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Lithium ion battery insulating coating, preparation method and pole piece and lithium ion battery using insulating coating

A technology for lithium-ion batteries and insulating coatings, applied in the field of lithium-ion battery insulating coatings, pole pieces and lithium-ion batteries, can solve the problems of uneven insulation performance of coatings, affecting lithium-ion batteries, and difficulty in uniform coating. Achieve the effects of easy operation, improved resistance consistency, and uniform stability

Inactive Publication Date: 2015-03-25
CHINA AVIATION LITHIUM BATTERY LUOYANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the production, use and testing cannot completely avoid the occurrence of internal short circuit problems. Usually, tapes are used to insulate the tabs, dressing edges and scribed areas to solve the internal short circuit problem. However, this insulation The tape is thick, and at the same time, the manual operation is heavy, the process is complicated, and the production efficiency is low. Moreover, the tape has defects such as long-term soaking failure, dissolution of viscous material, electrolyte contamination, deformation and failure at high temperature, etc., which affect the performance of lithium-ion batteries. Aiming at the defects of insulating tape, an insulating coating has been developed in the prior art, which can be coated on areas such as tabs, dressing edges, and markings to achieve insulation and prevent short circuits. For example, Chinese patent CN101867070B discloses an inorganic An insulating coating composed of oxides and binders, but the coating is not easy to coat evenly, and the insulation performance of the coating is not uniform.

Method used

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  • Lithium ion battery insulating coating, preparation method and pole piece and lithium ion battery using insulating coating
  • Lithium ion battery insulating coating, preparation method and pole piece and lithium ion battery using insulating coating
  • Lithium ion battery insulating coating, preparation method and pole piece and lithium ion battery using insulating coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The lithium-ion battery insulating coating of this embodiment is composed of the following active ingredients in weight percent: 95% of aluminum oxide, 4% of ethylene-vinyl acetate copolymer emulsion, and 1% of sodium methylcellulose.

[0044] The preparation method of the lithium-ion battery insulating coating in this example is as follows: weigh each component according to the composition of the insulating coating, weigh 10 g of sodium methylcellulose and dissolve it in 400 g of water to obtain solution A. Weigh 3500g of deionized water, add 950g of alumina powder into the water and mix evenly to obtain dispersion B, then add 80g of ethylene-vinyl acetate copolymer emulsion to dispersion B, mix evenly, grind and disperse through 0.4mm zirconium beads 5h to get the mixed solution C, then add the solution A to the mixed solution C, mix evenly, stir and disperse at 7000rpm for 2h, and then get the water-based insulating coating.

[0045] The insulating coating prepared b...

Embodiment 2

[0049] The lithium-ion battery insulating coating of this embodiment is composed of the following active ingredients in weight percent: 40% of aluminum oxide, 30% of barium sulfate, 29% of styrene-butadiene rubber emulsion, and 1% of polyvinyl alcohol.

[0050] The preparation method of the lithium-ion battery insulating coating in this example is as follows: weigh each component according to the composition of the insulating coating, weigh 10 g of polyvinyl alcohol and dissolve it in 500 g of water to obtain solution A. Weigh 3600g of deionized water, add 400g of alumina powder and 300g of barium sulfate into the water and mix evenly to obtain dispersion B, then add 290g of styrene-butadiene rubber to the dispersion B, mix evenly, grind and disperse through 0.8mm zirconium beads 2h to get the mixed solution C, then add the solution A to the mixed solution C, mix evenly, stir and disperse at 8000rpm for 1h, and then get the water-based insulating coating.

[0051] The insulati...

Embodiment 3

[0054] The lithium-ion battery insulating coating of this embodiment is made up of the active ingredient of following percentage by weight: styrene-butadiene rubber emulsion 30%, ethylene-vinyl acetate copolymer emulsion 45%, polytetrafluoroethylene emulsion 22%, polyoxyethylene 2% , Sodium methylcellulose 1%.

[0055] The preparation method of the lithium-ion battery insulating coating in this example is as follows: weigh each component according to the composition of the insulating coating, weigh 20 g of polyethylene oxide and 10 g of sodium methylcellulose and dissolve them in 600 g of water to obtain solution A. Take by weighing 2000g deionized water, add 600g styrene-butadiene rubber emulsion in water and mix homogeneously, obtain mixed solution B, then add 900g ethylene-vinyl acetate copolymer emulsion in mixed solution B, mix homogeneously, obtain mixed solution C, add to Add 440g of polytetrafluoroethylene emulsion to the mixed solution C, and mix evenly to obtain the ...

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Abstract

The invention discloses a lithium ion battery insulating coating, a preparation method and a pole piece and a lithium ion battery using the insulating coating, and belongs to the technical field of lithium ion batteries. The effective components of the lithium ion battery insulating coating disclosed by the invention is formed by inorganic powder, an adhesive and a dispersing agent, wherein the three components generate a synergistic effect to improve the uniformity and stability of the insulating coating and improve the resistance uniformity of an insulating coating layer formed by the insulating coating, and the bonding strength with an aluminum foil matrix for the pole piece is high, thereby being unlikely to drop. The preparation method of the lithium ion battery insulating coating disclosed by the invention is easy to operate and is suitable for industrialized promotion and application, the inorganic powder, the adhesive and the dispersing agent are mixed in a high speed stirring and dispersing manner, so as to improve the uniformity and stability of the insulating coating, and the insulating coating is free of such phenomena as lamination and settlement after being stored for a long term. The lithium ion battery prepared by the insulating coating disclosed by the invention is good in safety performance and is stable in electrochemical performance.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to an insulating coating for lithium ion batteries, a preparation method, pole pieces and lithium ion batteries using the insulating coating. Background technique [0002] The main reasons for the failure of lithium-ion batteries are overcharging, overheating, short circuit and so on. Overcharging and overheating can be solved by external methods such as PTC, fuse, and cooling equipment, but short circuit is difficult to solve by external methods, and can only be improved from the inside of the lithium-ion battery. From a theoretical analysis, although the cause of the short circuit is quite complicated, the result is the short circuit of the positive and negative poles. According to the short circuit contact method of the positive and negative poles, the internal short circuit can be divided into four types as shown in Table 1 below: [0003] Table 1 Diff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/25C09D7/12H01M4/13H01M10/0525
CPCC08L2203/20C08L2205/03C08L2205/035C09D5/00C09D7/61C09D7/65C09D109/06C09D109/08C09D123/0853C09D183/04H01M4/13H01M10/0525C08L1/286C08K2003/2227C08L29/04C08K2003/3045C08L27/18C08L71/02C08L9/08C08L5/00C08K2003/2296C08L9/02C08L39/06C08K2003/2244Y02E60/10
Inventor 王海文张国军怀永建白莉刘娇张海峰贾海
Owner CHINA AVIATION LITHIUM BATTERY LUOYANG
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