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Self-cleaning material for signal line and preparation method thereof

A self-cleaning and signal line technology, applied in the field of polymer materials, can solve the problems of signal lines that do not have self-cleaning function, no appearance, low surface energy, etc., and achieve the effect of bright appearance, reasonable process and good weather resistance

Active Publication Date: 2017-02-15
DONGGUAN YINGTONG WIRE +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, there is no composite material that uses hydroxyl-terminated fluorine-containing polyester polysiloxane, chitosan surface-modified calcium carbonate, isocyanate, and thermoplastic polyolefin elastomer to prepare fluorine-containing siloxane. Using its low surface energy, self-cleaning effect, good elasticity, and excellent comprehensive performance, it is applied to signal wires to overcome the lack of self-cleaning function of existing signal wires

Method used

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  • Self-cleaning material for signal line and preparation method thereof
  • Self-cleaning material for signal line and preparation method thereof
  • Self-cleaning material for signal line and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] This embodiment provides a self-cleaning material for signal lines, which is made of the following components in parts by weight:

[0034]

[0035] The PS-b-PDMS-b-PS block copolymer uses n-butyllithium as an initiator, cyclohexane as a solvent, tetrahydrofuran as a polarity regulator, and dichlorodimethylsilane as a coupling agent. Polystyrene-b-polydimethylsiloxane-b-polystyrene block copolymer prepared by coupling reaction and anion polymerization. The molecular weight Mn of this polymer is 22120g / mol, and the content of polydimethylsiloxane segment is between 22-33%. Paper Polystyrene-b-polydimethylsiloxane-b-polystyrene triblock copolymer synthesis and its modified epoxy coating.

[0036] The POE-g-MAH is a maleic anhydride grafted ethylene-octene copolymer prepared by a solvothermal synthesis method, and the grafting rate is 5-10%.

[0037] The fluorinated diisocyanate is OCNCH 2 CH 2 (CF 2 )nCH 2 CH 2 NCO, OCN (CF 2 ) 3 NCO, NCOCH 2 (CF 2 ) 4 CH 2...

Embodiment 2

[0052] Embodiment 2: A self-cleaning material for signal lines and its preparation method provided in this embodiment are basically the same as in Embodiment 1, except that:

[0053] A self-cleaning material for signal lines, which is made of the following components in parts by weight:

[0054]

[0055] The PS-b-PDMS-b-PS block copolymer uses n-butyllithium as an initiator, cyclohexane as a solvent, tetrahydrofuran as a polarity regulator, and dichlorodimethylsilane as a coupling agent. Polystyrene-b-polydimethylsiloxane-b-polystyrene block copolymer prepared by coupling reaction and anionic polymerization method, wherein the content of polydimethylsiloxane segment is 22% .

[0056] The POE-g-MAH is a maleic anhydride grafted ethylene-octene copolymer prepared by a solvothermal synthesis method, and the grafting rate is 5%.

[0057] The fluorinated diisocyanate is OCNCH 2 CH 2 (CF 2 )nCH 2 CH 2 NCO, the range of n is 2, and NCOCH 2 (CF 2 ) 4 CH 2 A mixture of NC...

Embodiment 3

[0062] Embodiment 3: A self-cleaning material for signal lines and its preparation method provided in this embodiment are basically the same as Embodiments 1 and 2, except that:

[0063] A self-cleaning material for signal lines, which is made of the following components in parts by weight:

[0064]

[0065]

[0066] The PS-b-PDMS-b-PS block copolymer uses n-butyllithium as an initiator, cyclohexane as a solvent, tetrahydrofuran as a polarity regulator, and dichlorodimethylsilane as a coupling agent. Polystyrene-b-polydimethylsiloxane-b-polystyrene block copolymer prepared by coupling reaction and anionic polymerization method, wherein the content of polydimethylsiloxane segment is 27% .

[0067] The POE-g-MAH is a maleic anhydride grafted ethylene-octene copolymer prepared by a solvothermal synthesis method, and the grafting rate is 7%.

[0068] The fluorinated diisocyanate is OCNCH 2 CH 2 (CF 2 )nCH 2 CH 2 NCO, the value range of n is 16.

[0069] The processin...

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Abstract

The invention discloses a self-cleaning material for signal lines. The self-cleaning material is prepared from the following ingredients, by weight, 30-40 parts of hydroxyl-terminated fluorine-containing polyester polysiloxane, 10-20 parts of chitosan- adipic acid dual coating modified calcium carbonate, 40-60 parts of diisocyanate fluoride, 20-30 parts of a PS-b-PDMS-b-PS segmented copolymer, 10-15 parts of POE-g-MAH and 15-25 parts of a processing aid. The invention also discloses a preparation method of the self-cleaning material for signal lines. The product has characteristics of low surface tension of fluoroalkyl-containing and siloxane-containing structures, hydrophobicity, oleophobicity and the like. When the product is applied to signal lines, the product has advantages of self-cleaning function, high anti-pollution ability, flexibility, good elasticity, good hand feeling, good weatherability, chemicals resistance, antibacterial property and the like, and is not easy to scratch or leave a trace. When in use, the product can keep bright in appearance for a long time. thus, the defect that most existing fluorine-containing materials have high hardness and inflexible molecular chain and are not applicable to signal lines is overcome.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a self-cleaning material for signal lines and a preparation method thereof. Background technique [0002] During long-term use, signal wires such as earphone wires often come into contact with oil, moisture, cosmetics, etc. due to storage or wearing. Dirt, oil and water resistance. [0003] Polyurethane (PU) materials have been widely used in many fields and daily life because of their good mechanical properties, low temperature curing, high adhesion strength, and water resistance, solvent resistance, and low temperature resistance. However, with the rapid development and progress of society, higher and newer requirements have been put forward for the protective and decorative properties of materials, especially durability. Facing the new requirements, the original polyurethane materials have shown great shortcomings. , which limits its application, and fluorine-conta...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L75/04C08L51/06C08L53/00C08K13/06C08K9/10C08K3/26C08K5/09C08K5/098C08K5/134C08K5/57C08G18/77C08G18/61B29C47/92B29C48/92
Inventor 向伟吴朝秋
Owner DONGGUAN YINGTONG WIRE
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