EVA injection machine table for once ejection to obtain the bi-color antibacterial EVA footwear, the echerichia coli and staphylococcus aureus antibacterial rates of the bi-color antibacterial EVA footwear are more than 99%, the bi-color antibacterial EVA footwear has good water-proof weather-proof lasting antibacterial properties, has the characteristics of light weight, good comprehensive performance, high production efficiency, high product qualified rate and the like, and is especially suitable for production of sandals, slippers, indoor shoes and other EVA shoes which are in direct contact with human skin, and is lightweight and comfortable, and cost-effective.

Description

technical field [0001] The invention belongs to the technical field of organic polymer compounds, and in particular relates to a double-color antibacterial EVA shoe and a preparation method thereof. Background technique [0002] Shoes are daily necessities that everyone wears. People wear shoes for 2 / 3 of their lives. When most people wear shoes and boots, especially in summer and after exercise, due to the sharp increase in sweat secretion and the rapid reproduction of microorganisms, a large amount of organic matter in sweat is decomposed to produce stench, which even leads to foot odor, athlete's foot, Hong Kong A series of illnesses such as pin, beriberi directly affect people's physical and mental health. The reason is that EVA is a crystalline polymer with high crystallinity, so that there are relatively few small holes that can pass through the gas, that is, the air permeability is poor, and the temperature and humidity are just suitable for easy bacterial reproduct...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L23/28C08L9/00C08K13/02C08K5/14C08K3/04C08K5/098C08K5/09C08K3/34C08J9/10B29C45/16A43B13/04B29L31/50
CPCA43B13/04B29C45/16B29L2031/50C08J9/103C08J2323/08C08L23/0853C08L2205/025C08L2205/035C08L23/0815C08L9/00C08L23/286C08K13/02C08K5/14C08K5/098C08K5/09C08K3/34C08K3/04C08K2003/2241
Inventor 卢鑫丁思博罗显发廖毅彬郭彩莲周小兰林荷香林江金校红郑荣大
Owner 茂泰(福建)新材料科技有限公司
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